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Efficient excimer-based white OLEDs with reduced efficiency roll-off

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/5.0043955· OSTI ID:1848479
 [1];  [2];  [2];  [2]
  1. Arizona State University, Tempe, AZ (United States). Department of Materials Science and Engineering; Arizona State Univ., Tempe, AZ (United States)
  2. Arizona State University, Tempe, AZ (United States). Department of Materials Science and Engineering
A tetradentate Pt(II) complex, Pt2O2-p2m, which exhibits both efficient monomer and excimer emission, was synthesized. Through rational device design to broaden the recombination zone, an OLED device employing Pt2O2-p2m demonstrated an impressively high peak external quantum efficiency (EQE) of 21.5% and a warm white emission with a color rendering index of 71 and Commission Internationale de L'Eclairage coordinates of (0.409, 0.458). Moreover, a reduced efficiency roll-off was also observed to retain high EQE values of 20% EQE at 1000 cd/m2 and 17% EQE at 5000 cd/m2, and an LT70 (time to 70% initial luminance) was estimated to be over 150 h at 1000 cd/m2 under constant operation at accelerated driving conditions.
Research Organization:
Arizona State University, Tempe, AZ (United States)
Sponsoring Organization:
USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
EE0007090; EE0008721
OSTI ID:
1848479
Alternate ID(s):
OSTI ID: 1766357
Journal Information:
Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 7 Vol. 118; ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English

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