Atomically Dispersed Transition Metals on Carbon Nanotubes with Ultrahigh Loading for Selective Electrochemical Carbon Dioxide Reduction

Cheng, Yi; Zhao, Shiyong; Johannessen, Bernt; Veder, Jean-Pierre; Saunders, Martin; Rowles, Matthew; Cheng, Min; Liu, Chang; Chisholm, Matthew; De Marco, Roland; Cheng, Hui-Ming; Yang, Shize; Jiang, San Ping

doi:10.1002/adma.201706287

Title: Atomically Dispersed Transition Metals on Carbon Nanotubes with Ultrahigh Loading for Selective Electrochemical Carbon Dioxide Reduction

Journal Article · Fri Feb 09 00:00:00 EST 2018 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201706287· OSTI ID:1846560

Cheng, Yi ^[1]; Zhao, Shiyong ^[1]; Johannessen, Bernt ^[2]; Veder, Jean-Pierre ^[1]; Saunders, Martin ^[3]; Rowles, Matthew ^[1]; Cheng, Min ^[4]; Liu, Chang ^[4];

^[5]; De Marco, Roland ^[6]; Cheng, Hui-Ming ^[7];

^[5]; Jiang, San Ping ^[1]

Curtin Univ., Perth, WA (Australia)
Australian Synchrotron, Clayton (Australia)
Univ. of Western Australia, Perth, WA (Australia)
Chinese Academy of Sciences (CAS), Shenyang (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Curtin Univ., Perth, WA (Australia); Univ. of Sunshine Coast, Queensland (Australia); Univ. of Queensland, Brisbane, QLD (Australia)
Chinese Academy of Sciences (CAS), Shenyang (China); Tsinghua Univ., Shenzhua (China); King Abdulaziz Univ., Jeddah (Saudi Arabia)

Single-atom catalysts (SACs) are the smallest entities for catalytic reactions with projected high atomic efficiency, superior activity, and selectivity; however, practical applications of SACs suffer from a very low metal loading of 1–2 wt%. Here, a class of SACs based on atomically dispersed transition metals on nitrogen-doped carbon nanotubes (MSA-N-CNTs, where M = Ni, Co, NiCo, CoFe, and NiPt) is synthesized with an extraordinarily high metal loading, e.g., 20 wt% in the case of NiSA-N-CNTs, using a new multistep pyrolysis process. Among these materials, NiSA-N-CNTs show an excellent selectivity and activity for the electrochemical reduction of CO₂ to CO, achieving a turnover frequency (TOF) of 11.7 s^-1 at -0.55 V (vs reversible hydrogen electrode (RHE)), two orders of magnitude higher than Ni nanoparticles supported on CNTs.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Univ. of California, Oakland, CA (United States)

Sponsoring Organization:: Australian Research Council; National Science Foundation (NSF); National Natural Science Foundation of China (NSFC); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC05-00OR22725; AC02-05CH11231; DP150102044; DP150102025; LE120100026; ACI-1053575; 51521091

OSTI ID:: 1846560

Alternate ID(s):: OSTI ID: 1419993; OSTI ID: 1543459

Journal Information:: Advanced Materials, Vol. 30, Issue 13; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 467 works

Citation information provided by
Web of Science

References (40)

Ionic Exchange of Metal–Organic Frameworks to Access Single Nickel Sites for Efficient Electroreduction of CO ₂ Zhao, Changming; Dai, Xinyao; Yao, Tao Journal of the American Chemical Society, Vol. 139, Issue 24 https://doi.org/10.1021/jacs.7b02736	journal	June 2017
Graphitic carbon nitride supported single-atom catalysts for efficient oxygen evolution reaction Li, Xiyu; Cui, Peng; Zhong, Wenhui Chemical Communications, Vol. 52, Issue 90 https://doi.org/10.1039/C6CC07049C	journal	January 2016
Selective Conversion of CO ₂ to CO with High Efficiency Using an Inexpensive Bismuth-Based Electrocatalyst DiMeglio, John L.; Rosenthal, Joel Journal of the American Chemical Society, Vol. 135, Issue 24 https://doi.org/10.1021/ja4033549	journal	June 2013
Tackling CO Poisoning with Single-Atom Alloy Catalysts Liu, Jilei; Lucci, Felicia R.; Yang, Ming Journal of the American Chemical Society, Vol. 138, Issue 20 https://doi.org/10.1021/jacs.6b03339	journal	May 2016
Nanostructured 2D Materials: Prospective Catalysts for Electrochemical CO ₂ Reduction Liu, Jinlong; Guo, Chunxian; Vasileff, Anthony Small Methods, Vol. 1, Issue 1-2 https://doi.org/10.1002/smtd.201600006	journal	November 2016
Exceptional Size-Dependent Activity Enhancement in the Electroreduction of CO ₂ over Au Nanoparticles Mistry, Hemma; Reske, Rulle; Zeng, Zhenhua Journal of the American Chemical Society, Vol. 136, Issue 47 https://doi.org/10.1021/ja508879j	journal	November 2014
Nickel L-Edge Soft X-ray Spectroscopy of Nickel−Iron Hydrogenases and Model CompoundsEvidence for High-Spin Nickel(II) in the Active Enzyme Wang, Hongxin; Ralston, C. Y.; Patil, D. S. Journal of the American Chemical Society, Vol. 122, Issue 43 https://doi.org/10.1021/ja000945g	journal	November 2000
Utilization of Electropolymerized Films of Cobalt Porphyrin for the Reduction of Carbon Dioxide in Aqueous Media Pander, James E.; Fogg, Alex; Bocarsly, Andrew B. ChemCatChem, Vol. 8, Issue 22 https://doi.org/10.1002/cctc.201600875	journal	October 2016
Molecule-Level g-C ₃ N ₄ Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions Zheng, Yao; Jiao, Yan; Zhu, Yihan Journal of the American Chemical Society, Vol. 139, Issue 9 https://doi.org/10.1021/jacs.6b13100	journal	February 2017
Nanoporous Graphene with Single-Atom Nickel Dopants: An Efficient and Stable Catalyst for Electrochemical Hydrogen Production Qiu, H. -J.; Ito, Yoshikazu; Cong, Weitao Angewandte Chemie, Vol. 127, Issue 47 https://doi.org/10.1002/ange.201507381	journal	October 2015
A General Approach to Preferential Formation of Active Fe–N _x Sites in Fe–N/C Electrocatalysts for Efficient Oxygen Reduction Reaction Sa, Young Jin; Seo, Dong-Jun; Woo, Jinwoo Journal of the American Chemical Society, Vol. 138, Issue 45 https://doi.org/10.1021/jacs.6b09470	journal	November 2016
Recent Advances in Atomic Metal Doping of Carbon-based Nanomaterials for Energy Conversion Bayatsarmadi, Bita; Zheng, Yao; Vasileff, Anthony Small, Vol. 13, Issue 21 https://doi.org/10.1002/smll.201700191	journal	April 2017
Only a supporting role Armstrong, Gavin Nature Chemistry, Vol. 5, Issue 10 https://doi.org/10.1038/nchem.1772	journal	September 2013
A Stable Single-Site Palladium Catalyst for Hydrogenations Vilé, Gianvito; Albani, Davide; Nachtegaal, Maarten Angewandte Chemie International Edition, Vol. 54, Issue 38 https://doi.org/10.1002/anie.201505073	journal	July 2015
Effect of Chloride Anions on the Synthesis and Enhanced Catalytic Activity of Silver Nanocoral Electrodes for CO ₂ Electroreduction Hsieh, Yu-Chi; Senanayake, Sanjaya D.; Zhang, Yu ACS Catalysis, Vol. 5, Issue 9 https://doi.org/10.1021/acscatal.5b01235	journal	August 2015
A Local Proton Source Enhances CO ₂ Electroreduction to CO by a Molecular Fe Catalyst Costentin, Cyrille; Drouet, Samuel; Robert, Marc Science, Vol. 338, Issue 6103 https://doi.org/10.1126/science.1224581	journal	October 2012
Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions Chen, Pengzuo; Zhou, Tianpei; Xing, Lili Angewandte Chemie International Edition, Vol. 56, Issue 2 https://doi.org/10.1002/anie.201610119	journal	December 2016
Hydroformylation of Olefins by a Rhodium Single-Atom Catalyst with Activity Comparable to RhCl(PPh ₃ ) ₃ Lang, Rui; Li, Tianbo; Matsumura, Daiju Angewandte Chemie International Edition, Vol. 55, Issue 52 https://doi.org/10.1002/anie.201607885	journal	November 2016
Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide-Derived Nanostructured Silver Electrocatalysts Ma, Ming; Trześniewski, Bartek J.; Xie, Jie Angewandte Chemie International Edition, Vol. 55, Issue 33 https://doi.org/10.1002/anie.201604654	journal	July 2016
X-ray spectroscopic studies of nickel complexes, with application to the structure of nickel sites in hydrogenases Colpas, Gerard J.; Maroney, Michael J.; Bagyinka, Csaba. Inorganic Chemistry, Vol. 30, Issue 5 https://doi.org/10.1021/ic00005a010	journal	March 1991
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO ₂ to CO Zhu, Wenlei; Michalsky, Ronald; Metin, Önder Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja409445p	journal	October 2013
Cobalt-Embedded Nitrogen-Rich Carbon Nanotubes Efficiently Catalyze Hydrogen Evolution Reaction at All pH Values Zou, Xiaoxin; Huang, Xiaoxi; Goswami, Anandarup Angewandte Chemie, Vol. 126, Issue 17 https://doi.org/10.1002/ange.201311111	journal	March 2014
Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300361m	journal	April 2013
Electrodeposited Zn Dendrites with Enhanced CO Selectivity for Electrocatalytic CO ₂ Reduction Rosen, Jonathan; Hutchings, Gregory S.; Lu, Qi ACS Catalysis, Vol. 5, Issue 8 https://doi.org/10.1021/acscatal.5b00922	journal	July 2015
The Current Performance of the Wide Range (90–2500 eV) Soft X-ray Beamline at the Australian Synchrotron Cowie, B. C. C.; Tadich, A.; Thomsen, L. SRI 2009, 10TH INTERNATIONAL CONFERENCE ON RADIATION INSTRUMENTATION, AIP Conference Proceedings https://doi.org/10.1063/1.3463197	conference	January 2010
Single-atom catalysis of CO oxidation using Pt1/FeOx Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng Nature Chemistry, Vol. 3, Issue 8 https://doi.org/10.1038/nchem.1095	journal	July 2011
Improved catalysts for hydrogen evolution reaction in alkaline solutions through the electrochemical formation of nickel-reduced graphene oxide interface Gutić, Sanjin J.; Dobrota, Ana S.; Leetmaa, Mikael Physical Chemistry Chemical Physics, Vol. 19, Issue 20 https://doi.org/10.1039/C7CP01237C	journal	January 2017
Carbon Solving Carbon's Problems: Recent Progress of Nanostructured Carbon-Based Catalysts for the Electrochemical Reduction of CO ₂ Vasileff, Anthony; Zheng, Yao; Qiao, Shi Zhang Advanced Energy Materials, Vol. 7, Issue 21 https://doi.org/10.1002/aenm.201700759	journal	July 2017
Potential-Cycling Synthesis of Single Platinum Atoms for Efficient Hydrogen Evolution in Neutral Media Zhang, Lihan; Han, Lili; Liu, Haoxuan Angewandte Chemie International Edition, Vol. 56, Issue 44 https://doi.org/10.1002/anie.201706921	journal	August 2017
Single-Atom Catalyst of Platinum Supported on Titanium Nitride for Selective Electrochemical Reactions Yang, Sungeun; Kim, Jiwhan; Tak, Young Joo Angewandte Chemie International Edition, Vol. 55, Issue 6 https://doi.org/10.1002/anie.201509241	journal	December 2015
Stabilizing a Platinum ₁ Single-Atom Catalyst on Supported Phosphomolybdic Acid without Compromising Hydrogenation Activity Zhang, Bin; Asakura, Hiroyuki; Zhang, Jia Angewandte Chemie International Edition, Vol. 55, Issue 29 https://doi.org/10.1002/anie.201602801	journal	May 2016
Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: Development of highly efficient metal-free bifunctional electrocatalyst Yang, Hong Bin; Miao, Jianwei; Hung, Sung-Fu Science Advances, Vol. 2, Issue 4 https://doi.org/10.1126/sciadv.1501122	journal	April 2016
Single Atom (Pd/Pt) Supported on Graphitic Carbon Nitride as an Efficient Photocatalyst for Visible-Light Reduction of Carbon Dioxide Gao, Guoping; Jiao, Yan; Waclawik, Eric R. Journal of the American Chemical Society, Vol. 138, Issue 19 https://doi.org/10.1021/jacs.6b02692	journal	May 2016
The preparation of chromium, nickel and chromium–nickel alloy nanoparticles on supports Tilley, Richard D.; Jefferson, David A. J. Mater. Chem., Vol. 12, Issue 12 https://doi.org/10.1039/B204774H	journal	January 2002
In situ nucleation of carbon nanotubes by the injection of carbon atoms into metal particles Rodríguez-Manzo, Julio A.; Terrones, Mauricio; Terrones, Humberto Nature Nanotechnology, Vol. 2, Issue 5 https://doi.org/10.1038/nnano.2007.107	journal	April 2007
Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide-Derived Nanostructured Silver Electrocatalysts Ma, Ming; Trześniewski, Bartek J.; Xie, Jie Angewandte Chemie, Vol. 128, Issue 33 https://doi.org/10.1002/ange.201604654	journal	July 2016
Potential-Cycling Synthesis of Single Platinum Atoms for Efficient Hydrogen Evolution in Neutral Media Zhang, Lihan; Han, Lili; Liu, Haoxuan Angewandte Chemie, Vol. 129, Issue 44 https://doi.org/10.1002/ange.201706921	journal	August 2017
Nanoporous Graphene with Single-Atom Nickel Dopants: An Efficient and Stable Catalyst for Electrochemical Hydrogen Production Qiu, H. -J.; Ito, Yoshikazu; Cong, Weitao Angewandte Chemie International Edition, Vol. 54, Issue 47 https://doi.org/10.1002/anie.201507381	journal	October 2015
Stabilizing a Platinum ₁ Single-Atom Catalyst on Supported Phosphomolybdic Acid without Compromising Hydrogenation Activity Zhang, Bin; Asakura, Hiroyuki; Zhang, Jia Angewandte Chemie, Vol. 128, Issue 29 https://doi.org/10.1002/ange.201602801	journal	May 2016
Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions Chen, Pengzuo; Zhou, Tianpei; Xing, Lili Angewandte Chemie, Vol. 129, Issue 2 https://doi.org/10.1002/ange.201610119	journal	December 2016

Cited By (61)

Atomically Defined Undercoordinated Active Sites for Highly Efficient CO ₂ Electroreduction Zheng, Wanzhen; Yang, Jian; Chen, Hengquan Advanced Functional Materials, Vol. 30, Issue 4 https://doi.org/10.1002/adfm.201907658	journal	November 2019
From Molecular Precursors to Nanoparticles—Tailoring the Adsorption Properties of Porous Carbon Materials by Controlled Chemical Functionalization Perovic, Milena; Qin, Qing; Oschatz, Martin Advanced Functional Materials, Vol. 30, Issue 41 https://doi.org/10.1002/adfm.201908371	journal	January 2020
Carbon-Supported Single Atom Catalysts for Electrochemical Energy Conversion and Storage Peng, Yi; Lu, Bingzhang; Chen, Shaowei Advanced Materials, Vol. 30, Issue 48 https://doi.org/10.1002/adma.201801995	journal	August 2018
Recent Advances in Electrochemical CO ₂ -to-CO Conversion on Heterogeneous Catalysts Zheng, Tingting; Jiang, Kun; Wang, Haotian Advanced Materials, Vol. 30, Issue 48 https://doi.org/10.1002/adma.201802066	journal	August 2018
Harnessing the Wisdom in Colloidal Chemistry to Make Stable Single-Atom Catalysts Hülsey, Max J.; Zhang, Jiaguang; Yan, Ning Advanced Materials, Vol. 30, Issue 47 https://doi.org/10.1002/adma.201802304	journal	July 2018
Synthesis and Applications of Graphdiyne‐Based Metal‐Free Catalysts Zuo, Zicheng; Wang, Dan; Zhang, Jin Advanced Materials, Vol. 31, Issue 13 https://doi.org/10.1002/adma.201803762	journal	September 2018
Emerging Carbon‐Based Heterogeneous Catalysts for Electrochemical Reduction of Carbon Dioxide into Value‐Added Chemicals Wu, Jingjie; Sharifi, Tiva; Gao, Ying Advanced Materials, Vol. 31, Issue 13 https://doi.org/10.1002/adma.201804257	journal	December 2018
Iron‐Free Cathode Catalysts for Proton‐Exchange‐Membrane Fuel Cells: Cobalt Catalysts and the Peroxide Mitigation Approach Wang, Xiao Xia; Prabhakaran, Venkateshkumar; He, Yanghua Advanced Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adma.201805126	journal	December 2018
Metal and Nonmetal Codoped 3D Nanoporous Graphene for Efficient Bifunctional Electrocatalysis and Rechargeable Zn–Air Batteries Qiu, Hua‐Jun; Du, Peng; Hu, Kailong Advanced Materials, Vol. 31, Issue 19 https://doi.org/10.1002/adma.201900843	journal	March 2019
Synergistic Catalysis over Iron‐Nitrogen Sites Anchored with Cobalt Phthalocyanine for Efficient CO ₂ Electroreduction Lin, Long; Li, Haobo; Yan, Chengcheng Advanced Materials, Vol. 31, Issue 41 https://doi.org/10.1002/adma.201903470	journal	August 2019
Catalysis of a Single Transition Metal Site for Water Oxidation: From Mononuclear Molecules to Single Atoms Zhang, Huayang; Tian, Wenjie; Duan, Xiaoguang Advanced Materials, Vol. 32, Issue 18 https://doi.org/10.1002/adma.201904037	journal	December 2019
Enzymes Immobilized on Carbon Nitride (C ₃ N ₄ ) Cooperating with Metal Nanoparticles for Cascade Catalysis Wang, Yangxin; Zhang, Ningning; Hübner, René Advanced Materials Interfaces, Vol. 6, Issue 6 https://doi.org/10.1002/admi.201801664	journal	January 2019
Iron Single Atoms on Graphene as Nonprecious Metal Catalysts for High‐Temperature Polymer Electrolyte Membrane Fuel Cells Cheng, Yi; He, Shuai; Lu, Shanfu Advanced Science, Vol. 6, Issue 10 https://doi.org/10.1002/advs.201802066	journal	March 2019
Orbital Interactions in Bi-Sn Bimetallic Electrocatalysts for Highly Selective Electrochemical CO ₂ Reduction toward Formate Production Wen, Guobin; Lee, Dong Un; Ren, Bohua Advanced Energy Materials, Vol. 8, Issue 31 https://doi.org/10.1002/aenm.201802427	journal	September 2018
Densely Populated Isolated Single CoN Site for Efficient Oxygen Electrocatalysis Wu, Jiabin; Zhou, He; Li, Qun Advanced Energy Materials, Vol. 9, Issue 22 https://doi.org/10.1002/aenm.201900149	journal	April 2019
A Disquisition on the Active Sites of Heterogeneous Catalysts for Electrochemical Reduction of CO ₂ to Value‐Added Chemicals and Fuel Daiyan, Rahman; Saputera, Wibawa Hendra; Masood, Hassan Advanced Energy Materials, Vol. 10, Issue 11 https://doi.org/10.1002/aenm.201902106	journal	November 2019
Engineering Local Coordination Environments of Atomically Dispersed and Heteroatom‐Coordinated Single Metal Site Electrocatalysts for Clean Energy‐Conversion Zhu, Yuanzhi; Sokolowski, Joshua; Song, Xiancheng Advanced Energy Materials, Vol. 10, Issue 11 https://doi.org/10.1002/aenm.201902844	journal	November 2019
In Situ Thermal Atomization To Convert Supported Nickel Nanoparticles into Surface-Bound Nickel Single-Atom Catalysts Yang, Jian; Qiu, Zongyang; Zhao, Changming Angewandte Chemie, Vol. 130, Issue 43 https://doi.org/10.1002/ange.201808049	journal	October 2018
Isolated Diatomic Ni‐Fe Metal–Nitrogen Sites for Synergistic Electroreduction of CO ₂ Ren, Wenhao; Tan, Xin; Yang, Wanfeng Angewandte Chemie, Vol. 131, Issue 21 https://doi.org/10.1002/ange.201901575	journal	April 2019
When Nanozymes Meet Single‐Atom Catalysis Jiao, Lei; Yan, Hongye; Wu, Yu Angewandte Chemie, Vol. 132, Issue 7 https://doi.org/10.1002/ange.201905645	journal	October 2019
Highly Efficient CO ₂ Electroreduction on ZnN ₄ -based Single-Atom Catalyst Yang, Fa; Song, Ping; Liu, Xiaozhi Angewandte Chemie International Edition, Vol. 57, Issue 38 https://doi.org/10.1002/anie.201805871	journal	August 2018
Reaction Mechanisms of Well-Defined Metal-N ₄ Sites in Electrocatalytic CO ₂ Reduction Zhang, Zheng; Xiao, Jianping; Chen, Xue-Jiao Angewandte Chemie International Edition, Vol. 57, Issue 50 https://doi.org/10.1002/anie.201808593	journal	November 2018
Metal-Organic-Framework-Derived Hollow N-Doped Porous Carbon with Ultrahigh Concentrations of Single Zn Atoms for Efficient Carbon Dioxide Conversion Yang, Qihao; Yang, Chun-Chuen; Lin, Chia-Her Angewandte Chemie International Edition, Vol. 58, Issue 11 https://doi.org/10.1002/anie.201813494	journal	January 2019
Isolated Diatomic Ni-Fe Metal-Nitrogen Sites for Synergistic Electroreduction of CO ₂ Ren, Wenhao; Tan, Xin; Yang, Wanfeng Angewandte Chemie International Edition, Vol. 58, Issue 21 https://doi.org/10.1002/anie.201901575	journal	April 2019
When Nanozymes Meet Single‐Atom Catalysis Jiao, Lei; Yan, Hongye; Wu, Yu Angewandte Chemie International Edition, Vol. 59, Issue 7 https://doi.org/10.1002/anie.201905645	journal	February 2020
Single Atom Catalysts on Carbon-Based Materials Rivera-Cárcamo, Camila; Serp, Philippe ChemCatChem, Vol. 10, Issue 22 https://doi.org/10.1002/cctc.201801174	journal	November 2018
Metal Ionic Liquids Produce Metal‐Dispersed Carbon‐Nitrogen Networks for Efficient CO ₂ Electroreduction Cheng, Xiuyan; Tan, Dongxing; Zeng, Shaojuan ChemCatChem, Vol. 11, Issue 14 https://doi.org/10.1002/cctc.201900615	journal	June 2019
Atomic Ni Species Anchored N‐Doped Carbon Hollow Spheres as Nanoreactors for Efficient Electrochemical CO ₂ Reduction Ma, Shuangshuang; Su, Panpan; Huang, Wenjuan ChemCatChem, Vol. 11, Issue 24 https://doi.org/10.1002/cctc.201901643	journal	October 2019
Highly Sensitive and Selective Electrochemical Detection of Dopamine using Hybrid Bilayer Membranes Patrice, Fato T.; Zhao, Li‐Jun; Fodjo, Essy K. ChemElectroChem, Vol. 6, Issue 3 https://doi.org/10.1002/celc.201801367	journal	September 2018
Atomically Dispersed Bimetallic FeNi Catalysts as Highly Efficient Bifunctional Catalysts for Reversible Oxygen Evolution and Oxygen Reduction Reactions Cheng, Yi; He, Shuai; Veder, Jean‐Pierre ChemElectroChem, Vol. 6, Issue 13 https://doi.org/10.1002/celc.201900483	journal	July 2019
Rational Design of Ag‐Based Catalysts for the Electrochemical CO ₂ Reduction to CO: A Review Sun, Dalei; Xu, Xiaomin; Qin, Yanling ChemSusChem, Vol. 13, Issue 1 https://doi.org/10.1002/cssc.201902061	journal	December 2019
Electrochemical CO ₂ Reduction to C ₁ Products on Single Nickel/Cobalt/Iron‐Doped Graphitic Carbon Nitride: A DFT Study Guo, Chen; Zhang, Tian; Deng, Xiangxuan ChemSusChem, Vol. 12, Issue 23 https://doi.org/10.1002/cssc.201902483	journal	November 2019
Optimizing Electron Densities of Ni‐N‐C Complexes by Hybrid Coordination for Efficient Electrocatalytic CO ₂ Reduction Wang, Zhong‐Li; Choi, Jaecheol; Xu, Mingquan ChemSusChem, Vol. 13, Issue 5 https://doi.org/10.1002/cssc.201903427	journal	February 2020
Single‐Atom Iron‐Nitrogen Catalytic Site with Graphitic Nitrogen for Efficient Electroreduction of CO ₂ Zhu, Ying; Li, Xueyan; Wang, Xingpu ChemistrySelect, Vol. 5, Issue 4 https://doi.org/10.1002/slct.201904529	journal	January 2020
Highly Efficient Electroreduction of CO 2 on Nickel Single‐Atom Catalysts: Atom Trapping and Nitrogen Anchoring Mou, Kaiwen; Chen, Zhipeng; Zhang, Xinxin Small, Vol. 15, Issue 49 https://doi.org/10.1002/smll.201903668	journal	October 2019
Defective Porous Carbon Polyhedra Decorated with Copper Nanoparticles for Enhanced NIR‐Driven Photothermal Cancer Therapy Weng, Yangziwan; Guan, Shanyue; Wang, Li Small, Vol. 16, Issue 1 https://doi.org/10.1002/smll.201905184	journal	December 2019
Modulating the Electronic Structure of Single‐Atom Catalysts on 2D Nanomaterials for Enhanced Electrocatalytic Performance Zhu, Yuanzhi; Peng, Wenchao; Li, Yang Small Methods, Vol. 3, Issue 9 https://doi.org/10.1002/smtd.201800438	journal	March 2019
Supported Single Atoms as New Class of Catalysts for Electrochemical Reduction of Carbon Dioxide Cheng, Yi; Yang, Shize; Jiang, San Ping Small Methods, Vol. 3, Issue 9 https://doi.org/10.1002/smtd.201800440	journal	February 2019
Nitrogen‐Doped Porous Carbon Supported Nonprecious Metal Single‐Atom Electrocatalysts: from Synthesis to Application Guo, Jiaojiao; Huo, Juanjuan; Liu, Yan Small Methods, Vol. 3, Issue 9 https://doi.org/10.1002/smtd.201900159	journal	May 2019
Densely Populated Single Atom Catalysts Wu, Jiabin; Xiong, Liukang; Zhao, Bote Small Methods, Vol. 4, Issue 2 https://doi.org/10.1002/smtd.201900540	journal	November 2019
Microwave absorbing and infrared radiation properties of Al@multi-walled carbon nanotubes composites Liu, Qingping; Xing, Honglong; Wang, Huan Journal of Materials Science: Materials in Electronics, Vol. 30, Issue 22 https://doi.org/10.1007/s10854-019-02342-5	journal	October 2019
In situ synthesis of surfactant-free Pt nanoparticles supported on multi-walled carbon nanotubes under visible light Feng, Yinxia; Su, Biquan; Xian, Liang Chemical Papers, Vol. 74, Issue 4 https://doi.org/10.1007/s11696-019-00955-y	journal	October 2019
A cocoon silk chemistry strategy to ultrathin N-doped carbon nanosheet with metal single-site catalysts Zhu, Youqi; Sun, Wenming; Luo, Jun Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06296-w	journal	September 2018
Single-atom nickel confined nanotube superstructure as support for catalytic wet air oxidation of acetic acid Jin, Chengyu; Ma, Lei; Sun, Wenjing Communications Chemistry, Vol. 2, Issue 1 https://doi.org/10.1038/s42004-019-0239-8	journal	November 2019
Unusual synergetic effect of nickel single atoms on the electrocatalytic activity of palladium for alcohol oxidation reactions in alkaline media Nitaya, Thantakorn; Cheng, Yi; Lu, Shanfu Chemical Communications, Vol. 54, Issue 87 https://doi.org/10.1039/c8cc07095d	journal	January 2018
Atomically dispersed Ni as the active site towards selective hydrogenation of nitroarenes Yang, Fan; Wang, Minjian; Liu, Wei Green Chemistry, Vol. 21, Issue 3 https://doi.org/10.1039/c8gc03664k	journal	January 2019
Heteroatom-doped carbon materials and their composites as electrocatalysts for CO ₂ reduction Cui, Huijuan; Guo, Yibo; Guo, Limin Journal of Materials Chemistry A, Vol. 6, Issue 39 https://doi.org/10.1039/c8ta07430e	journal	January 2018
Single Sb sites for efficient electrochemical CO ₂ reduction Jia, Mingwen; Hong, Song; Wu, Tai-Sing Chemical Communications, Vol. 55, Issue 80 https://doi.org/10.1039/c9cc06178a	journal	January 2019
Highly efficient electrochemical conversion of CO ₂ and NaCl to CO and NaClO Quan, Fengjiao; Zhan, Guangming; Shang, Huan Green Chemistry, Vol. 21, Issue 12 https://doi.org/10.1039/c9gc01099h	journal	January 2019
Poly-phenylenediamine-derived atomically dispersed Ni sites for the electroreduction of CO ₂ to CO Zheng, Yonglong; Han, Jianyu; Takele, Leta Inorganic Chemistry Frontiers, Vol. 6, Issue 7 https://doi.org/10.1039/c9qi00297a	journal	January 2019
Cu _x Ni _y alloy nanoparticles embedded in a nitrogen–carbon network for efficient conversion of carbon dioxide Tan, Dongxing; Zhang, Jianling; Cheng, Xiuyan Chemical Science, Vol. 10, Issue 16 https://doi.org/10.1039/c9sc00174c	journal	January 2019
Single-atom catalysts for electrochemical clean energy conversion: recent progress and perspectives Li, Huining; Zhu, Han; Zhuang, Zechao Sustainable Energy & Fuels, Vol. 4, Issue 3 https://doi.org/10.1039/c9se01004a	journal	January 2020
1D/2D nitrogen-doped carbon nanorod arrays/ultrathin carbon nanosheets: outstanding catalysts for the highly efficient electroreduction of CO ₂ to CO Zhu, Ying; Lv, Kuilin; Wang, Xingpu Journal of Materials Chemistry A, Vol. 7, Issue 24 https://doi.org/10.1039/c9ta02353d	journal	January 2019
Emerging nanostructured carbon-based non-precious metal electrocatalysts for selective electrochemical CO ₂ reduction to CO Wang, Xinyue; Zhao, Qidong; Yang, Bin Journal of Materials Chemistry A, Vol. 7, Issue 44 https://doi.org/10.1039/c9ta09681g	journal	January 2019
A review of non-precious metal single atom confined nanomaterials in different structural dimensions (1D–3D) as highly active oxygen redox reaction electrocatalysts Liu, Jin; Zhang, Hao; Qiu, Ming Journal of Materials Chemistry A, Vol. 8, Issue 5 https://doi.org/10.1039/c9ta11852g	journal	January 2020
Effects of the Carbon Support Doping with Nitrogen for the Hydrogen Production from Formic Acid over Ni Catalysts Nishchakova, Alina D.; Bulushev, Dmitri A.; Stonkus, Olga A. Energies, Vol. 12, Issue 21 https://doi.org/10.3390/en12214111	journal	October 2019
Mesoporous Nitrogen‐Doped Carbon‐Nanosphere‐Supported Isolated Single‐Atom Pd Catalyst for Highly Efficient Semihydrogenation of Acetylene Feng, Quanchen; Zhao, Shu; Xu, Qi Advanced Materials, Vol. 31, Issue 36 https://doi.org/10.1002/adma.201901024	journal	June 2019
Metal and Nonmetal Codoped 3D Nanoporous Graphene for Efficient Bifunctional Electrocatalysis and Rechargeable Zn–Air Batteries Qiu, Hua‐Jun; Du, Peng; Hu, Kailong Advanced Materials, Vol. 33, Issue 14 https://doi.org/10.1002/adma.202101386	journal	April 2021
In Situ Thermal Atomization To Convert Supported Nickel Nanoparticles into Surface-Bound Nickel Single-Atom Catalysts Yang, Jian; Qiu, Zongyang; Zhao, Changming Angewandte Chemie International Edition, Vol. 57, Issue 43 https://doi.org/10.1002/anie.201808049	journal	October 2018
Carbon‐Rich Nonprecious Metal Single Atom Electrocatalysts for CO ₂ Reduction and Hydrogen Evolution Wang, Tingting; Zhao, Qidong; Fu, Yuanyuan Small Methods, Vol. 3, Issue 10 https://doi.org/10.1002/smtd.201900210	journal	May 2019
Carbon dioxide electroreduction on single-atom nickel decorated carbon membranes with industry compatible current densities Yang, Hengpan; Lin, Qing; Zhang, Chao Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14402-0	journal	January 2020

Figures / Tables (4)

Similar Records

One-Pot Pyrolysis Method to Fabricate Carbon Nanotube Supported Ni Single-Atom Catalysts with Ultrahigh Loading

Journal Article · Mon Sep 10 00:00:00 EDT 2018 · ACS Applied Energy Materials · OSTI ID:1846560

Zhao, Shiyong; Cheng, Yi; Veder, Jean-Pierre; +9 more

Controlled One‐pot Synthesis of Nickel Single Atoms Embedded in Carbon Nanotube and Graphene Supports with High Loading

Journal Article · Wed Apr 29 00:00:00 EDT 2020 · ChemNanoMat · OSTI ID:1846560

Zhao, Shiyong; Wang, Tianshuai; Zhou, Guangmin; +11 more

Single-Atom Catalysts for Selective Oxygen Reduction: Transition Metals in Uniform Carbon Nanospheres with High Loadings

Journal Article · Thu Oct 19 00:00:00 EDT 2023 · JACS Au · OSTI ID:1846560

Jeskey, Jacob; Ding, Yong; Chen, Yidan; +4 more

Related Subjects

36 MATERIALS SCIENCE
single-atom catalyst
carbon dioxide reduction
carbon monoxide
transition metals
Chemistry
Science & Technology - Other Topics
Materials Science
Physics