Design of an additively manufactured functionally graded material of 316 stainless steel and Ti-6Al-4V with Ni-20Cr, Cr, and V intermediate compositions

Bobbio, Lourdes D.; Bocklund, Brandon; Simsek, Emrah; Ott, Ryan T.; Kramer, Matt J.; Liu, Zi-Kui; Beese, Allison M.

doi:10.1016/j.addma.2022.102649

Design of an additively manufactured functionally graded material of 316 stainless steel and Ti-6Al-4V with Ni-20Cr, Cr, and V intermediate compositions

Journal Article · Tue Feb 01 00:00:00 EST 2022 · Additive Manufacturing

DOI:https://doi.org/10.1016/j.addma.2022.102649· OSTI ID:1846443

Bobbio, Lourdes D. ^[1]; Bocklund, Brandon ^[1]; Simsek, Emrah ^[2]; Ott, Ryan T. ^[2]; Kramer, Matt J. ^[2]; Liu, Zi-Kui ^[1]; Beese, Allison M. ^[1]

Pennsylvania State Univ., University Park, PA (United States)
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)

This study presents a method for designing a computationally informed gradient pathway to fabricate a functionally graded material (FGM) with terminal alloys of 316 stainless steel (SS316) and Ti-6Al-4V via directed energy deposition additive manufacturing with powder feedstock. In this work, the grading is accomplished through the introduction of intermediate elements and alloys (Ni-20Cr, Cr, and V) to avoid the brittle Fe-Ti intermetallic phases that form in the direct liquid phase joining of Ti-alloys and stainless steels. Using a combination of equilibrium calculations and Scheil-Gulliver simulations, a compositional pathway was designed to avoid deleterious phases. FGM samples were fabricated and experimentally characterized to determine the viability of the pathway. A change in phases from fcc to bcc was predicted to occur within the Ni-20Cr/Cr gradient region, and this was validated through experimental characterization. No detrimental phases (intermetallic, Laves, or σ phases) formed along the gradient path, demonstrating a successful computationally-informed design and fabrication of an FGM from SS316 to Ti-6Al-4V.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: National Aeronautics and Space Administration (NASA); National Science Foundation (NSF); USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1846443

Alternate ID(s):: OSTI ID: 1843875

Report Number(s):: IS-J-10,716; 90NSSC18K1168; DGE-1449785

Journal Information:: Additive Manufacturing, Journal Name: Additive Manufacturing Vol. 51; ISSN 2214-8604

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (42)

Functionally Graded Alloys Obtained by Additive Manufacturing: Functionally Graded Alloys Obtained by Additive Manufacturing Niendorf, Thomas; Leuders, Stefan; Riemer, Andre Advanced Engineering Materials, Vol. 16, Issue 7 https://doi.org/10.1002/adem.201300579	journal	March 2014
The Cr−V (Chromium-Vanadium) system Smith, J. F.; Bailey, D. M.; Carlson, O. N. Journal of Phase Equilibria, Vol. 2, Issue 4 https://doi.org/10.1007/BF02876166	journal	March 1982
Interfacial properties of diffusion bonded Ti-6Al-4V to AISI 304 stainless steel by inserting a Cu interlayer Özdemir, N.; Bilgin, B. The International Journal of Advanced Manufacturing Technology, Vol. 41, Issue 5-6 https://doi.org/10.1007/s00170-008-1493-6	journal	April 2008
First-Principles Calculations and CALPHAD Modeling of Thermodynamics Liu, Zi-Kui Journal of Phase Equilibria and Diffusion, Vol. 30, Issue 5 https://doi.org/10.1007/s11669-009-9570-6	journal	September 2009
Thermodynamic Assessments of the Ni-Cr-Ti System and Atomic Mobility of Its fcc Phase Huang, Jinwan; Wang, Yang; Wang, Jingjing Journal of Phase Equilibria and Diffusion, Vol. 39, Issue 5 https://doi.org/10.1007/s11669-018-0650-3	journal	June 2018
Interdiffusion studies in titanium–304 stainless steel system Kale, G. B.; Patil, R. V.; Gawade, P. S. Journal of Nuclear Materials, Vol. 257, Issue 1 https://doi.org/10.1016/S0022-3115(98)00179-2	journal	September 1998
Thermodynamic reassessment of Fe-Cr-Ni system with emphasis on the iron-rich corner Miettinen, Jyrki Calphad, Vol. 23, Issue 2 https://doi.org/10.1016/S0364-5916(99)00027-9	journal	June 1999
Diffusion bonded transition joints of titanium to stainless steel with improved properties Ghosh, M.; Chatterjee, S. Materials Science and Engineering: A, Vol. 358, Issue 1-2 https://doi.org/10.1016/S0921-5093(03)00298-3	journal	October 2003
The effect of intermetallics on the strength properties of diffusion bonds formed between Ti–5.5Al–2.4V and 304 stainless steel Ghosh, M.; Chatterjee, S.; Mishra, B. Materials Science and Engineering: A, Vol. 363, Issue 1-2 https://doi.org/10.1016/S0921-5093(03)00649-X	journal	December 2003
The compound energy formalism Hillert, Mats Journal of Alloys and Compounds, Vol. 320, Issue 2 https://doi.org/10.1016/S0925-8388(00)01481-X	journal	May 2001
Characterization of transition joints of commercially pure titanium to 304 stainless steel Ghosh, M.; Chatterjee, S. Materials Characterization, Vol. 48, Issue 5 https://doi.org/10.1016/S1044-5803(02)00306-6	journal	July 2002
Additive manufacturing of a functionally graded material from Ti-6Al-4V to Invar: Experimental characterization and thermodynamic calculations Bobbio, Lourdes D.; Otis, Richard A.; Borgonia, John Paul Acta Materialia, Vol. 127 https://doi.org/10.1016/j.actamat.2016.12.070	journal	April 2017
Modeling of Ni–Cr–Mo based alloys: Part II — Kinetics Turchi, P. E. A.; Kaufman, L.; Liu, Zi-Kui Calphad, Vol. 31, Issue 2 https://doi.org/10.1016/j.calphad.2006.12.006	journal	June 2007
Thermodynamic modeling and optimization of the Fe–Ni–Ti system De Keyzer, Jozefien; Cacciamani, Gabriele; Dupin, Nathalie Calphad, Vol. 33, Issue 1 https://doi.org/10.1016/j.calphad.2008.10.003	journal	March 2009
Thermodynamic modeling of the Fe–Ti–V system Guo, Cuiping; Li, Changrong; Zheng, Xiang Calphad, Vol. 38 https://doi.org/10.1016/j.calphad.2012.06.010	journal	September 2012
Experimental investigation and thermodynamic calculation of the phase equilibria in the Fe–Ni–V system Zhao, C. C.; Yang, S. Y.; Lu, Y. Calphad, Vol. 46 https://doi.org/10.1016/j.calphad.2014.02.004	journal	September 2014
Thermodynamic modeling of Ti-Fe-Cr ternary system Wang, Shusen; Wang, Kun; Chen, Guangyao Calphad, Vol. 56 https://doi.org/10.1016/j.calphad.2016.12.007	journal	March 2017
Experimental investigation and thermodynamic modeling of the Ni–Ti–V system Zou, Lei; Guo, Cuiping; Li, Changrong Calphad, Vol. 64 https://doi.org/10.1016/j.calphad.2018.11.006	journal	March 2019
Characterization of a functionally graded material of Ti-6Al-4V to 304L stainless steel with an intermediate V section Bobbio, Lourdes D.; Bocklund, Brandon; Otis, Richard Journal of Alloys and Compounds, Vol. 742 https://doi.org/10.1016/j.jallcom.2018.01.156	journal	April 2018
Analysis of formation and growth of the σ phase in additively manufactured functionally graded materials Bobbio, Lourdes D.; Bocklund, Brandon; Reichardt, Ashley Journal of Alloys and Compounds, Vol. 814 https://doi.org/10.1016/j.jallcom.2019.151729	journal	January 2020
Joining of titanium to 304L stainless steel by friction welding Dey, H. C.; Ashfaq, M.; Bhaduri, A. K. Journal of Materials Processing Technology, Vol. 209, Issue 18-19 https://doi.org/10.1016/j.jmatprotec.2009.06.018	journal	September 2009
Kinetics of σ-phase formation in equiatomic cold-rolled Fe–V alloys Costa, B. F. O.; Cieslak, J.; Dubiel, S. M. Materials Chemistry and Physics, Vol. 143, Issue 1 https://doi.org/10.1016/j.matchemphys.2013.07.020	journal	December 2013
Interface microstructure and strength properties of Ti–6Al–4V and microduplex stainless steel diffusion bonded joints Kundu, S.; Sam, S.; Chatterjee, S. Materials & Design, Vol. 32, Issue 5 https://doi.org/10.1016/j.matdes.2010.12.052	journal	May 2011
Development and characterization of Ti-6Al-4V to 304L stainless steel gradient components fabricated with laser deposition additive manufacturing Reichardt, Ashley; Dillon, R. Peter; Borgonia, John Paul Materials & Design, Vol. 104 https://doi.org/10.1016/j.matdes.2016.05.016	journal	August 2016
Functionally Graded Materials through robotics-inspired path planning Eliseeva, O. V.; Kirk, T.; Samimi, P. Materials & Design, Vol. 182 https://doi.org/10.1016/j.matdes.2019.107975	journal	November 2019
Nd:YAG pulsed laser welding of TC4 Ti alloy to 301L stainless steel using Ta/V/Fe composite interlayer Zhang, Y.; Sun, D. Q.; Gu, X. Y. Materials Letters, Vol. 212 https://doi.org/10.1016/j.matlet.2017.10.057	journal	February 2018
Compositionally graded magnetic-nonmagnetic bimetallic structure using laser engineered net shaping Heer, Bryan; Bandyopadhyay, Amit Materials Letters, Vol. 216 https://doi.org/10.1016/j.matlet.2017.12.129	journal	April 2018
A functionally graded material from TC4 to 316L stainless steel fabricated by double-wire + arc additive manufacturing Chen, Xinya; Han, Jian; Wang, Jun Materials Letters, Vol. 300 https://doi.org/10.1016/j.matlet.2021.130141	journal	October 2021
Microstructural evolution and mechanical properties of laser beam welded joints between pure V and 17-4PH stainless steel Adomako, Nana Kwabena; Kim, Jeng O.; Kim, Jeoung Han Materials Science and Engineering: A, Vol. 753 https://doi.org/10.1016/j.msea.2019.03.036	journal	April 2019
Experimental validation of Scheil–Gulliver simulations for gradient path planning in additively manufactured functionally graded materials Bocklund, Brandon; Bobbio, Lourdes D.; Otis, Richard A. Materialia, Vol. 11 https://doi.org/10.1016/j.mtla.2020.100689	journal	June 2020
Tensile behavior of stainless steel 304L to Ni-20Cr functionally graded material: Experimental characterization and computational simulations Bobbio, Lourdes D.; Bocklund, Brandon; Liu, Zi-Kui Materialia, Vol. 18 https://doi.org/10.1016/j.mtla.2021.101151	journal	August 2021
Interlayer thickening for development of laser-welded Ti-SS joint strength Elmi Hosseini, Seyed Reza; Feng, Kai; Nie, Pulin Optics & Laser Technology, Vol. 112 https://doi.org/10.1016/j.optlastec.2018.11.022	journal	April 2019
Effect of bonding time on interfacial microstructure and shear strength of vacuum diffusion bonding super-Ni/NiCr laminated composite to Ti-6Al-4V joint without interlayer Liu, Kun; Li, Yajiang; Xia, Chunzhi Vacuum, Vol. 143 https://doi.org/10.1016/j.vacuum.2017.06.025	journal	September 2017
Developing Gradient Metal Alloys through Radial Deposition Additive Manufacturing Hofmann, Douglas C.; Roberts, Scott; Otis, Richard Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep05357	journal	June 2014
Sigma-Phase in Fe-Cr and Fe-V Alloy Systems and its Physical Properties Dubiel, Stanisław M.; Cieślak, Jakub Critical Reviews in Solid State and Materials Sciences, Vol. 36, Issue 4 https://doi.org/10.1080/10408436.2011.589232	journal	October 2011
Laser deposition additive manufacturing of 17-4PH stainless steel on Ti-6Al-4V using V interlayer Adomako, Nana Kwabena; Noh, Sanghoon; Oh, Chang-Seok Materials Research Letters, Vol. 7, Issue 7 https://doi.org/10.1080/21663831.2019.1596989	journal	March 2019
Computational Design of Gradient Paths in Additively Manufactured Functionally Graded Materials Kirk, Tanner; Galvan, Edgar; Malak, Richard Journal of Mechanical Design, Vol. 140, Issue 11 https://doi.org/10.1115/1.4040816	journal	September 2018
Thermodynamic and kinetic modeling of the Cr-Ti-V system Ghosh, G. Journal of Phase Equilibria, Vol. 23, Issue 4 https://doi.org/10.1361/105497102770331569	journal	August 2002
A Thermodynamic Evaluation of the Fe - Cr - V System / Eine thermodynamische Bewertung des Systems Fe-Cr-V Lee, Byeong-Joo International Journal of Materials Research, Vol. 83, Issue 5 https://doi.org/10.1515/ijmr-1992-830502	journal	May 1992
Chemically graded Fe–Al/steel samples fabricated by laser metal deposition Lotfian, Saeid; Rolink, Gesa; Weisheit, Andreas MRS Advances, Vol. 2, Issue 26 https://doi.org/10.1557/adv.2017.124	journal	January 2017
Intermetallics Synthesis in the Fe–Al System via Layer by Layer 3D Laser Cladding Shishkovsky, Igor; Missemer, Floran; Kakovkina, Nina Crystals, Vol. 3, Issue 4 https://doi.org/10.3390/cryst3040517	journal	October 2013
pycalphad: CALPHAD-based Computational Thermodynamics in Python Otis, Richard; Liu, Zi-Kui Journal of Open Research Software, Vol. 5 https://doi.org/10.5334/jors.140	journal	January 2017

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36 MATERIALS SCIENCE
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Design of an additively manufactured functionally graded material of 316 stainless steel and Ti-6Al-4V with Ni-20Cr, Cr, and V intermediate compositions

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