Investigation of Reactivities of Bimetallic Cu-Fe Oxygen Carriers with Coal in High Temperature In-situ Gasification Chemical-Looping Combustion (iG-CLC) and Chemical-Looping with Oxygen Uncoupling (CLOU) Using a Fixed Bed Reactor

Wang, Ping; Howard, Bret; Means, Nicholas C.

doi:10.1016/j.fuel.2020.119012

Title: Investigation of Reactivities of Bimetallic Cu-Fe Oxygen Carriers with Coal in High Temperature In-situ Gasification Chemical-Looping Combustion (iG-CLC) and Chemical-Looping with Oxygen Uncoupling (CLOU) Using a Fixed Bed Reactor

Journal Article · 15 February 2022 · Fuel

DOI:https://doi.org/10.1016/j.fuel.2020.119012· OSTI ID:1846386

Wang, Ping ^[1]; Howard, Bret ^[1]; Means, Nicholas C.

NETL

This study investigated reduction reactivities and CO2 conversion efficiency of synthesized Fe-Cu-Si OCs for both in-situ gasification CLC (iG-CLC) and Chemical-Looping with Oxygen Uncoupling (CLOU) at high temperatures (950 to 1100°C) with varying ratios of OC to coal char (φ) using a fixed bed reactor-quadrupole mass spectrometer system.

View Journal Article

Cite

Export

Save

Research Organization:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

DOE Contract Number:: DE-FE0004000

OSTI ID:: 1846386

Journal Information:: Fuel, Vol. 285, Issue NA

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

References (34)

Investigation of Combined Supports for Cu-Based Oxygen Carriers for Chemical-Looping with Oxygen Uncoupling (CLOU) Adánez-Rubio, Iñaki; Arjmand, Mehdi; Leion, Henrik Energy & Fuels, Vol. 27, Issue 7 https://doi.org/10.1021/ef401161s	journal	June 2013
Copper-Decorated Hematite as an Oxygen Carrier for in Situ Gasification Chemical Looping Combustion of Coal Yang, Weijing; Zhao, Haibo; Ma, Jinchen Energy & Fuels, Vol. 28, Issue 6 https://doi.org/10.1021/ef5001584	journal	May 2014
Cement bonded fine hematite and copper ore particles as oxygen carrier in chemical looping combustion Tian, Xin; Zhao, Haibo; Ma, Jinchen Applied Energy, Vol. 204 https://doi.org/10.1016/j.apenergy.2017.07.025	journal	October 2017
Synergetic effects of mixed copper–iron oxides oxygen carriers in chemical looping combustion Siriwardane, Ranjani; Tian, Hanjing; Simonyi, Thomas Fuel, Vol. 108 https://doi.org/10.1016/j.fuel.2013.01.023	journal	June 2013
Development of Cu-based oxygen carriers for Chemical-Looping with Oxygen Uncoupling (CLOU) process Gayán, Pilar; Adánez-Rubio, Iñaki; Abad, Alberto Fuel, Vol. 96 https://doi.org/10.1016/j.fuel.2012.01.021	journal	June 2012
Progress in Chemical-Looping Combustion and Reforming technologies Adanez, Juan; Abad, Alberto; Garcia-Labiano, Francisco Progress in Energy and Combustion Science, Vol. 38, Issue 2, p. 215-282 https://doi.org/10.1016/j.pecs.2011.09.001	journal	April 2012
Chemical looping combustion of hard coal in a 1 MWth pilot plant using ilmenite as oxygen carrier Ströhle, Jochen; Orth, Matthias; Epple, Bernd Applied Energy, Vol. 157 https://doi.org/10.1016/j.apenergy.2015.06.035	journal	November 2015
Evaluation of a Spray-Dried CuO/MgAl ₂ O ₄ Oxygen Carrier for the Chemical Looping with Oxygen Uncoupling Process Adánez-Rubio, Iñaki; Gayán, Pilar; Abad, Alberto Energy & Fuels, Vol. 26, Issue 5 https://doi.org/10.1021/ef3002229	journal	December 2011
Coal Chemical-Looping with Oxygen Uncoupling (CLOU) Using a Cu-Based Oxygen Carrier Derived from Natural Minerals Wang, Ping; Howard, Bret; Means, Nicholas Energies, Vol. 12, Issue 8 https://doi.org/10.3390/en12081453	journal	April 2019
Chemical-Looping Combustion and Gasification of Coals and Oxygen Carrier Development: A Brief Review Wang, Ping; Means, Nicholas; Shekhawat, Dushyant Energies, Vol. 8, Issue 10 https://doi.org/10.3390/en81010605	journal	September 2015
Parametric and dynamic studies of an iron-based 25-kWth coal direct chemical looping unit using sub-bituminous coal Bayham, Samuel; McGiveron, Omar; Tong, Andrew Applied Energy, Vol. 145 https://doi.org/10.1016/j.apenergy.2015.02.026	journal	May 2015
CLC, a promising concept with challenging development issues Gauthier, T.; Yazdanpanah, M.; Forret, A. Powder Technology, Vol. 316 https://doi.org/10.1016/j.powtec.2017.01.003	journal	July 2017
Demonstration of chemical-looping with oxygen uncoupling (CLOU) process in a 1.5kWth continuously operating unit using a Cu-based oxygen-carrier Abad, Alberto; Adánez-Rubio, Iñaki; Gayán, Pilar International Journal of Greenhouse Gas Control, Vol. 6 https://doi.org/10.1016/j.ijggc.2011.10.016	journal	January 2012
Characterization of natural copper ore as oxygen carrier in chemical-looping with oxygen uncoupling of anthracite Zhao, Haibo; Wang, Kun; Fang, Yanfei International Journal of Greenhouse Gas Control, Vol. 22 https://doi.org/10.1016/j.ijggc.2013.12.023	journal	March 2014
Selection of Oxygen Carriers for Chemical-Looping Combustion Adánez, J.; de Diego, L. F.; García-Labiano, F. Energy & Fuels, Vol. 18, Issue 2, p. 371-377 https://doi.org/10.1021/ef0301452	journal	March 2004
Coal combustion with a spray granulated Cu-Mn mixed oxide for the Chemical Looping with Oxygen Uncoupling (CLOU) process Adánez-Rubio, Iñaki; Abad, Alberto; Gayán, Pilar Applied Energy, Vol. 208 https://doi.org/10.1016/j.apenergy.2017.09.098	journal	December 2017
The investigations of hematite-CuO oxygen carrier in chemical looping combustion Jiang, Shouxi; Shen, Laihong; Wu, Jian Chemical Engineering Journal, Vol. 317 https://doi.org/10.1016/j.cej.2017.01.091	journal	June 2017
Activities in the spinel solid solution, phase equilibria and thermodynamic properties of ternary phases in the system Cu-Fe-0 Jacob, K. T.; Fitzner, K.; Alcock, C. B. Metallurgical Transactions B, Vol. 8, Issue 2 https://doi.org/10.1007/BF02696932	journal	September 1977
Performance of CLOU process in the combustion of different types of coal with CO2 capture Adánez-Rubio, I.; Abad, A.; Gayán, P. International Journal of Greenhouse Gas Control, Vol. 12 https://doi.org/10.1016/j.ijggc.2012.11.025	journal	January 2013
Reduction of hematite (Fe 2 O 3 ) to metallic iron (Fe) by CO in a micro fluidized bed reaction analyzer: A multistep kinetics study Chen, Hongsheng; Zheng, Zhong; Chen, Zhiwei Powder Technology, Vol. 316 https://doi.org/10.1016/j.powtec.2017.02.067	journal	July 2017
Ferritization of copper ions in the Cu–Fe–O system Ristić, M.; Hannoyer, B.; Popović, S. Materials Science and Engineering: B, Vol. 77, Issue 1 https://doi.org/10.1016/S0921-5107(00)00474-8	journal	August 2000
Investigation of Chemical Looping Combustion of Coal with CuFe₂O₄ Oxygen Carrier Wang, Baowen; Yan, Rong; Zhao, Haibo Energy & Fuels, Vol. 25, Issue 7, p. 3344-3354 https://doi.org/10.1021/ef2004078	journal	July 2011
Thermodynamic Assessment of the Cu-Fe-O System Khvan, Alexnadra V.; Fabrichnaya, Olga B.; Savinykh, Galina Journal of Phase Equilibria and Diffusion, Vol. 32, Issue 6 https://doi.org/10.1007/s11669-011-9951-5	journal	September 2011
Chemical-looping combustion: Status and research needs Adánez, Juan; Abad, Alberto Proceedings of the Combustion Institute, Vol. 37, Issue 4 https://doi.org/10.1016/j.proci.2018.09.002	journal	January 2019
Chemical-looping with oxygen uncoupling for combustion of solid fuels Mattisson, Tobias; Lyngfelt, Anders; Leion, Henrik International Journal of Greenhouse Gas Control, Vol. 3, Issue 1, p. 11-19 https://doi.org/10.1016/j.ijggc.2008.06.002	journal	January 2009
Sulphur, nitrogen and mercury emissions from coal combustion with CO2 capture in chemical looping with oxygen uncoupling (CLOU) Pérez-Vega, Raúl; Adánez-Rubio, Iñaki; Gayán, Pilar International Journal of Greenhouse Gas Control, Vol. 46 https://doi.org/10.1016/j.ijggc.2015.12.034	journal	March 2016
Evaluation of iron- and manganese-based mono- and mixed-metallic oxygen carriers for chemical looping combustion Bhavsar, Saurabh; Tackett, Brian; Veser, Götz Fuel, Vol. 136 https://doi.org/10.1016/j.fuel.2014.07.068	journal	November 2014
Development and performance of Cu-based oxygen carriers for chemical-looping combustion Chuang, S.; Dennis, J.; Hayhurst, A. Combustion and Flame, Vol. 154, Issue 1-2 https://doi.org/10.1016/j.combustflame.2007.10.005	journal	July 2008
Thermal Analysis of Chemical-Looping Combustion Jerndal, E.; Mattisson, T.; Lyngfelt, A. Chemical Engineering Research and Design, Vol. 84, Issue 9 https://doi.org/10.1205/cherd05020	journal	September 2006
Chemical looping combustion of solid fuels Adánez, J.; Abad, A.; Mendiara, T. Progress in Energy and Combustion Science, Vol. 65 https://doi.org/10.1016/j.pecs.2017.07.005	journal	March 2018
The reactivity of CuO oxygen carrier and coal in Chemical-Looping with Oxygen Uncoupled (CLOU) and In-situ Gasification Chemical-Looping Combustion (iG-CLC) Wang, Ping; Means, Nicholas; Howard, Bret H. Fuel, Vol. 217 https://doi.org/10.1016/j.fuel.2017.12.102	journal	April 2018
Design and operation of a 1 MWth chemical looping plant Ströhle, Jochen; Orth, Matthias; Epple, Bernd Applied Energy, Vol. 113 https://doi.org/10.1016/j.apenergy.2013.09.008	journal	January 2014
Chemical looping combustion of hard coal and torrefied biomass in a 1 MW th pilot plant Ohlemüller, Peter; Ströhle, Jochen; Epple, Bernd International Journal of Greenhouse Gas Control, Vol. 65 https://doi.org/10.1016/j.ijggc.2017.08.013	journal	October 2017
Iron-based syngas chemical looping process and coal-direct chemical looping process development at Ohio State University Tong, Andrew; Bayham, Samuel; Kathe, Mandar V. Applied Energy, Vol. 113 https://doi.org/10.1016/j.apenergy.2013.05.024	journal	January 2014

Similar Records

Coal Chemical-Looping with Oxygen Uncoupling (CLOU) Using a Cu-Based Oxygen Carrier Derived from Natural Minerals

Journal Article · 2019 · Energies (Basel) · OSTI ID:1846386

Wang, Ping; Howard, Bret; Means, Nicholas; +2 more

Conversion of Coal in a Fluidized Bed Chemical Looping Reactor with and without Oxygen Uncoupling

Conference · 2018 · OSTI ID:1846386

Merrett, Kirsten M.; Whitty, Kevin J.

Examining and Modeling Oxygen Uncoupling Kinetics of Cu-Based Oxygen Carriers for Chemical Looping with Oxygen Uncoupling (CLOU) in a Drop Tube Fluidized Bed Reactor

Journal Article · 2019 · Energy and Fuels · OSTI ID:1846386

Means, Nicholas C.; Burgess, Ward A.; Howard, Bret H.; +3 more

Title: Investigation of Reactivities of Bimetallic Cu-Fe Oxygen Carriers with Coal in High Temperature In-situ Gasification Chemical-Looping Combustion (iG-CLC) and Chemical-Looping with Oxygen Uncoupling (CLOU) Using a Fixed Bed Reactor

Citation Formats

References (34)

Similar Records

Related Subjects