The magnetic order in multiferroic DyMnO3

Lee, Jenn-Min; Huang, Shih-Wen; Jeng, Horng-Tay; Shao, Yu-Cheng; Wray, L. Andrew; Chen, Jin Ming; Qiao, Ruimin; Yang, Wanli; Lin, Jiunn-Yuan; Schoenlein, Robert W.; Chuang, Yi-De

doi:10.1016/j.elspec.2020.147013

The magnetic order in multiferroic DyMnO₃

Journal Article · Tue Nov 10 04:00:00 EST 2020 · Journal of Electron Spectroscopy and Related Phenomena

DOI:https://doi.org/10.1016/j.elspec.2020.147013· OSTI ID:1844372

Lee, Jenn-Min ^[1]; Huang, Shih-Wen ^[2]; Jeng, Horng-Tay ^[3]; Shao, Yu-Cheng ^[4]; Wray, L. Andrew ^[5]; Chen, Jin Ming ^[6]; Qiao, Ruimin ^[7]; Yang, Wanli ^[7]; Lin, Jiunn-Yuan ^[8]; Schoenlein, Robert W. ^[7]; Chuang, Yi-De ^[7]

Lund Univ. (Sweden); National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
Lund Univ. (Sweden); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
National Tsing Hua Univ., Hsinchu (Taiwan)
Tamkang Univ., Taipei (Taiwan); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
New York Univ. (NYU), NY (United States)
National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
National Chiao Tung Univ., Hsinchu (Taiwan)

We report that with flexibility in tuning their electric and magnetic properties, multiferroics can be used in information exchange and storage in ways that are very different from the present electronic materials. Here we use resonant soft X-ray scattering spectroscopy to study the F-type (0,τ,0) and C-type (0, 1–2τ, 0) diffraction peaks from sinusoidal antiferromagnetic spin order in multiferroic DyMnO₃. By comparing the temperature dependence of ordering wave vectors τ, peak intensities I, and correlation lengths λ measured at Mn L_2^-, O K-, and Dy M₅-edges, we show that the nearly perfect locking between the ordering wave vectors from Dy 4f states and Mn 3d orbitals manifesting the second harmonic diffraction peak implies the notable orbital involvement in the coupling between Mn and Dy spins. Our DFT calculations further suggest that the lattice response to different antiferromagnetic ground states (A-type versus E-type) is much weaker in TbMnO₃, in agreement with previous claim that the symmetric exchange interaction can be an important factor for understanding the ferroelectricity in DyMnO₃ than in TbMnO₃.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); MOST of Taiwan

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1844372

Alternate ID(s):: OSTI ID: 1874398

Journal Information:: Journal of Electron Spectroscopy and Related Phenomena, Journal Name: Journal of Electron Spectroscopy and Related Phenomena Vol. 246; ISSN 0368-2048

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (57)

Multiferroics with Spiral Spin Orders Tokura, Yoshinori; Seki, Shinichiro Advanced Materials, Vol. 22, Issue 14 https://doi.org/10.1002/adma.200901961	journal	December 2009
Emerging routes to multiferroics Ramesh, Ramamoorthy Nature, Vol. 461, Issue 7268 https://doi.org/10.1038/4611218a	journal	October 2009
Magnetic control of ferroelectric polarization Kimura, T.; Goto, T.; Shintani, H. Nature, Vol. 426, Issue 6962 https://doi.org/10.1038/nature02018	journal	November 2003
Electric polarization reversal and memory in a multiferroic material induced by magnetic fields Hur, N.; Park, S.; Sharma, P. A. Nature, Vol. 429, Issue 6990 https://doi.org/10.1038/nature02572	journal	May 2004
Multiferroic and magnetoelectric materials Eerenstein, W.; Mathur, N. D.; Scott, J. F. Nature, Vol. 442, Issue 7104 https://doi.org/10.1038/nature05023	journal	August 2006
Bond- versus site-centred ordering and possible ferroelectricity in manganites Efremov, Dmitry V.; van den Brink, Jeroen; Khomskii, Daniel I. Nature Materials, Vol. 3, Issue 12 https://doi.org/10.1038/nmat1236	journal	November 2004
Multiferroics: a magnetic twist for ferroelectricity Cheong, Sang-Wook; Mostovoy, Maxim Nature Materials, Vol. 6, Issue 1 https://doi.org/10.1038/nmat1804	journal	January 2007
New routes to multiferroics Rao, C. N. R.; Serrao, Claudy Rayan Journal of Materials Chemistry, Vol. 17, Issue 47 https://doi.org/10.1039/b709126e	journal	January 2007
Resonant x-ray emission spectroscopy of multiferroic TbMnO3 Chen, J. M.; Chen, C. K.; Chou, T. L. Applied Physics Letters, Vol. 91, Issue 5 https://doi.org/10.1063/1.2762288	journal	July 2007
Development of a compact fast CCD camera and resonant soft x-ray scattering endstation for time-resolved pump-probe experiments Doering, D.; Chuang, Y. -D.; Andresen, N. Review of Scientific Instruments, Vol. 82, Issue 7 https://doi.org/10.1063/1.3609862	journal	July 2011
Multiferroics of spin origin Tokura, Yoshinori; Seki, Shinichiro; Nagaosa, Naoto Reports on Progress in Physics, Vol. 77, Issue 7 https://doi.org/10.1088/0034-4885/77/7/076501	journal	July 2014
Effect of ionic size on the orbital ordering transition in RMnO _3+δ Maris, G.; Volotchaev, V.; Palstra, T. T. M. New Journal of Physics, Vol. 6 https://doi.org/10.1088/1367-2630/6/1/153	journal	January 2004
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Distorted perovskite with e g 1 configuration as a frustrated spin system Kimura, T.; Ishihara, S.; Shintani, H. Physical Review B, Vol. 68, Issue 6 https://doi.org/10.1103/PhysRevB.68.060403	journal	August 2003
Magnetoelectric phase diagrams of orthorhombic R MnO 3 ( R = Gd , Tb, and Dy) Kimura, T.; Lawes, G.; Goto, T. Physical Review B, Vol. 71, Issue 22 https://doi.org/10.1103/PhysRevB.71.224425	journal	June 2005
Magnetic-field-induced transition in the lattice modulation of colossal magnetoelectric Gd Mn O 3 and Tb Mn O 3 compounds Arima, T.; Goto, T.; Yamasaki, Y. Physical Review B, Vol. 72, Issue 10 https://doi.org/10.1103/PhysRevB.72.100102	journal	September 2005
Field-induced linear magnetoelastic coupling in multiferroic TbMnO 3 Aliouane, N.; Argyriou, D. N.; Strempfer, J. Physical Review B, Vol. 73, Issue 2 https://doi.org/10.1103/PhysRevB.73.020102	journal	January 2006
Role of the Dzyaloshinskii-Moriya interaction in multiferroic perovskites Sergienko, I. A.; Dagotto, E. Physical Review B, Vol. 73, Issue 9 https://doi.org/10.1103/PhysRevB.73.094434	journal	March 2006
Commensurate Dy magnetic ordering associated with incommensurate lattice distortion in multiferroic DyMnO 3 Feyerherm, R.; Dudzik, E.; Aliouane, N. Physical Review B, Vol. 73, Issue 18 https://doi.org/10.1103/PhysRevB.73.180401	journal	May 2006
Melting of incommensurate-ferroelectric phase with magnetic field in multiferroic TbMnO 3 Argyriou, D. N.; Aliouane, N.; Strempfer, J. Physical Review B, Vol. 75, Issue 2 https://doi.org/10.1103/PhysRevB.75.020101	journal	January 2007
Absence of commensurate ordering at the polarization flop transition in multiferroic Dy Mn O 3 Strempfer, J.; Bohnenbuck, B.; Mostovoy, M. Physical Review B, Vol. 75, Issue 21 https://doi.org/10.1103/PhysRevB.75.212402	journal	June 2007
Strong coupling between the spin polarization of Mn and Tb in multiferroic Tb Mn O 3 determined by x-ray resonance exchange scattering Voigt, J.; Persson, J.; Kim, J. W. Physical Review B, Vol. 76, Issue 10 https://doi.org/10.1103/PhysRevB.76.104431	journal	September 2007
Microscopic theory of spin-polarization coupling in multiferroic transition metal oxides Jia, Chenglong; Onoda, Shigeki; Nagaosa, Naoto Physical Review B, Vol. 76, Issue 14 https://doi.org/10.1103/PhysRevB.76.144424	journal	October 2007
X-ray resonant diffraction study of multiferroic Dy Mn 2 O 5 Ewings, R. A.; Boothroyd, A. T.; McMorrow, D. F. Physical Review B, Vol. 77, Issue 10 https://doi.org/10.1103/PhysRevB.77.104415	journal	March 2008
Magnetic-field-induced transitions in multiferroic TbMnO 3 probed by resonant and nonresonant x-ray diffraction Strempfer, J.; Bohnenbuck, B.; Zegkinoglou, I. Physical Review B, Vol. 78, Issue 2 https://doi.org/10.1103/PhysRevB.78.024429	journal	July 2008
Origin of multiferroic spiral spin order in the R MnO 3 perovskites Dong, Shuai; Yu, Rong; Yunoki, Seiji Physical Review B, Vol. 78, Issue 15 https://doi.org/10.1103/PhysRevB.78.155121	journal	October 2008
Magnetic-field induced effects on the electric polarization in R MnO 3 ( R = Dy , Gd ) Feyerherm, R.; Dudzik, E.; Wolter, A. U. B. Physical Review B, Vol. 79, Issue 13 https://doi.org/10.1103/PhysRevB.79.134426	journal	April 2009
Nearest and next-nearest superexchange interactions in orthorhombic perovskite manganites R MnO 3 ( R = rare earth) Kim, Beom Hyun; Min, B. I. Physical Review B, Vol. 80, Issue 6 https://doi.org/10.1103/PhysRevB.80.064416	journal	August 2009
Microscopic model and phase diagrams of the multiferroic perovskite manganites Mochizuki, Masahito; Furukawa, Nobuo Physical Review B, Vol. 80, Issue 13 https://doi.org/10.1103/PhysRevB.80.134416	journal	October 2009
Perovskite manganites hosting versatile multiferroic phases with symmetric and antisymmetric exchange strictions Ishiwata, Shintaro; Kaneko, Yoshio; Tokunaga, Yusuke Physical Review B, Vol. 81, Issue 10 https://doi.org/10.1103/PhysRevB.81.100411	journal	March 2010
Magnetic order of multiferroic ErMn 2 O 5 studied by resonant soft x-ray Bragg diffraction Staub, U.; Bodenthin, Y.; García-Fernández, M. Physical Review B, Vol. 81, Issue 14 https://doi.org/10.1103/PhysRevB.81.144401	journal	April 2010
Strong orbital polarization in orthorhombic DyMnO 3 : A combined x-ray linear dichroism and ab initio electronic structure study Chen, J. M.; Hu, Z.; Jeng, H. T. Physical Review B, Vol. 81, Issue 20 https://doi.org/10.1103/PhysRevB.81.201102	journal	May 2010
Landau model for the phase diagrams of the orthorhombic rare-earth manganites R MnO 3 ( R = Eu , Gd, Tb, Dy, Ho) Ribeiro, J. L.; Vieira, L. G. Physical Review B, Vol. 82, Issue 6 https://doi.org/10.1103/PhysRevB.82.064410	journal	August 2010
Effect of Jahn-Teller distortion on magnetic ordering in Dy(Fe,Mn)O 3 perovskites Chiang, F. -K.; Chu, M. -W.; Chou, F. C. Physical Review B, Vol. 83, Issue 24 https://doi.org/10.1103/PhysRevB.83.245105	journal	June 2011
Theory of spin-phonon coupling in multiferroic manganese perovskites R MnO 3 Mochizuki, Masahito; Furukawa, Nobuo; Nagaosa, Naoto Physical Review B, Vol. 84, Issue 14 https://doi.org/10.1103/PhysRevB.84.144409	journal	October 2011
Prominent role of oxygen in the multiferroicity of DyMnO 3 and TbMnO 3 : A resonant soft x-ray scattering spectroscopy study Huang, S. W.; Lee, J. M.; Jeng, Horng-Tay Physical Review B, Vol. 94, Issue 3 https://doi.org/10.1103/PhysRevB.94.035145	journal	July 2016
Striped Multiferroic Phase in Double-Exchange Model for Quarter-Doped Manganites Dong, Shuai; Yu, Rong; Liu, J. -M. Physical Review Letters, Vol. 103, Issue 10 https://doi.org/10.1103/PhysRevLett.103.107204	journal	September 2009
Nature of the Magnetic Order and Origin of Induced Ferroelectricity in TbMnO 3 Wilkins, S. B.; Forrest, T. R.; Beale, T. A. W. Physical Review Letters, Vol. 103, Issue 20 https://doi.org/10.1103/PhysRevLett.103.207602	journal	November 2009
Spin Model of Magnetostrictions in Multiferroic Mn Perovskites Mochizuki, Masahito; Furukawa, Nobuo; Nagaosa, Naoto Physical Review Letters, Vol. 105, Issue 3 https://doi.org/10.1103/PhysRevLett.105.037205	journal	July 2010
Antiferromagnetically Spin Polarized Oxygen Observed in Magnetoelectric TbMn 2 O 5 Beale, T. A. W.; Wilkins, S. B.; Johnson, R. D. Physical Review Letters, Vol. 105, Issue 8 https://doi.org/10.1103/PhysRevLett.105.087203	journal	August 2010
Cycloidal Order of 4 f Moments as a Probe of Chiral Domains in DyMnO 3 Schierle, E.; Soltwisch, V.; Schmitz, D. Physical Review Letters, Vol. 105, Issue 16 https://doi.org/10.1103/PhysRevLett.105.167207	journal	October 2010
Theory of Magnetic Switching of Ferroelectricity in Spiral Magnets Mochizuki, Masahito; Furukawa, Nobuo Physical Review Letters, Vol. 105, Issue 18 https://doi.org/10.1103/PhysRevLett.105.187601	journal	October 2010
Ferroelectricity and Giant Magnetocapacitance in Perovskite Rare-Earth Manganites Goto, T.; Kimura, T.; Lawes, G. Physical Review Letters, Vol. 92, Issue 25 https://doi.org/10.1103/PhysRevLett.92.257201	journal	June 2004
Spin Current and Magnetoelectric Effect in Noncollinear Magnets Katsura, Hosho; Nagaosa, Naoto; Balatsky, Alexander V. Physical Review Letters, Vol. 95, Issue 5 https://doi.org/10.1103/PhysRevLett.95.057205	journal	July 2005
Magnetic Inversion Symmetry Breaking and Ferroelectricity in TbMnO 3 Kenzelmann, M.; Harris, A. B.; Jonas, S. Physical Review Letters, Vol. 95, Issue 8 https://doi.org/10.1103/PhysRevLett.95.087206	journal	August 2005
Ferroelectricity in Spiral Magnets Mostovoy, Maxim Physical Review Letters, Vol. 96, Issue 6 https://doi.org/10.1103/PhysRevLett.96.067601	journal	February 2006
Collinear to Spiral Spin Transformation without Changing the Modulation Wavelength upon Ferroelectric Transition in Tb 1 − x Dy x MnO 3 Arima, T.; Tokunaga, A.; Goto, T. Physical Review Letters, Vol. 96, Issue 9 https://doi.org/10.1103/PhysRevLett.96.097202	journal	March 2006
Effect of Orbital Rotation and Mixing on the Optical Properties of Orthorhombic R MnO 3 ( R = La , Pr, Nd, Gd, and Tb) Kim, M. W.; Moon, S. J.; Jung, J. H. Physical Review Letters, Vol. 96, Issue 24 https://doi.org/10.1103/PhysRevLett.96.247205	journal	June 2006
Enhanced Ferroelectric Polarization by Induced Dy Spin Order in Multiferroic DyMnO 3 Prokhnenko, O.; Feyerherm, R.; Dudzik, E. Physical Review Letters, Vol. 98, Issue 5 https://doi.org/10.1103/PhysRevLett.98.057206	journal	February 2007
Electric Control of Spin Helicity in a Magnetic Ferroelectric Yamasaki, Y.; Sagayama, H.; Goto, T. Physical Review Letters, Vol. 98, Issue 14 https://doi.org/10.1103/PhysRevLett.98.147204	journal	April 2007
Multiferroicity Induced by Dislocated Spin-Density Waves Betouras, Joseph J.; Giovannetti, Gianluca; van den Brink, Jeroen Physical Review Letters, Vol. 98, Issue 25 https://doi.org/10.1103/PhysRevLett.98.257602	journal	June 2007
Coupling of Frustrated Ising Spins to the Magnetic Cycloid in Multiferroic TbMnO 3 Prokhnenko, O.; Feyerherm, R.; Mostovoy, M. Physical Review Letters, Vol. 99, Issue 17 https://doi.org/10.1103/PhysRevLett.99.177206	journal	October 2007
Dual Nature of Improper Ferroelectricity in a Magnetoelectric Multiferroic Picozzi, S.; Yamauchi, K.; Sanyal, B. Physical Review Letters, Vol. 99, Issue 22 https://doi.org/10.1103/PhysRevLett.99.227201	journal	November 2007
MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics Spaldin, N. A. Science, Vol. 309, Issue 5733 https://doi.org/10.1126/science.1113357	journal	July 2005
Applications of Modern Ferroelectrics Scott, J. F. Science, Vol. 315, Issue 5814 https://doi.org/10.1126/science.1129564	journal	February 2007
Spiral Magnets as Magnetoelectrics Kimura, T. Annual Review of Materials Research, Vol. 37, Issue 1 https://doi.org/10.1146/annurev.matsci.37.052506.084259	journal	August 2007

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