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Detecting ionizing radiation using halide perovskite semiconductors processed through solution and alternative methods

Journal Article · · Nature Photonics
 [1];  [2];  [3]
  1. Soochow University, Suzhou (China); Northwestern University, Evanston, IL (United States)
  2. Hebrew University of Jerusalem (Israel)
  3. Northwestern University, Evanston, IL (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

We report the direct detection of high-energy radiation such as X-rays and.-rays by semiconductors at room temperature is a challenging proposition that requires remarkably pure and nearly perfect crystals. The emergence of metal halide perovskites, defect-tolerant semiconductors, is reviving hope for new materials in this field after an almost 20 year hiatus. Metal halide perovskites, which combine exceptional optoelectronic properties, versatile chemistry and simple synthesis, are challenging traditional approaches for the development of novel semiconductors for detecting hard radiation. We discuss the relevant physical properties, promising materials, fabrication techniques and device architectures for high-performance, low-cost detectors by targeting next-generation semiconductors for radiation detection. We also present a perspective on the impact of such advances in future medical imaging applications.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
Soochow University; Defense Threat Reduction Agency (DTRA); State Key Laboratory of Radiation Medicine and Protection
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1844345
Journal Information:
Nature Photonics, Journal Name: Nature Photonics Journal Issue: 1 Vol. 16; ISSN 1749-4885
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

References (106)

Experimental evaluation of the GE NM/CT 870 CZT clinical SPECT system equipped with WEHR and MEHRS collimator journal January 2021
High‐Quality Cuboid CH 3 NH 3 PbI 3 Single Crystals for High Performance X‐Ray and Photon Detectors journal December 2018
2D Hybrid Perovskite Ferroelectric Enables Highly Sensitive X‐Ray Detection with Low Driving Voltage journal November 2019
Unveiling the Structural Descriptor of A 3 B 2 X 9 Perovskite Derivatives toward X‐Ray Detectors with Low Detection Limit and High Stability journal May 2020
Halide Perovskites: Poor Man's High-Performance Semiconductors journal May 2016
Hot‐Pressed CsPbBr 3 Quasi‐Monocrystalline Film for Sensitive Direct X‐ray Detection journal September 2019
Tuning the Structural and Optoelectronic Properties of Cs 2 AgBiBr 6 Double‐Perovskite Single Crystals through Alkali‐Metal Substitution journal August 2020
Sensitive and Stable 2D Perovskite Single‐Crystal X‐ray Detectors Enabled by a Supramolecular Anchor journal September 2020
Triple‐Cation and Mixed‐Halide Perovskite Single Crystal for High‐Performance X‐ray Imaging journal January 2021
Sensitive Direct Converting X‐Ray Detectors Utilizing Crystalline CsPbBr 3 Perovskite Films Fabricated via Scalable Melt Processing journal January 2020
Controlled Cooling for Synthesis of Cs 2 AgBiBr 6 Single Crystals and Its Application for X‐Ray Detection journal June 2019
Ultrafast Ionizing Radiation Detection by p–n Junctions Made with Single Crystals of Solution‐Processed Perovskite journal August 2018
Polarons in Metal Halide Perovskites journal April 2020
Exploring Lead‐Free Hybrid Double Perovskite Crystals of (BA) 2 CsAgBiBr 7 with Large Mobility‐Lifetime Product toward X‐Ray Detection journal September 2019
A‐site Cation Engineering for Highly Efficient MAPbI 3 Single‐Crystal X‐ray Detector journal December 2019
Centimeter‐Sized Single Crystal of Two‐Dimensional Halide Perovskites Incorporating Straight‐Chain Symmetric Diammonium Ion for X‐Ray Detection journal June 2020
Amorphous selenium and its alloys from early xeroradiography to high resolution X-ray image detectors and ultrasensitive imaging tubes: Amorphous Se from early xeroradiography to high resolution X-ray image detectors journal July 2009
PIN Diodes Array Made of Perovskite Single Crystal for X-Ray Imaging journal September 2018
Lead-free halide perovskite Cs3Bi2Br9 single crystals for high-performance X-ray detection journal January 2021
Photon mass attenuation and energy-absorption coefficients journal November 1982
Single crystals for radiation detectors journal January 1992
Thick films of X-ray polycrystalline mercuric iodide detectors journal May 2001
Progress in the science and technology of direct conversion a-Se X-ray sensors journal April 2002
Requirements on amorphous semiconductors for medical X-ray detectors journal February 2001
Review of the Shockley–Ramo theorem and its application in semiconductor gamma-ray detectors journal May 2001
Cadmium zinc telluride and its use as a nuclear radiation detector material journal April 2001
Dependence of the electrical properties of stabilized a-Se on the preparation conditions and the development of a double layer X-ray detector structure journal May 2008
Ultrasensitive and stable X-ray detection using zero-dimensional lead-free perovskites journal October 2020
Inch-Size 0D-Structured Lead-Free Perovskite Single Crystals for Highly Sensitive Stable X-Ray Imaging journal July 2020
Metal Halide Perovskites for X-Ray Detection and Imaging journal January 2021
Co-axial silicon/perovskite heterojunction arrays for high-performance direct-conversion pixelated X-ray detectors journal December 2020
Detection of charged particles with a methylammonium lead tribromide perovskite single crystal
  • Xu, Qiang; Wei, Haotong; Wei, Wei
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 848 https://doi.org/10.1016/j.nima.2016.12.062
journal March 2017
Noise sources and their limitations on the performance of compound semiconductor hard radiation detectors
  • Liu, Zhifu; Peters, J. A.; Kim, Joon-Il
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 916 https://doi.org/10.1016/j.nima.2018.11.013
journal February 2019
Perovskite CsPbBr3 single crystal detector for alpha-particle spectroscopy
  • He, Yihui; Liu, Zhifu; McCall, Kyle M.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 922 https://doi.org/10.1016/j.nima.2019.01.008
journal April 2019
Intrinsic photopeak efficiency measurement and simulation for pixelated CdZnTe detector
  • Chen, Zhuo; Zhu, Yuefeng; He, Zhong
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 980 https://doi.org/10.1016/j.nima.2020.164501
journal November 2020
Improved Radiation Sensing with Methylammonium Lead Tribromide Perovskite Semiconductors
  • Tan, Ryan; Dryzhakov, Bogdan; Charest, Jessica
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 986 https://doi.org/10.1016/j.nima.2020.164710
journal January 2021
Solution-Grown CsPbBr 3 Perovskite Single Crystals for Photon Detection journal November 2016
Strong Electron–Phonon Coupling and Self-Trapped Excitons in the Defect Halide Perovskites A 3 M 2 I 9 (A = Cs, Rb; M = Bi, Sb) journal April 2017
Halide Perovskite Photovoltaics: Background, Status, and Future Prospects journal March 2019
Charge Transport Behavior in Solution-Grown Methylammonium Lead Tribromide Perovskite Single Crystal Using α Particles journal May 2018
Unravelling the Material Composition Effects on the Gamma Ray Stability of Lead Halide Perovskite Solar Cells: MAPbI 3 Breaks the Records journal March 2020
Facile Strategy for Facet Competition Management to Improve the Performance of Perovskite Single-Crystal X-ray Detectors journal April 2020
Exciton Polarons in Two-Dimensional Hybrid Metal-Halide Perovskites journal March 2020
High-Performance X-ray Detection Based on One-Dimensional Inorganic Halide Perovskite CsPbI 3 journal December 2019
Solution-Grown Formamidinium Hybrid Perovskite (FAPbBr 3 ) Single Crystals for α-Particle and γ-Ray Detection at Room Temperature journal March 2021
Enhanced X-ray Sensitivity of MAPbBr 3 Detector by Tailoring the Interface-States Density journal January 2019
High-Energy Photon Spectroscopy Using All Solution-Processed Heterojunctioned Surface-Modified Perovskite Single Crystals journal August 2019
Rubidium Doping to Enhance Carrier Transport in CsPbBr 3 Single Crystals for High-Performance X-Ray Detection journal December 2019
TlSn 2 I 5 , a Robust Halide Antiperovskite Semiconductor for γ-Ray Detection at Room Temperature journal June 2017
α-Particle Detection and Charge Transport Characteristics in the A 3 M 2 I 9 Defect Perovskites (A = Cs, Rb; M = Bi, Sb) journal August 2018
Resolving the Energy of γ-Ray Photons with MAPbI 3 Single Crystals journal September 2018
Zero-Dimensional Cs 2 TeI 6 Perovskite: Solution-Processed Thick Films with High X-ray Sensitivity journal December 2018
Crystal Growth of the Perovskite Semiconductor CsPbBr 3 : A New Material for High-Energy Radiation Detection journal June 2013
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties journal July 2013
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells journal May 2009
Three-Dimensional Lead Iodide Perovskitoid Hybrids with High X-ray Photoresponse journal March 2020
Demonstration of Energy-Resolved γ-Ray Detection at Room Temperature by the CsPbCl 3 Perovskite Semiconductor journal January 2021
2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications journal June 2015
Defect Antiperovskite Compounds Hg 3 Q 2 I 2 (Q = S, Se, and Te) for Room-Temperature Hard Radiation Detection journal May 2017
Cs 2 PbI 2 Cl 2 , All-Inorganic Two-Dimensional Ruddlesden–Popper Mixed Halide Perovskite with Optoelectronic Response journal August 2018
Hybrid organic—inorganic perovskites: low-cost semiconductors with intriguing charge-transport properties journal January 2016
All-solid-state dye-sensitized solar cells with high efficiency journal May 2012
Efficient planar heterojunction perovskite solar cells by vapour deposition journal September 2013
Printable organometallic perovskite enables large-area, low-dose X-ray imaging journal October 2017
Dopant compensation in alloyed CH3NH3PbBr3−xClx perovskite single crystals for gamma-ray spectroscopy journal July 2017
Metal-halide perovskites for photovoltaic and light-emitting devices journal May 2015
Detection of X-ray photons by solution-processed lead halide perovskites journal May 2015
Detection of gamma photons using solution-grown single crystals of hybrid lead halide perovskites journal July 2016
Sensitive X-ray detectors made of methylammonium lead tribromide perovskite single crystals journal March 2016
Perovskites target X-ray detection journal April 2016
Monolithic integration of hybrid perovskite single crystals with heterogenous substrate for highly sensitive X-ray imaging journal April 2017
High-performance direct conversion X-ray detectors based on sintered hybrid lead triiodide perovskite wafers journal June 2017
Direct measurement of the exciton binding energy and effective masses for charge carriers in organic–inorganic tri-halide perovskites journal June 2015
Ferroelectric large polarons journal April 2018
Cs2AgBiBr6 single-crystal X-ray detectors with a low detection limit journal October 2017
Highly sensitive X-ray detector made of layered perovskite-like (NH4)3Bi2I9 single crystal with anisotropic response journal June 2019
CsPbBr3 perovskite detectors with 1.4% energy resolution for high-energy γ-rays journal December 2020
Perovskite-filled membranes for flexible and large-area direct-conversion X-ray detector arrays journal August 2020
Heterogeneity at multiple length scales in halide perovskite semiconductors journal July 2019
All-inorganic perovskite nanocrystal scintillators journal August 2018
Optical and electronic anisotropies in perovskitoid crystals of Cs 3 Bi 2 I 9 studies of nuclear radiation detection journal January 2018
Bismuth halide perovskite derivatives for direct X-ray detection journal January 2020
Melt-grown large-sized Cs 2 TeI 6 crystals for X-ray detection journal January 2020
Bandgap Dependence and Related Features of Radiation Ionization Energies in Semiconductors journal March 1968
Currents to Conductors Induced by a Moving Point Charge journal October 1938
Room temperature semiconductor detectors for nuclear security journal July 2019
X-ray sensitivity of photoconductors: application to stabilized a-Se journal October 2000
Thallium Halide Crystal Counter journal December 1947
Alkali Halide Scintillation Counters journal July 1948
Local Polar Fluctuations in Lead Halide Perovskite Crystals journal March 2017
Semiconductor materials and radiation detection journal February 2006
Comparison of CMOS and a-Si flat panel imagers for X-ray imaging conference May 2011
Currents Induced by Electron Motion journal September 1939
Recent Developments of Amorphous Selenium-Based X-Ray Detectors: A Review journal February 2020
Performance of Perovskite CsPbBr 3 Single Crystal Detector for Gamma-Ray Detection journal February 2020
Sensitivity of x-ray photoconductors: Charge trapping and absorption-limited universal sensitivity curves journal May 2002
Medical Imaging Principles, Detectors, and Electronics journal October 2009
Molecular behavior of zero-dimensional perovskites journal December 2017
A sensitive and robust thin-film x-ray detector using 2D layered perovskite diodes journal April 2020
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites journal October 2012
Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals journal January 2015
Properties and potential optoelectronic applications of lead halide perovskite nanocrystals journal November 2017
Photon-counting CT: Technical Principles and Clinical Prospects journal November 2018
Structural Phase Transition and Electrical Conductivity of the Perovskite CH 3 NH 3 Sn 1 - x Pb x Br 3 and CsSnBr 3 journal September 1990
The underappreciated lone pair in halide perovskites underpins their unusual properties journal June 2020
Amorphous and Polycrystalline Photoconductors for Direct Conversion Flat Panel X-Ray Image Sensors journal May 2011

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