Metal‐Organic Framework Glass Anode with an Exceptional Cycling‐Induced Capacity Enhancement for Lithium‐Ion Batteries

Gao, Chengwei; Jiang, Zhenjing; Qi, Shibin; Wang, Peixing; Jensen, Lars Rosgaard; Johansen, Morten; Christensen, Christian Kolle; Zhang, Yanfei; Ravnsbæk, Dorthe Bomholdt; Yue, Yuanzheng

doi:10.1002/adma.202110048

Metal‐Organic Framework Glass Anode with an Exceptional Cycling‐Induced Capacity Enhancement for Lithium‐Ion Batteries

Journal Article · Mon Jan 31 00:00:00 EST 2022 · Advanced Materials

DOI:https://doi.org/10.1002/adma.202110048· OSTI ID:1842902

^[1]; Jiang, Zhenjing ^[2]; Qi, Shibin ^[2]; Wang, Peixing ^[2]; Jensen, Lars Rosgaard ^[3]; Johansen, Morten ^[4]; Christensen, Christian Kolle ^[4]; Zhang, Yanfei ^[2]; Ravnsbæk, Dorthe Bomholdt ^[5]; ^[6]

Department of Chemistry and Bioscience Aalborg University Aalborg 9220 Denmark, Laboratory of Infrared Material and Devices The Research Institute of Advanced Technologies Ningbo University Ningbo 315211 China, School of Materials Science and Engineering Qilu University of Technology (Shandong Academy of Sciences) Jinan 250353 China
School of Materials Science and Engineering Qilu University of Technology (Shandong Academy of Sciences) Jinan 250353 China
Department of Materials and Production Aalborg University Aalborg 9220 Denmark
Department of Physics Chemistry and Pharmacy University of Southern Denmark Odense M 5230 Denmark
Department of Chemistry Aarhus University Aarhus C 8000 Denmark
Department of Chemistry and Bioscience Aalborg University Aalborg 9220 Denmark

Abstract

Metal‐organic frameworks (MOFs) hold great promise as high‐energy anode materials for next‐generation lithium‐ion batteries (LIBs) due to their tunable chemistry, pore structure and abundant reaction sites. However, the pore structure of crystalline MOFs tends to collapse during lithium‐ion insertion and extraction, and hence, their electrochemical performances are rather limited. As a critical breakthrough, a MOF glass anode for LIBs has been developed in the present work. In detail, it is fabricated by melt‐quenching Cobalt‐ZIF‐62 (Co(Im) _1.75 (bIm) _0.25 ) to glass, and then by combining glass with carbon black and binder. The derived anode exhibits high lithium storage capacity (306 mAh g ⁻¹ after 1000 cycles at of 2 A g ⁻¹ ), outstanding cycling stability, and superior rate performance compared with the crystalline Cobalt‐ZIF‐62 and the amorphous one prepared by high‐energy ball‐milling. Importantly, it is found that the Li‐ion storage capacity of the MOF glass anode continuously rises with charge–discharge cycling and even tripled after 1000 cycles. Combined spectroscopic and structural analyses, along with density functional theory calculations, reveal the origin of the cycling‐induced enhancement of the performances of the MOF glass anode, that is, the increased distortion and local breakage of the CoN coordination bonds making the Li‐ion intercalation sites more accessible.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1842902

Alternate ID(s):: OSTI ID: 1856388

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 10 Vol. 34; ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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