Structure–Property Correlation of Hierarchically Porous Carbons for Fluorocarbon Adsorption

Shen, Jian; Estevez, Luis; Barpaga, Dushyant; Zheng, Jian; Shutthanandan, Vaithiyalingam; McGrail, B. Peter; Motkuri, Radha Kishan

doi:10.1021/acsami.1c16315

Title: Structure–Property Correlation of Hierarchically Porous Carbons for Fluorocarbon Adsorption

Journal Article · Tue Nov 09 00:00:00 EST 2021 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.1c16315· OSTI ID:1842681

Shen, Jian ^[1];

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^[4];

^[5]; McGrail, B. Peter ^[3];

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Xiangtan Univ. (China); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Advanced & Innovative Multifunctional Materials, Dayton, OH (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Sichuan Univ., Chengdu (China)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)

Although traditional commercially available porous carbon-fluorocarbon working pairs have shown promising applicability for adsorption cooling, advancements in synthetic carbons may further improve performance. Moreover, insights into structure-property relationships that target higher sorption capacities within these synthesized carbons may guide such materials' future design. We utilized hierarchically porous synthetic carbons (HPCs) with colossal microporous and mesoporous characterized by high surface areas (up to 2689 m²/g) and pore volumes (up to 10.31 cm³/g) towards fluorocarbon R134a adsorption. This unique pore topology leads to exceptional R134a uptake, ~250 wt.%, outperforming the highest uptake carbon material to date, Maxsorb III (~220 wt.%). Additionally, material characterizations reveal that the outstanding R134a capacity may be attributed to textural properties and oxygen-terminated functional groups more than graphitization of the material. Most importantly, HPCs are efficiently utilized in a two-bed model chiller device, where the performance shows excellent working capacity (105 wt%, ~1.5 times the value of reported carbon materials/R134a). Fluorocarbons adsorption on HPCs also displays fast kinetics (equilibrium time: ~2 min) mainly driven by physical adsorption (Qst: ~27 kJ/mol), characteristic of swiftly reversible behavior adsorption-desorption behaviors. This work provides a fundamental understanding of the applicability of HPCs/R134a working pair for adsorption cooling.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Geothermal Technologies Office

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1842681

Report Number(s):: PNNL-SA-165898

Journal Information:: ACS Applied Materials and Interfaces, Vol. 13, Issue 45; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Hierarchically porous carbons
Fluorocarbon
R134a sorption
Adsorption cooling
Sorbents
Adsorption
Carbon
Porous materials
Materials

Title: Structure–Property Correlation of Hierarchically Porous Carbons for Fluorocarbon Adsorption

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