Selective Removal of Perfluorobutyric Acid Using an Electroactive Ion Exchanger Based on Polypyrrole@Iron Oxide on Carbon Cloth

Huyan, Chenxi; Ding, Shichao; Lyu, Zhaoyuan; Engelhard, Mark H.; Tian, Yuhao; Du, Dan; Liu, Dong; Lin, Yuehe

doi:10.1021/acsami.1c09374

Selective Removal of Perfluorobutyric Acid Using an Electroactive Ion Exchanger Based on Polypyrrole@Iron Oxide on Carbon Cloth

Journal Article · Thu Oct 07 00:00:00 EDT 2021 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.1c09374· OSTI ID:1842679

Huyan, Chenxi ^[1]; Ding, Shichao ^[1]; Lyu, Zhaoyuan ^[1]; ^[2]; Tian, Yuhao ^[1]; ^[1]; Liu, Dong ^[1]; ^[1]

Washington State Univ., Pullman, WA (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)

Perfluorabutyric acid (PFBA) is one classify of perfluoroalkyl and polyfluoroalkyl substances (PFASs), which is applied to wide-spread industry compounds. The removal of PFBA has attracted considerable scientific interest in recent decades because it caused environmental pollutions and human diseases. For removing PFASs from wastewater, the adsorption method has been commonly used for the remediation of PFASs. However, it is usually limited by the inevitable “secondary waster” produced in this treatment process. In this work, PFBA can be removed effectively by synergizing the electrically switched ion exchange (ESIX) and a novel nanostructured ion exchanger. Herein, the nanostructured ion exchanger is designed by coating polypyrrole (PPy) @ Fe₂O₃ nanoneedle on carbon cloth (PPy@Fe₂O₃ NN-CC). Overall, results show that PPy@Fe₂O₃ NN-CC film enhances ion exchange speed and efficiency, which endures its high-capacity adsorption ability and rapid regeneration property, thereby reducing secondary waste. Moreover, ESIX based on PPy@Fe₂O₃ NN-CC has high selectivity for adsorption of PFBA over Cl^-, SO₄^2- and NO₃^-.

View Accepted Manuscript (DOE)

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1842679

Report Number(s):: PNNL-SA-163041

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 41 Vol. 13; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Electrically switched ion exchange (ESIX)
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Selective Removal of Perfluorobutyric Acid Using an Electroactive Ion Exchanger Based on Polypyrrole@Iron Oxide on Carbon Cloth

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