Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials

Susner, Michael A.; Chyasnavichyus, Marius; McGuire, Michael A.; Ganesh, Panchapakesan; Maksymovych, Petro

doi:10.1002/adma.201602852

Title: Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials

Journal Article · Mon Aug 21 00:00:00 EDT 2017 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201602852· OSTI ID:1842642

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Air Force Research Lab. (AFRL), Wright-Patterson AFB, OH (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); UES Inc., Beavercreek, OH (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Since the discovery of Dirac physics in graphene, research in 2D materials has exploded with the aim of finding new materials and harnessing their unique and tunable electronic and optical properties. The follow-on work on 2D dielectrics and semiconductors has led to the emergence and development of hexagonal boron nitride, black phosphorus, and transition metal disulfides. However, the spectrum of good insulating materials is still very narrow. Likewise, 2D materials exhibiting correlated phenomena such as superconductivity, magnetism, and ferroelectricity have yet to be developed or discovered. These properties will significantly enrich the spectrum of functional 2D materials, particularly in the case of high phase-transition temperatures. They will also advance a fascinating fundamental frontier of size and proximity effects on correlated ground states. In this work, a broad family of layered metal thio(seleno)phosphate materials that are moderate- to wide-bandgap semiconductors with incipient ionic conductivity and a host of ferroic properties are reviewed. It is argued that this material class has the potential to merge the sought-after properties of complex oxides with electronic functions of 2D and quasi-2D electronic materials, as well as to create new avenues for both applied and fundamental materials research in structural and magnetic correlations.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1842642

Alternate ID(s):: OSTI ID: 1375659

Journal Information:: Advanced Materials, Vol. 29, Issue 38; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 227 works

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Tunable quadruple-well ferroelectric van der Waals crystals Brehm, John A.; Neumayer, Sabine M.; Tao, Lei Nature Materials, Vol. 19, Issue 1 https://doi.org/10.1038/s41563-019-0532-z	journal	November 2019
Field Effect Transistor Based on Layered NiPS 3 Jenjeti, Ramesh Naidu; Kumar, Rajat; Austeria, Muthu P. Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-26522-1	journal	June 2018
Two-dimensional GeAsSe with high and unidirectional conductivity Zhang, Wei; Wang, Yang-Gang; Ding, Yanhuai Nanoscale, Vol. 10, Issue 34 https://doi.org/10.1039/c8nr02731e	journal	January 2018
Layered franckeite and teallite intrinsic heterostructures: shear exfoliation and electrocatalysis Gusmão, Rui; Sofer, Zdeněk; Luxa, Jan Journal of Materials Chemistry A, Vol. 6, Issue 34 https://doi.org/10.1039/c8ta06021e	journal	January 2018
Layered metal phosphorous trichalcogenides nanosheets: facile synthesis and photocatalytic hydrogen evolution Cheng, Zhongzhou; Sendeku, Marshet Getaye; Liu, Quanlin Nanotechnology, Vol. 31, Issue 13 https://doi.org/10.1088/1361-6528/ab646d	journal	January 2020
Cation role in the thermal properties of layered materials $M^{1 +} M^{3 +} P_{2} {(S, Se)}_{6} (M^{1 +} = Cu, Ag; M^{3 +} = In, Bi)$ Liubachko, V.; Oleaga, A.; Salazar, A. Physical Review Materials, Vol. 3, Issue 10 https://doi.org/10.1103/physrevmaterials.3.104415	journal	October 2019
High-Yield Production of Monolayer FePS ₃ Quantum Sheets via Chemical Exfoliation for Efficient Photocatalytic Hydrogen Evolution Cheng, Zhongzhou; Shifa, Tofik Ahmed; Wang, Fengmei Advanced Materials, Vol. 30, Issue 26 https://doi.org/10.1002/adma.201707433	journal	May 2018
Probing and controlling magnetic states in 2D layered magnetic materials Mak, Kin Fai; Shan, Jie; Ralph, Daniel C. Nature Reviews Physics, Vol. 1, Issue 11 https://doi.org/10.1038/s42254-019-0110-y	journal	September 2019
Robust two-dimensional ferroelectricity in single-layer γ-SbP and γ-SbAs Shen, Shiying; Liu, Chang; Ma, Yandong Nanoscale, Vol. 11, Issue 24 https://doi.org/10.1039/c9nr02265a	journal	January 2019
Photochemical HER activity of layered metal phospho-sulfides and -selenides Barua, Manaswee; Ayyub, Mohd Monis; Vishnoi, Pratap Journal of Materials Chemistry A, Vol. 7, Issue 39 https://doi.org/10.1039/c9ta06044h	journal	January 2019
NiPS ₃ nanosheets for passive pulse generation in an Er-doped fiber laser Wang, Jin; Wang, Tao; Shi, Xinyao Journal of Materials Chemistry C, Vol. 7, Issue 46 https://doi.org/10.1039/c9tc04722k	journal	January 2019
Suppression of magnetic ordering in XXZ-type antiferromagnetic monolayer NiPS3 Kim, Kangwon; Lim, Soo Yeon; Lee, Jae-Ung arXiv https://doi.org/10.48550/arxiv.1901.10890	text	January 2019

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