skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Microfracture-pore structure characterization and water-rock interaction in three lithofacies of the Lower Eagle Ford Formation

Journal Article · · Engineering Geology
 [1]; ORCiD logo [1];  [1];  [1];  [2];  [1];  [3]
  1. Univ. of Texas, Arlington, TX (United States)
  2. China Univ. of Geosciences, Wuhan (China)
  3. China Univ. of Petroleum (East China), Qingdao (China)

The microfracture-pore structures and water-rock interactions of eight samples of three typical lithofacies (three limestone, three wackestone, and two mudstone) from the Lower Eagle Ford Formation have been investigated using an integrated methodology. The methods used were X-ray diffraction (XRD), total organic carbon (TOC) content, pyrolysis, thin-section petrography, scanning electron microscopy (SEM), mercury intrusion porosimetry (MIP), spontaneous water imbibition, and water vapor & nitrogen physisorption. Petrophysical properties such as organic richness, maturity, mineral composition, types and patterns of microfractures and pores, porosity, pore-throat size distribution, pore size distribution, pore connectivity, water adsorption and desorption behavior were determined from these methods, and the results compared among the three lithofacies. For example, the three limestone EAS samples and three wackestone DM samples show a low porosity range from 2.02–3.35%, whereas the two mudstone VRU samples exhibit a much large average porosity of 11.7% by MIP results. Nitrogen physisorption results show that pore size distributions have a good similarity in N2 adsorption volume for the samples with similar lithology. Microfractures are morphologically divided into seven types, with their definitions & pictorial examples presented and possible formation mechanisms proposed. In addition, the water vapor physisorption behavior and their controlling factors are discussed. Here, the water adsorption capacity shows a positive relationship (R2 = 0.90) with clay content and a negative relationship (R2 = 0.99) with carbonate content. In general, this integrated study of microfracture-pore structure characterization and water-rock interaction provides some insights of water vapor adsorption behavior in different lithofacies and whether microfractures could be an important pathway for fluid flow.

Research Organization:
Univ. of Texas, Arlington, TX (United States)
Sponsoring Organization:
USDOE Office of Nuclear Energy (NE)
Grant/Contract Number:
NE0008797
OSTI ID:
1842341
Alternate ID(s):
OSTI ID: 1808890
Journal Information:
Engineering Geology, Vol. 292; ISSN 0013-7952
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (71)

Coupled nano-petrophysical and organic-geochemical study of the Wolfberry Play in Howard County, Texas U.S.A. journal December 2020
Experimental Confirmation of Different Mechanisms of Evaporation from Ink-Bottle Type Pores:  Equilibrium, Pore Blocking, and Cavitation journal December 2002
Characterization of Eagle Ford Shale journal December 2002
Characterization of marl and interbedded limestone layers in the Eagle Ford Formation, DeWitt county, Texas journal January 2019
Hysteretic Behavior of Metolachlor Adsorption-Desorption in Soils journal January 2000
Water Vapor Adsorption in Porous Building Materials: Experimental Measurement and Theoretical Analysis journal October 2011
Water Vapor Diffusion and Adsorption of Sandstones: Influence of Rock Texture and Composition journal January 2016
Characteristics and the formation mechanism of the heterogeneous microfractures in the tight oil reservoir of Ordos Basin, China journal August 2020
Natural Fractures in shale: A review and new observations journal November 2014
Microfracture spacing distributions and the evolution of fracture patterns in sandstones journal March 2018
Changes in water vapor adsorption and water film thickness in clayey materials as a function of relative humidity journal January 2020
Dynamics of Water Adsorption onto a Calcite Surface as a Function of Relative Humidity journal February 2008
Rock fabric heterogeneity and its influence on the petrophysical properties of a building limestone: Lede stone (Belgium) as an example journal January 2017
Microfractures: A review journal December 2014
A Thermodynamically Based Method to Quantify True Sorption Hysteresis journal May 2005
Investigation of a shallow slope failure on expansive clay in Texas journal March 2017
Low nanopore connectivity limits gas production in Barnett formation journal December 2015
Pore Geometry Characteristics and Fluid–Rock Interaction in the Haynesville Shale, East Texas, United States journal October 2020
Development of a new durability index for compacted shale journal June 2012
Durability of Rock as Function of Grain Size, Pore Size, and Rate of Capillary Absorption of Water journal February 1989
A simulation study of the effect of clay swelling on fracture generation and porosity change in shales under stress anisotropy journal December 2020
Experimental study of water vapor adsorption behaviors on shale journal July 2019
Water vapor adsorption on geothermal reservoir rocks journal August 1995
Organic matter-hosted pore system, Marcellus Formation (Devonian), Pennsylvania journal February 2013
Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix-related mudrock pores journal June 2012
Pore characteristics and influencing factors of different types of shales journal April 2019
Effect of air-drying duration on the engineering properties of four clay-bearing rocks in Texas journal September 2010
The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms journal January 1951
Laboratory measurement of water imbibition into low-permeability welded tuff journal February 2001
Water Sorption and Distribution Characteristics in Clay and Shale: Effect of Surface Force journal October 2016
Water retention of a bentonite for deep geological radioactive waste repositories: High-temperature experiments and thermodynamic modeling journal May 2020
Experimental investigations on the geometry and connectivity of pore space in organic-rich Wufeng and Longmaxi shales journal June 2017
Modeling large underground experimental halls for the Superconducting Super Collider journal December 1993
Water sorption behaviour of gas shales: II. Pore size distribution journal June 2017
Water sorption behaviour of gas shales: I. Role of clays journal June 2017
Low pore connectivity in natural rock journal May 2012
Estimating permeability using median pore-throat radius obtained from mercury intrusion porosimetry journal March 2013
Coevolution of crack-seal texture and fracture porosity in sedimentary rocks: cathodoluminescence observations of regional fractures journal May 2004
Macro-fracture mode and micro-fracture mechanism of shale journal April 2015
Origin and characterization of Eagle Ford pore networks in the south Texas Upper Cretaceous shelf journal March 2017
In situ visualization of fluid flow image within deformed rock by X-ray CT journal October 2003
The influence of fracture cements in tight Paleogene saline lacustrine carbonate reservoirs, western Qaidam Basin, northwest China journal November 2012
Adsorption hysteresis in ink-bottle pore journal July 2003
Water adsorption characteristics of organic-rich Wufeng and Longmaxi Shales, Sichuan Basin (China) journal October 2020
A complex rock topple-rock slide failure of an anaclinal rock slope in the Wu Gorge, Yangtze River, China journal June 2016
Microfractures in the middle Carboniferous carbonate rocks and their control on reservoir quality in the Zanaral Oilfield journal April 2018
Controls On Sedimentation and Cyclicity of the Boquillas and Equivalent Eagle Ford Formation from Detailed Outcrop Studies of Western and Central Texas, U.S.A. journal July 2019
Engineering geological properties of Leitha Limestone from historical quarries in Burgenland and Styria, Austria journal June 2014
Water vapor sorption and its mechanical effect on clay-bearing conglomerate selected from China journal July 2012
Vapor-Pressure Lowering in Geothermal Systems journal February 1983
Microfracturing and microporosity in shales journal November 2016
Geomechanical and water vapor absorption characteristics of clay-bearing soft rocks at great depth journal November 2014
Characterization of micro-nano pore networks in shale oil reservoirs of Paleogene Shahejie Formation in Dongying Sag of Bohai Bay Basin, East China journal October 2017
Experimental investigation on the mechanical behaviours of a low-clay shale under water-based fluids journal January 2018
Microcrack nucleation in marble journal February 1976
Predicting and characterizing fractures in dolostone reservoirs: using the link between diagenesis and fracturing journal January 2004
Spontaneous Imbibition of Brine and Oil in Gas Shales: Effect of Water Adsorption and Resulting Microfractures journal May 2013
Pore structure and fluid uptake of the Yeso, Abo, and Cisco Formations in the Permian Basin in southeast New Mexico, USA journal November 2019
Depositional controls on sediment body architecture in the Eagle Ford/Boquillas system: Insights from outcrops in west Texas, United States journal April 2016
Water vapor sorption on Marcellus shale: measurement, modeling and thermodynamic analysis journal December 2017
Pore types and pore-size distributions across thermal maturity, Eagle Ford Formation, southern Texas journal September 2015
Adsorption of Gases in Multimolecular Layers journal February 1938
Free Energy of Adsorption of Water and Metal Ions on the {101̄4} Calcite Surface journal August 2004
Experimental study of the effect of stress anisotropy on fracture propagation in Eagle Ford shale under water imbibition journal January 2019
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) journal January 1985
Gas transport and storage capacity in shale gas reservoirs – A review. Part A: Transport processes journal December 2015
Diagenesis in porosity evolution of opening-mode fractures, Middle Triassic to Lower Jurassic La Boca Formation, NE Mexico journal June 2006
Water adsorption at high temperature on core samples from The Geysers geothermal field, California, USA journal April 2001
Liquid water uptake in unconfined Callovo Oxfordian clay-rock studied with neutron and X-ray imaging journal March 2018
Microfracturing in the Upper Triassic Sichuan Basin tight-gas sandstones: Tectonic, overpressure, and diagenetic origins journal December 2010
Mechanisms for Soil-Water Retention and Hysteresis at High Suction Range journal August 2015