Electrical and thermal transport in van der Waals magnets 2 H − M x TaS 2   ( M = Mn ,   Co )

Liu, Yu; Hu, Zhixiang; Tong, Xiao; Bauer, Eric D.; Petrovic, C.

doi:10.1103/PhysRevResearch.4.013048

Title: Electrical and thermal transport in van der Waals magnets $2 H − M_{x} {TaS}_{2} (M = Mn, Co)$

Journal Article · Mon Jan 24 00:00:00 EST 2022 · Physical Review Research

DOI:https://doi.org/10.1103/PhysRevResearch.4.013048· OSTI ID:1841636

; Hu, Zhixiang; Tong, Xiao; Bauer, Eric D.;

We report a detailed study of electrical and thermal transport properties in 2H-M_x TaS₂ (M = Mn, Co) magnets where M atoms are intercalated in the van der Waals gap. The intercalation induces ferromagnetism (FM) with an easy-plane anisotropy in 2H-M_x TaS₂, but FM with a strong uniaxial anisotropy in 2H-Co_0.22TaS₂, which finally evolves into a three-dimensional antiferromagnetism (AFM) in 2H-Co_0.34TaS₂. Temperature-dependent electrical resistivity shows metallic behavior for all samples. Thermopower is negative in the whole temperature range for 2H-Co_xTaS₂, whereas the sign changes from negative to positive with increasing Mn for 2H-Mn_x TaS₂. The diffusive thermoelectric response dominates in both high- and low-temperature ranges for all samples. A clear kink in electrical resistivity, a weak anomaly in thermal conductivity, as well as a slope change in thermopower were observed at the magnetic transitions for 2H-Mn_0.28 TaS₂(T_c ≈ 82 K) and 2H-Co_0.34TaS₂ (T_N ≈ 36 K), respectively, albeit weaker for lower x crystals. Co-intercalation promoted FM to AFM transition is further confirmed by Hall resistivity; the sign change of the ordinary Hall coefficient indicates a multiband behavior in 2H-Co_xTaS₂.

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Research Organization:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: SC0012704; 89233218CNA000001

OSTI ID:: 1841636

Alternate ID(s):: OSTI ID: 1865030

Report Number(s):: LA-UR-21-29465; PPRHAI; 013048

Journal Information:: Physical Review Research, Journal Name: Physical Review Research Vol. 4 Journal Issue: 1; ISSN 2643-1564

Publisher:: American Physical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Electrical and thermal transport in van der Waals magnets 2 H − M x TaS 2 ( M = Mn , Co )

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Title: Electrical and thermal transport in van der Waals magnets $2 H − M_{x} {TaS}_{2} (M = Mn, Co)$