Chemical structure and dissolution behaviour of CaO and ZnO containing alkali-borosilicate glass

Fisher, Adam J.; Ding, Hao; Rajbhandari, Prashant; Walkley, Brant; Blackburn, Lewis R.; Stennett, Martin C.; Hand, Russell J.; Hyatt, Neil C.; Harrison, Michael T.; Corkhill, Claire L.

doi:10.1039/D1MA01029H

Chemical structure and dissolution behaviour of CaO and ZnO containing alkali-borosilicate glass

Journal Article · Sun Feb 06 23:00:00 EST 2022 · Materials Advances

DOI:https://doi.org/10.1039/D1MA01029H· OSTI ID:1840058

Fisher, Adam J. ^[1]; Ding, Hao ^[1]; Rajbhandari, Prashant ^[1]; ^[2]; Blackburn, Lewis R. ^[1]; ^[1]; ^[1]; ^[1]; Harrison, Michael T. ^[3]; ^[1]

NucleUS Immobilisation Science Laboratory, Department of Materials Science and Engineering, University of Sheffield, Sheffield, S1 3JD, UK
Department of Chemical and Biological Engineering, University of Sheffield, S1 3JD, UK
National Nuclear Laboratory, Sellafield, Seascale, Cumbria, CA20 1PG, UK

Altering the CaO to ZnO ratio of alkali borosilicate glass, in favour of ZnO, causes phase separation with hardystonite-like (Ca ₂ ZnSi ₂ O ₇ ) and willemite-like (ZnSi ₂ O ₄ ) structures identified. This is concurrent with increased glass durability.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; SC0012704

OSTI ID:: 1840058

Journal Information:: Materials Advances, Journal Name: Materials Advances Journal Issue: 3 Vol. 3; ISSN MAADC9; ISSN 2633-5409

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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