Shape memory effect in metallic glasses

Xu, Tianding; Wang, Xiao-Dong; Dufresne, Eric M.; Ren, Yang; Cao, Qingping; Zhang, Dongxian; Jiang, Jian-Zhong

doi:10.1016/j.matt.2021.08.010

Title: Shape memory effect in metallic glasses

Journal Article · Wed Oct 06 00:00:00 EDT 2021 · Matter (Online)

DOI:https://doi.org/10.1016/j.matt.2021.08.010· OSTI ID:1840033

Xu, Tianding ^[1]; Wang, Xiao-Dong ^[1]; Dufresne, Eric M. ^[2];

^[2]; Cao, Qingping ^[1];

^[1]; Jiang, Jian-Zhong ^[1]

Zhejiang Univ., Hangzhou (China)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Shape memory effect (SME), mainly present in crystalline Ti-Ni alloys, is basically missing in metallic glasses (MGs) that lack the long-range periodic order of crystals. In this work, we report experimental results of SME in annealed MGs, in which the low-energy configuration state recovery is observed by both differential scanning calorimetry and X-ray photon correlation spectroscopy. We elucidate the origin of SME in MGs under the potential energy landscape framework, i.e., after annealing, the energy of MGs enters into a deep basin and atoms are located in the low-energy configuration state. Albeit deviating from their relative stable configurations by temperature changes, atoms in the annealed MGs tend to return to the low-energy atomic configurations along certain trajectories as pre-annealing temperature is approached, These results could extend the application of MGs as functional materials by directionally manipulating their energy states via annealing and rejuvenation.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC); National Natural Science Foundation of China (NSFC); National Key Research and Development Program of China; Zhejiang Provincial Natural Science Foundation of China; Fundamental Research Funds for the Central Universities

Grant/Contract Number:: AC02-06CH11357; 51671169; U1832203; 11975202; 2017YFA0403400; Y4110192; LZ20E010002

OSTI ID:: 1840033

Journal Information:: Matter (Online), Vol. 4, Issue 10; ISSN 2590-2385

Publisher:: Cell Press/ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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