Multi-phase equation of state of ultrapure hafnium to 120 GPa

Huston, L. Q.; Velisavljevic, N.; Smith, J. S.; Gray, G. T.; Sturtevant, B. T.

doi:10.1088/1361-648x/ac33dd

Multi-phase equation of state of ultrapure hafnium to 120 GPa

Journal Article · Fri Nov 12 00:00:00 EST 2021 · Journal of Physics. Condensed Matter

DOI:https://doi.org/10.1088/1361-648x/ac33dd· OSTI ID:1839690

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Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Argonne National Lab. (ANL), Lemont, IL (United States); Carnegie Inst. of Science, Argonne, IL (United States). High Pressure Collaborative Access Team (HPCAT)

Hafnium (Hf) is an industrially important material due to its large neutron absorption cross-section and its high corrosion resistance. When subjected to high pressure, Hf phase transforms from its hexagonal close packed α-Hf phase to the hexagonal ω-Hf phase. Upon further compression, ω-Hf phase transforms to the body centered cubic β-Hf phase. In this study, the high pressure phase transformations of Hf are studied by compressing and decompressing a well-characterized Hf sample in diamond anvil cells up to 120 GPa while collecting x-ray diffraction data. The phase transformations of Hf were compared in both a He pressure transmitting medium (PTM) and no PTM over several experiments. It was found that the α-Hf to ω-Hf phase transition occurs at a higher pressure during compression and lower pressure during decompression with a helium (He) PTM compared to using no PTM. Finally, there was little difference in the ω-Hf to β-Hf phase transition pressure between the He PTM and no PTM. The equation of state was fit for all three phases of Hf and under both PTM and no-PTM.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: LDRD; USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE National Nuclear Security Administration (NNSA). Office of Experimental Sciences

Grant/Contract Number:: 89233218CNA000001; AC02-06CH11357

OSTI ID:: 1839690

Alternate ID(s):: OSTI ID: 1853928

Report Number(s):: LA-UR-21-24396; 170237

Journal Information:: Journal of Physics. Condensed Matter, Journal Name: Journal of Physics. Condensed Matter Journal Issue: 5 Vol. 34; ISSN 0953-8984

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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