Discharging Behavior of Hollandite α-MnO2 in a Hydrated Zinc-Ion Battery

Le, Thanh; Sadique, Nahian; Housel, Lisa M.; Poyraz, Altug S.; Takeuchi, Esther S.; Takeuchi, Kenneth J.; Marschilok, Amy C.; Liu, Ping

doi:10.1021/acsami.1c18849

Discharging Behavior of Hollandite α-MnO₂ in a Hydrated Zinc-Ion Battery

Journal Article · Mon Dec 13 00:00:00 EST 2021 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.1c18849· OSTI ID:1839214

Le, Thanh ^[1]; Sadique, Nahian ^[2]; Housel, Lisa M. ^[3]; ^[4]; ^[5]; ^[5]; ^[5]; ^[6]

State Univ. of New York (SUNY), Stony Brook, NY (United States)
State Univ. of New York (SUNY), Stony Brook, NY (United States); State Univ. of New York (SUNY), Stony Brook, NY (United States). Inst. for Electrochemically Stored Energy
State Univ. of New York (SUNY), Stony Brook, NY (United States). Inst. for Electrochemically Stored Energy; Brookhaven National Lab. (BNL), Upton, NY (United States)
Department of Chemistry, Kennesaw State University, Kennesaw, Georgia 30144, United States
State Univ. of New York (SUNY), Stony Brook, NY (United States); State Univ. of New York (SUNY), Stony Brook, NY (United States). Inst. for Electrochemically Stored Energy; Brookhaven National Lab. (BNL), Upton, NY (United States)
State Univ. of New York (SUNY), Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Hollandite, α-MnO₂, is of interest as a prospective cathode material for hydrated zinc ion batteries (ZIBs); however, the mechanistic understanding of the discharge process remains limited. Herein, a systematic study on the initial discharge of α-MnO₂ cathode under hydrated environment was reported using density functional theory (DFT) in combination with complementary experiments, where the DFT predictions well described the experimental measurements on discharge voltages and manganese oxidation states. According to the DFT calculations, both protons (H⁺) and zinc ions (Zn²⁺) contribute to the discharging potentials of α-MnO₂ observed experimentally, where the presence of water plays an essential role during the process. This study provides valuable insights into the mechanistic understanding of the discharge of α-MnO₂ in hydrated ZIBs, emphasizing the crucial interplay among the H₂O molecules, the intercalated Zn²⁺ or H⁺ ions, and the Mn⁴⁺ ions on the tunnel wall to enhance the stability of discharged states and, thus, the electrochemical performances in hydrated ZIBs.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012673; SC0012704

OSTI ID:: 1839214

Report Number(s):: BNL--222592-2022-JAAM

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 50 Vol. 13; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (77)

Intercalated Water and Organic Molecules for Electrode Materials of Rechargeable Batteries Lee, Hyeon Jeong; Shin, Jaeho; Choi, Jang Wook Advanced Materials, Vol. 30, Issue 42 https://doi.org/10.1002/adma.201705851	journal	March 2018
Initiating Hexagonal MoO ₃ for Superb‐Stable and Fast NH ₄ ⁺ Storage Based on Hydrogen Bond Chemistry Liang, Guojin; Wang, Yanlei; Huang, Zhaodong Advanced Materials, Vol. 32, Issue 14 https://doi.org/10.1002/adma.201907802	journal	April 2020
Noninterference Revealing of “Layered to Layered” Zinc Storage Mechanism of δ‐MnO ₂ toward Neutral Zn–Mn Batteries with Superior Performance Jiang, Yuqi; Ba, Deliang; Li, Yuanyuan Advanced Science, Vol. 7, Issue 6 https://doi.org/10.1002/advs.201902795	journal	March 2020
Hydrated Intercalation for High‐Performance Aqueous Zinc Ion Batteries Shin, Jaeho; Choi, Dong Shin; Lee, Hyeon Jeong Advanced Energy Materials, Vol. 9, Issue 14 https://doi.org/10.1002/aenm.201900083	journal	February 2019
Toward a Reversible Mn ⁴⁺ /Mn ²⁺ Redox Reaction and Dendrite‐Free Zn Anode in Near‐Neutral Aqueous Zn/MnO ₂ Batteries via Salt Anion Chemistry Zeng, Xiaohui; Liu, Jiatu; Mao, Jianfeng Advanced Energy Materials, Vol. 10, Issue 32 https://doi.org/10.1002/aenm.201904163	journal	July 2020
Co ^2+/3+/4+ ‐Regulated Electron State of Mn‐O for Superb Aqueous Zinc‐Manganese Oxide Batteries Ji, Jie; Wan, Houzhao; Zhang, Bao Advanced Energy Materials, Vol. 11, Issue 6 https://doi.org/10.1002/aenm.202003203	journal	December 2020
An Electrolytic Zn–MnO ₂ Battery for High‐Voltage and Scalable Energy Storage Chao, Dongliang; Zhou, Wanhai; Ye, Chao Angewandte Chemie International Edition, Vol. 58, Issue 23 https://doi.org/10.1002/anie.201904174	journal	June 2019
High-Energy-Density Aqueous Magnesium-Ion Battery Based on a Carbon-Coated FeVO ₄ Anode and a Mg-OMS-1 Cathode Zhang, Hongyu; Ye, Ke; Zhu, Kai Chemistry - A European Journal, Vol. 23, Issue 67 https://doi.org/10.1002/chem.201703806	journal	November 2017
Interfacial adsorption–insertion mechanism induced by phase boundary toward better aqueous Zn‐ion battery Shan, Lutong; Wang, Yiren; Liang, Shuquan InfoMat, Vol. 3, Issue 9 https://doi.org/10.1002/inf2.12223	journal	June 2021
Graphene Scroll-Coated α-MnO ₂ Nanowires as High-Performance Cathode Materials for Aqueous Zn-Ion Battery Wu, Buke; Zhang, Guobin; Yan, Mengyu Small, Vol. 14, Issue 13 https://doi.org/10.1002/smll.201703850	journal	February 2018
Unravelling H ⁺ /Zn ²⁺ Synergistic Intercalation in a Novel Phase of Manganese Oxide for High‐Performance Aqueous Rechargeable Battery Zhao, Qinghe; Chen, Xin; Wang, Ziqi Small, Vol. 15, Issue 47 https://doi.org/10.1002/smll.201904545	journal	October 2019
H ⁺ ‐Insertion Boosted α‐MnO ₂ for an Aqueous Zn‐Ion Battery Gao, Xu; Wu, Hanwen; Li, Wenjie Small, Vol. 16, Issue 5 https://doi.org/10.1002/smll.201905842	journal	January 2020
Unraveling the Dissolution‐Mediated Reaction Mechanism of α‐MnO ₂ Cathodes for Aqueous Zn‐Ion Batteries Kim, Sung Joo; Wu, Daren; Sadique, Nahian Small, Vol. 16, Issue 48 https://doi.org/10.1002/smll.202005406	journal	November 2020
Zinc-manganese dioxide galvanic cell using zinc sulphate as electrolyte. Rechargeability of the cell Shoji, Takayuki; Hishinuma, Masakazu; Yamamoto, Takakazu Journal of Applied Electrochemistry, Vol. 18, Issue 4 https://doi.org/10.1007/BF01022245	journal	July 1988
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Degradation mechanism of layered MnO2 cathodes in Zn/ZnSO4/MnO2 rechargeable cells Kim, Sa Heum; Oh, Seung Mo Journal of Power Sources, Vol. 72, Issue 2 https://doi.org/10.1016/S0378-7753(97)02703-1	journal	April 1998
Memoir on the decomposition of water and of the bodies that it holds in solution by means of galvanic electricity de Grotthuss, C. J. T. Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1757, Issue 8 https://doi.org/10.1016/j.bbabio.2006.07.004	journal	August 2006
Manganese Sesquioxide as Cathode Material for Multivalent Zinc Ion Battery with High Capacity and Long Cycle Life Jiang, Baozheng; Xu, Chengjun; Wu, Changle Electrochimica Acta, Vol. 229 https://doi.org/10.1016/j.electacta.2017.01.163	journal	March 2017
Electrochemically induced spinel-layered phase transition of Mn3O4 in high performance neutral aqueous rechargeable zinc battery Hao, Jianwu; Mou, Jian; Zhang, Jingwen Electrochimica Acta, Vol. 259 https://doi.org/10.1016/j.electacta.2017.10.166	journal	January 2018
Graphene-Wrapped MnO/C Composites by MOFs-Derived as Cathode Material for Aqueous Zinc ion Batteries Tang, Fang; Gao, Jinyu; Ruan, Qiaoyun Electrochimica Acta, Vol. 353 https://doi.org/10.1016/j.electacta.2020.136570	journal	September 2020
The impact of battery energy storage for renewable energy power grids in Australia Keck, Felix; Lenzen, Manfred; Vassallo, Anthony Energy, Vol. 173 https://doi.org/10.1016/j.energy.2019.02.053	journal	April 2019
γ-MnO2 nanorods/graphene composite as efficient cathode for advanced rechargeable aqueous zinc-ion battery Wang, Chao; Zeng, Yinxiang; Xiao, Xiang Journal of Energy Chemistry, Vol. 43 https://doi.org/10.1016/j.jechem.2019.08.011	journal	April 2020
Thermal runaway caused fire and explosion of lithium ion battery Wang, Qingsong; Ping, Ping; Zhao, Xuejuan Journal of Power Sources, Vol. 208 https://doi.org/10.1016/j.jpowsour.2012.02.038	journal	June 2012
Zn/MnO2 battery chemistry with dissolution-deposition mechanism Guo, Xun; Zhou, Jiang; Bai, Chaolei Materials Today Energy, Vol. 16 https://doi.org/10.1016/j.mtener.2020.100396	journal	June 2020
Tuning phase evolution of β-MnO2 during microwave hydrothermal synthesis for high-performance aqueous Zn ion battery Liu, Mingqiang; Zhao, Qinghe; Liu, Hao Nano Energy, Vol. 64 https://doi.org/10.1016/j.nanoen.2019.103942	journal	October 2019
The effects of vanadium substitution on one-dimensional tunnel structures of cryptomelane: Combined TEM and DFT study Yang, Shi-Ze; Tallman, Killian R.; Liu, Ping Nano Energy, Vol. 71 https://doi.org/10.1016/j.nanoen.2020.104571	journal	May 2020
Investigation of α-MnO ₂ Tunneled Structures as Model Cation Hosts for Energy Storage Housel, Lisa M.; Wang, Lei; Abraham, Alyson Accounts of Chemical Research, Vol. 51, Issue 3 https://doi.org/10.1021/acs.accounts.7b00478	journal	February 2018
Toward the Understanding of the Reaction Mechanism of Zn/MnO ₂ Batteries Using Non-alkaline Aqueous Electrolytes Kim, Sung Joo; Wu, Daren; Housel, Lisa M. Chemistry of Materials, Vol. 33, Issue 18 https://doi.org/10.1021/acs.chemmater.1c01542	journal	September 2021
Probing the Release and Uptake of Water in α-MnO ₂ · x H ₂ O Yang, Zhenzhen; Ford, Denise C.; Park, Joong Sun Chemistry of Materials, Vol. 29, Issue 4 https://doi.org/10.1021/acs.chemmater.6b03721	journal	February 2017
Mechanism of Zn Insertion into Nanostructured δ-MnO ₂ : A Nonaqueous Rechargeable Zn Metal Battery Han, Sang-Don; Kim, Soojeong; Li, Dongguo Chemistry of Materials, Vol. 29, Issue 11 https://doi.org/10.1021/acs.chemmater.7b00852	journal	May 2017
Active Materials for Aqueous Zinc Ion Batteries: Synthesis, Crystal Structure, Morphology, and Electrochemistry Jia, Xiaoxiao; Liu, Chaofeng; Neale, Zachary G. Chemical Reviews, Vol. 120, Issue 15 https://doi.org/10.1021/acs.chemrev.9b00628	journal	July 2020
Transition Metal Substitution of Hollandite α-MnO ₂ : Enhanced Potential and Structural Stability on Lithiation from First-Principles Calculation Brady, Alexander B.; Tallman, Killian R.; Takeuchi, Esther S. The Journal of Physical Chemistry C, Vol. 123, Issue 41 https://doi.org/10.1021/acs.jpcc.9b05376	journal	September 2019
Boosted Charge Transfer in Twinborn α-(Mn ₂ O ₃ –MnO ₂ ) Heterostructures: Toward High-Rate and Ultralong-Life Zinc-Ion Batteries Long, Jun; Yang, Fuhua; Cuan, Jing ACS Applied Materials & Interfaces, Vol. 12, Issue 29 https://doi.org/10.1021/acsami.0c05812	journal	June 2020
Essential Role of Spinel ZnFe ₂ O ₄ Surfaces during Lithiation Guo, Haoyue; Marschilok, Amy C.; Takeuchi, Kenneth J. ACS Applied Materials & Interfaces, Vol. 10, Issue 41 https://doi.org/10.1021/acsami.8b12869	journal	September 2018
Deliberate Modification of Fe ₃ O ₄ Anode Surface Chemistry: Impact on Electrochemistry Wang, Lei; Housel, Lisa M.; Bock, David C. ACS Applied Materials & Interfaces, Vol. 11, Issue 22 https://doi.org/10.1021/acsami.8b21273	journal	May 2019
Functioning Mechanism of the Secondary Aqueous Zn-β-MnO ₂ Battery Li, Longyan; Hoang, Tuan K. A.; Zhi, Jian ACS Applied Materials & Interfaces, Vol. 12, Issue 11 https://doi.org/10.1021/acsami.9b22758	journal	February 2020
Electrochemically Induced Structural Transformation in a γ-MnO ₂ Cathode of a High Capacity Zinc-Ion Battery System Alfaruqi, Muhammad H.; Mathew, Vinod; Gim, Jihyeon Chemistry of Materials, Vol. 27, Issue 10 https://doi.org/10.1021/cm504717p	journal	May 2015
Facile Controlled Synthesis of MnO ₂ Nanostructures of Novel Shapes and Their Application in Batteries Cheng, Fangyi; Zhao, Jianzhi; Song, Wene Inorganic Chemistry, Vol. 45, Issue 5 https://doi.org/10.1021/ic051715b	journal	March 2006
Enhancing CO ₂ Electroreduction with the Metal–Oxide Interface Gao, Dunfeng; Zhang, Yi; Zhou, Zhiwen Journal of the American Chemical Society, Vol. 139, Issue 16 https://doi.org/10.1021/jacs.7b00102	journal	April 2017
Zn/MnO ₂ Battery Chemistry With H ⁺ and Zn ²⁺ Coinsertion Sun, Wei; Wang, Fei; Hou, Singyuk Journal of the American Chemical Society, Vol. 139, Issue 29 https://doi.org/10.1021/jacs.7b04471	journal	July 2017
Suppressed Activation Energy for Interfacial Charge Transfer of a Prussian Blue Analog Thin Film Electrode with Hydrated Ions (Li ⁺ , Na ⁺ , and Mg ²⁺ ) Mizuno, Yoshifumi; Okubo, Masashi; Hosono, Eiji The Journal of Physical Chemistry C, Vol. 117, Issue 21 https://doi.org/10.1021/jp311616s	journal	May 2013
Progress on the proton-radius puzzle Karr, Jean-Philippe; Marchand, Dominique Nature, Vol. 575, Issue 7781 https://doi.org/10.1038/d41586-019-03364-z	journal	November 2019
Value of storage technologies for wind and solar energy Braff, William A.; Mueller, Joshua M.; Trancik, Jessika E. Nature Climate Change, Vol. 6, Issue 10 https://doi.org/10.1038/nclimate3045	journal	June 2016
Reversible aqueous zinc/manganese oxide energy storage from conversion reactions Pan, Huilin; Shao, Yuyan; Yan, Pengfei Nature Energy, Vol. 1, Issue 5 https://doi.org/10.1038/nenergy.2016.39	journal	April 2016
Towards a calcium-based rechargeable battery Ponrouch, A.; Frontera, C.; Bardé, F. Nature Materials, Vol. 15, Issue 2 https://doi.org/10.1038/nmat4462	journal	October 2015
Computational understanding of Li-ion batteries Urban, Alexander; Seo, Dong-Hwa; Ceder, Gerbrand npj Computational Materials, Vol. 2, Issue 1 https://doi.org/10.1038/npjcompumats.2016.2	journal	March 2016
Polyaniline-intercalated manganese dioxide nanolayers as a high-performance cathode material for an aqueous zinc-ion battery Huang, Jianhang; Wang, Zhuo; Hou, Mengyan Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04949-4	journal	July 2018
Combined economic and technological evaluation of battery energy storage for grid applications Davies, D. M.; Verde, M. G.; Mnyshenko, O. Nature Energy, Vol. 4, Issue 1 https://doi.org/10.1038/s41560-018-0290-1	journal	December 2018
Diffusion-free Grotthuss topochemistry for high-rate and long-life proton batteries Wu, Xianyong; Hong, Jessica J.; Shin, Woochul Nature Energy, Vol. 4, Issue 2 https://doi.org/10.1038/s41560-018-0309-7	journal	January 2019
Regulation of synaptic plasticity and cognition by SUMO in normal physiology and Alzheimer's disease Lee, Linda; Dale, Elena; Staniszewski, Agnes Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep07190	journal	December 2014
Elucidating the intercalation mechanism of zinc ions into α-MnO ₂ for rechargeable zinc batteries Lee, Boeun; Lee, Hae Ri; Kim, Haesik Chemical Communications, Vol. 51, Issue 45 https://doi.org/10.1039/C5CC02585K	journal	January 2015
A first principles study of spinel ZnFe ₂ O ₄ for electrode materials in lithium-ion batteries Guo, Haoyue; Zhang, Yiman; Marschilok, Amy C. Physical Chemistry Chemical Physics, Vol. 19, Issue 38 https://doi.org/10.1039/C7CP04590E	journal	January 2017
Origin of unusual spinel-to-layered phase transformation by crystal water Yang, Eunjeong; Kim, Heejin; Kim, Sangryun Chemical Science, Vol. 9, Issue 2 https://doi.org/10.1039/C7SC04114D	journal	January 2018
Synthesis of cryptomelane type α-MnO ₂ (K _x Mn ₈ O ₁₆ ) cathode materials with tunable K ⁺ content: the role of tunnel cation concentration on electrochemistry Poyraz, Altug S.; Huang, Jianping; Pelliccione, Christopher J. Journal of Materials Chemistry A, Vol. 5, Issue 32 https://doi.org/10.1039/C7TA03476H	journal	January 2017
Highly crystalline ramsdellite as a cathode material for near-neutral aqueous MnO ₂ /Zn batteries Stoševski, Ivan; Bonakdarpour, Arman; Cuadra, Faye Chemical Communications, Vol. 55, Issue 14 https://doi.org/10.1039/C8CC07805J	journal	January 2019
Crystal water for high performance layered manganese oxide cathodes in aqueous rechargeable zinc batteries Nam, Kwan Woo; Kim, Heejin; Choi, Jin Hyeok Energy & Environmental Science, Vol. 12, Issue 6 https://doi.org/10.1039/C9EE00718K	journal	January 2019
Quantitative temporally and spatially resolved X-ray fluorescence microprobe characterization of the manganese dissolution-deposition mechanism in aqueous Zn/α-MnO ₂ batteries Wu, Daren; Housel, Lisa M.; Kim, Sung Joo Energy & Environmental Science, Vol. 13, Issue 11 https://doi.org/10.1039/D0EE02168G	journal	January 2020
Water-induced formation of an alkali-ion dimer in cryptomelane nanorods Cheng, Shaobo; Sharma, Vidushi; Poyraz, Altug S. Chemical Science, Vol. 11, Issue 19 https://doi.org/10.1039/D0SC01517B	journal	January 2020
The rechargeable aluminum-ion battery Jayaprakash, N.; Das, S. K.; Archer, L. A. Chemical Communications, Vol. 47, Issue 47 https://doi.org/10.1039/c1cc15779e	journal	January 2011
Accurate and efficient algorithm for Bader charge integration Yu, Min; Trinkle, Dallas R. The Journal of Chemical Physics, Vol. 134, Issue 6 https://doi.org/10.1063/1.3553716	journal	February 2011
Integrated ‘all-in-one’ strategy to stabilize zinc anodes for high-performance zinc-ion batteries Li, Canpeng; Xie, Xuesong; Liu, Hui National Science Review https://doi.org/10.1093/nsr/nwab177	journal	September 2021
Inhomogeneous Electron Gas Hohenberg, P.; Kohn, W. Physical Review, Vol. 136, Issue 3B, p. B864-B871 https://doi.org/10.1103/PhysRev.136.B864	journal	November 1964
Self-Consistent Equations Including Exchange and Correlation Effects Kohn, W.; Sham, L. J. Physical Review, Vol. 140, Issue 4A, p. A1133-A1138 https://doi.org/10.1103/PhysRev.140.A1133	journal	November 1965
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Charge localization and ordering in A 2 Mn 8 O 16 hollandite group oxides: Impact of density functional theory approaches Kaltak, Merzuk; Fernández-Serra, Marivi; Hybertsen, Mark S. Physical Review Materials, Vol. 1, Issue 7 https://doi.org/10.1103/PhysRevMaterials.1.075401	journal	December 2017
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries Kang, Kisuk; Shirley Meng, Ying; Breger, Julien Science, Vol. 311, Issue 5763, p. 977-980 https://doi.org/10.1126/science.1122152	journal	February 2006
Single Crystal Growth of α-MnO ₂ Yamamoto, Naoichi; Endo, Tadashi; Shimada, Masahiko Japanese Journal of Applied Physics, Vol. 13, Issue 4 https://doi.org/10.1143/JJAP.13.723	journal	April 1974
Electrochemical Insertion of Magnesium in Metal Oxides and Sulfides from Aprotic Electrolytes Novák, Petr Journal of The Electrochemical Society, Vol. 140, Issue 1 https://doi.org/10.1149/1.2056075	journal	January 1993
A Facile Preparation of λ -MnO ₂ as Cathode Material for High-Performance Zinc-Manganese Redox Flow Battery Liu, Nana; K., Mohanapriya; Pan, Junqing Journal of The Electrochemical Society, Vol. 167, Issue 4 https://doi.org/10.1149/1945-7111/ab75c2	journal	January 2020
Theoretical Analysis on De-Solvation of Lithium, Sodium, and Magnesium Cations to Organic Electrolyte Solvents Okoshi, Masaki; Yamada, Yuki; Yamada, Atsuo Journal of The Electrochemical Society, Vol. 160, Issue 11 https://doi.org/10.1149/2.074311jes	journal	January 2013
Climate change and fossil fuel: An examination of risks for the energy industry and producer states Krane, Jim MRS Energy & Sustainability, Vol. 4, Issue 1 https://doi.org/10.1557/mre.2017.3	journal	April 2017
Lithium-Ion Battery Aspects on Fires in Electrified Vehicles on the Basis of Experimental Abuse Tests Larsson, Fredrik; Andersson, Petra; Mellander, Bengt-Erik Batteries, Vol. 2, Issue 2 https://doi.org/10.3390/batteries2020009	journal	April 2016
Nanostructured MnO₂ as Electrode Materials for Energy Storage Julien, Christian M.; Mauger, Alain Nanomaterials, Vol. 7, Issue 11, p. 396 https://doi.org/10.3390/nano7110396	journal	November 2017

Similar Records

Tuning Discharge Behavior of Hollandite α-MnO₂ in Hydrated Zinc Ion Battery by Transition Metal Substitution

Journal Article · Thu Jan 05 19:00:00 EST 2023 · Journal of Physical Chemistry. C · OSTI ID:1964073

Rational optimization of substituted α–MnO₂ cathode for aqueous zinc–ion battery

Journal Article · Tue May 21 20:00:00 EDT 2024 · Energy Storage (Online) · OSTI ID:2382639

A two-electron transfer mechanism of the Zn-doped δ-MnO₂ cathode toward aqueous Zn-ion batteries with ultrahigh capacity

Journal Article · Sun Feb 13 19:00:00 EST 2022 · Journal of Materials Chemistry. A · OSTI ID:1978847

Related Subjects

25 ENERGY STORAGE
chemical structure
discharge of proton/zinc
hollandite α-MnO2
hydration
intercalation
ions
molecules
transition metals
zinc-ion batteries

Discharging Behavior of Hollandite α-MnO2 in a Hydrated Zinc-Ion Battery

Citation Formats

References (77)

Similar Records

Related Subjects

Discharging Behavior of Hollandite α-MnO₂ in a Hydrated Zinc-Ion Battery