Gated Molecular Diffusion at Liquid–Liquid Interfaces

Li, Lianshun; Sun, Huilou; Li, Mingwei; Yang, Yang; Russell, Thomas P.; Shi, Shaowei

doi:10.1002/anie.202105500

Gated Molecular Diffusion at Liquid–Liquid Interfaces

Journal Article · Wed Jun 30 00:00:00 EDT 2021 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202105500· OSTI ID:1839018

Li, Lianshun ^[1]; Sun, Huilou ^[1]; Li, Mingwei ^[1]; Yang, Yang ^[1]; ^[2]; ^[1]

Beijing Univ. of Chemical Technology, Beijing (China). Beijing Advanced Innovation Center for Soft Matter Science and Engineering
Univ. of Massachusetts, Amherst, MA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

The jamming of nanoparticle surfactants (NPSs) at liquid-liquid interface imparts attractive properties to the interfacial assemblies and enables the structuring of liquids. Herein, we report photoresponsive supramolecular microcapsules with jammed NPS assemblies at the oil-water interface, taking advantage of host-guest molecular recognition. The permeability of the colloidal membrane can be effectively manipulated by switching the NPSs from a jammed state to an unjammed state with a photo trigger, leading to a controlled molecular diffusion and release, affording a versatile platform for the construction of next generation smart microcapsule systems.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); US Army Research Office (ARO); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1839018

Alternate ID(s):: OSTI ID: 1997278

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 32 Vol. 60; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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