Iron redox analysis of silicate-based minerals and glasses using synchrotron X-ray absorption and laboratory X-ray emission spectroscopy

Jahrman, Evan P.; Weaver, Jamie L.; Govind, Niranjan; Perestjuk, Marko; Seidler, Gerald T.

doi:10.1016/j.jnoncrysol.2021.121326

Title: Iron redox analysis of silicate-based minerals and glasses using synchrotron X-ray absorption and laboratory X-ray emission spectroscopy

Journal Article · Tue Feb 01 00:00:00 EST 2022 · Journal of Non-Crystalline Solids

DOI:https://doi.org/10.1016/j.jnoncrysol.2021.121326· OSTI ID:1838401

Jahrman, Evan P.; Weaver, Jamie L.; Govind, Niranjan; Perestjuk, Marko; Seidler, Gerald T.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: KC-030105172685; AC05- 76RL1830; SC0012704

OSTI ID:: 1838401

Journal Information:: Journal of Non-Crystalline Solids, Journal Name: Journal of Non-Crystalline Solids Vol. 577 Journal Issue: C; ISSN 0022-3093

Publisher:: ElsevierCopyright Statement

Country of Publication:: Netherlands

Language:: English

References (76)

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Spin state of ferric iron in MgSiO3 perovskite and its effect on elastic properties Catalli, Krystle; Shim, Sang-Heon; Prakapenka, Vitali B. Earth and Planetary Science Letters, Vol. 289, Issue 1-2 https://doi.org/10.1016/j.epsl.2009.10.029	journal	January 2010
Probing the 3d Spin Momentum with X-ray Emission Spectroscopy: The Case of Molecular-Spin Transitions Vankó, György; Neisius, Thomas; Molnár, Gábor The Journal of Physical Chemistry B, Vol. 110, Issue 24 https://doi.org/10.1021/jp0615961	journal	June 2006
The effect of redox state on the local structural environment of iron in silicate glasses: a combined XAFS spectroscopy, molecular dynamics, and bond valence study Farges, François; Lefrère, Yannick; Rossano, Stéphanie Journal of Non-Crystalline Solids, Vol. 344, Issue 3 https://doi.org/10.1016/j.jnoncrysol.2004.07.050	journal	October 2004
Wet Chemical and UV-Vis Spectrometric Iron Speciation in Quenched Low and Intermediate Level Nuclear Waste Glasses Weaver, Jamie L.; Wall, Nathalie A.; McCloy, John S. MRS Proceedings, Vol. 1744 https://doi.org/10.1557/opl.2015.481	journal	January 2015
High pressure experimental calibration of the olivine-orthopyroxene-spinel oxygen geobarometer: implications for the oxidation state of the upper mantle Ballhaus, C.; Berry, R. F.; Green, D. H. Contributions to Mineralogy and Petrology, Vol. 107, Issue 1 https://doi.org/10.1007/BF00311183	journal	March 1991
Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido Complex Padamati, Sandeep K.; Angelone, Davide; Draksharapu, Apparao Journal of the American Chemical Society, Vol. 139, Issue 25 https://doi.org/10.1021/jacs.7b04158	journal	June 2017
A feasibility investigation of speciation by Fe K-edge XANES using a laboratory X-ray absorption spectrometer Mottram, L. M.; Cafferkey, S.; Mason, A. R. Journal of Geosciences https://doi.org/10.3190/jgeosci.299	journal	April 2020
NWChem: Past, present, and future Aprà, E.; Bylaska, E. J.; de Jong, W. A. The Journal of Chemical Physics, Vol. 152, Issue 18 https://doi.org/10.1063/5.0004997	journal	May 2020
Separate zones of sulfate and sulfide release from subducted mafic oceanic crust Tomkins, Andrew G.; Evans, Katy A. Earth and Planetary Science Letters, Vol. 428 https://doi.org/10.1016/j.epsl.2015.07.028	journal	October 2015
Robust optic alignment in a tilt-free implementation of the Rowland circle spectrometer Mortensen, Devon R.; Seidler, Gerald T. Journal of Electron Spectroscopy and Related Phenomena, Vol. 215 https://doi.org/10.1016/j.elspec.2016.11.006	journal	February 2017
Determination of the oxidation state of iron in Mid-Ocean Ridge basalt glasses by Raman spectroscopy Le Losq, Charles; Berry, Andrew J.; Kendrick, Mark A. American Mineralogist, Vol. 104, Issue 7 https://doi.org/10.2138/am-2019-6887	journal	July 2019
Johann-type laboratory-scale x-ray absorption spectrometer with versatile detection modes Honkanen, Ari-Pekka; Ollikkala, Sami; Ahopelto, Taru Review of Scientific Instruments, Vol. 90, Issue 3 https://doi.org/10.1063/1.5084049	journal	March 2019
Modern X-ray spectroscopy: XAS and XES in the laboratory Zimmermann, Patric; Peredkov, Sergey; Abdala, Paula Macarena Coordination Chemistry Reviews, Vol. 423 https://doi.org/10.1016/j.ccr.2020.213466	journal	November 2020
Valence-to-core X-ray emission spectroscopy of vanadium oxide and lithiated vanadyl phosphate materials Jahrman, Evan P.; Holden, William M.; Govind, Niranjan Journal of Materials Chemistry A, Vol. 8, Issue 32 https://doi.org/10.1039/D0TA03620J	journal	January 2020
Aminophosphines as Versatile Precursors for the Synthesis of Metal Phosphide Nanocrystals Mundy, M. Elizabeth; Ung, David; Lai, Nathan L. Chemistry of Materials, Vol. 30, Issue 15 https://doi.org/10.1021/acs.chemmater.8b02206	journal	July 2018
Oxidation state and coordination of Fe in minerals: An Fe K- XANES spectroscopic study Wilke, Max; Farges, François; Petit, Pierre-Emmanuel American Mineralogist, Vol. 86, Issue 5-6 https://doi.org/10.2138/am-2001-5-612	journal	May 2001
Fe (super 3+) distribution in oxidized olivine; a synchrotron micro-XANES study Dyar, M.; Delaney, Jeremy S.; Sutton, Stephen R. American Mineralogist, Vol. 83, Issue 11-12 Part 1 https://doi.org/10.2138/am-1998-11-1227	journal	December 1998
Maximum Overlap Atomic and Molecular Orbitals Lykos, Peter G.; Schmeising, Howard N. The Journal of Chemical Physics, Vol. 35, Issue 1 https://doi.org/10.1063/1.1731901	journal	July 1961
Electronic State of Iron in Hemoglobin, Myoglobin, and Derivatives, as Inferred from X‐Ray Fluorescence Spectra Koster, A. S. The Journal of Chemical Physics, Vol. 56, Issue 6 https://doi.org/10.1063/1.1677655	journal	March 1972
High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes—electronic and structural information Glatzel, Pieter; Bergmann, Uwe Coordination Chemistry Reviews, Vol. 249, Issue 1-2 https://doi.org/10.1016/j.ccr.2004.04.011	journal	January 2005
Hard x-ray emission spectroscopy: a powerful tool for the characterization of magnetic semiconductors Rovezzi, M.; Glatzel, P. Semiconductor Science and Technology, Vol. 29, Issue 2 https://doi.org/10.1088/0268-1242/29/2/023002	journal	January 2014
Laboratory-Based X-ray Absorption Spectroscopy on a Working Pouch Cell Battery at Industrially-Relevant Charging Rates Jahrman, Evan P.; Pellerin, Lisa A.; Ditter, Alexander S. Journal of The Electrochemical Society, Vol. 166, Issue 12 https://doi.org/10.1149/2.0721912jes	journal	January 2019
Effect of oxygen fugacity on the coordination and oxidation state of iron in alkali bearing silicate melts Knipping, Jaayke L.; Behrens, Harald; Wilke, Max Chemical Geology, Vol. 411 https://doi.org/10.1016/j.chemgeo.2015.07.004	journal	September 2015
A laboratory-based hard x-ray monochromator for high-resolution x-ray emission spectroscopy and x-ray absorption near edge structure measurements Seidler, G. T.; Mortensen, D. R.; Remesnik, A. J. Review of Scientific Instruments, Vol. 85, Issue 11 https://doi.org/10.1063/1.4901599	journal	November 2014
Fe-oxidation state in alkali-trisilicate glasses - A Raman spectroscopic study Welsch, Anna-Maria; Knipping, Jaayke L.; Behrens, Harald Journal of Non-Crystalline Solids, Vol. 471 https://doi.org/10.1016/j.jnoncrysol.2017.04.033	journal	September 2017
Laboratory von Hámos X-ray spectroscopy for routine sample characterization Németh, Zoltán; Szlachetko, Jakub; Bajnóczi, Éva G. Review of Scientific Instruments, Vol. 87, Issue 10 https://doi.org/10.1063/1.4964098	journal	October 2016
Probing Surface Defects of InP Quantum Dots Using Phosphorus Kα and Kβ X-ray Emission Spectroscopy Stein, Jennifer L.; Holden, William M.; Venkatesh, Amrit Chemistry of Materials, Vol. 30, Issue 18 https://doi.org/10.1021/acs.chemmater.8b02590	journal	August 2018
Calcium Valence-to-Core X-ray Emission Spectroscopy: A Sensitive Probe of Oxo Protonation in Structural Models of the Oxygen-Evolving Complex Mathe, Zachary; Pantazis, Dimitrios A.; Lee, Heui Beom Inorganic Chemistry, Vol. 58, Issue 23 https://doi.org/10.1021/acs.inorgchem.9b02866	journal	November 2019
Corresponding Orbitals and the Nonorthogonality Problem in Molecular Quantum Mechanics King, Harry F.; Stanton, Richard E.; Kim, Hojing The Journal of Chemical Physics, Vol. 47, Issue 6 https://doi.org/10.1063/1.1712221	journal	September 1967
A Mössbauer study of the oxidation state of Fe in silicate melts Jayasuriya, Kasthuri D.; O’Neill, Hugh St. C.; Berry, Andrew J. American Mineralogist, Vol. 89, Issue 11-12 https://doi.org/10.2138/am-2004-11-1203	journal	November 2004
Micro-Raman determination of iron redox state in dry natural glasses: Application to peralkaline rhyolites and basalts Di Muro, Andrea; Métrich, Nicole; Mercier, Maxime Chemical Geology, Vol. 259, Issue 1-2 https://doi.org/10.1016/j.chemgeo.2008.08.013	journal	February 2009
Factors Defining the Intercalation Electrochemistry of CaFe ₂ O ₄ -Type Manganese Oxides Nolis, Gene; Gallardo-Amores, José M.; Serrano-Sevillano, Jon Chemistry of Materials, Vol. 32, Issue 19 https://doi.org/10.1021/acs.chemmater.0c01858	journal	August 2020
Valence and spin states of iron are invisible in Earth’s lower mantle Liu, Jiachao; Dorfman, Susannah M.; Zhu, Feng Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03671-5	journal	March 2018
NWChem: A comprehensive and scalable open-source solution for large scale molecular simulations Valiev, M.; Bylaska, E. J.; Govind, N. Computer Physics Communications, Vol. 181, Issue 9, p. 1477-1489 https://doi.org/10.1016/j.cpc.2010.04.018	journal	September 2010
Probing Sulfur Chemical and Electronic Structure with Experimental Observation and Quantitative Theoretical Prediction of Kα and Valence-to-Core Kβ X-ray Emission Spectroscopy Holden, William M.; Jahrman, Evan P.; Govind, Niranjan The Journal of Physical Chemistry A, Vol. 124, Issue 26 https://doi.org/10.1021/acs.jpca.0c04195	journal	June 2020
X-ray microprobe analysis of iron oxidation states in silicates and oxides using X-ray absorption near edge structure (XANES) Bajt, S.; Sutton, S. R.; Delaney, J. S. Geochimica et Cosmochimica Acta, Vol. 58, Issue 23 https://doi.org/10.1016/0016-7037(94)90305-0	journal	December 1994
Oxidation state of iron in silicate glasses and melts: a thermochemical model Ottonello, Giulio; Moretti, Roberto; Marini, Luigi Chemical Geology, Vol. 174, Issue 1-3 https://doi.org/10.1016/S0009-2541(00)00314-4	journal	April 2001
A laboratory spectrometer for high throughput X-ray emission spectroscopy in catalysis research Malzer, Wolfgang; Grötzsch, Daniel; Gnewkow, Richard Review of Scientific Instruments, Vol. 89, Issue 11 https://doi.org/10.1063/1.5035171	journal	November 2018
Laboratory-scale X-ray absorption spectroscopy approach for actinide research: Experiment at the uranium L3-edge Bès, R.; Ahopelto, T.; Honkanen, A. -P. Journal of Nuclear Materials, Vol. 507 https://doi.org/10.1016/j.jnucmat.2018.04.034	journal	August 2018
Ferric-ferrous equilibria in Na2O-FeO-Fe2O3-SiO2 melts: Effects of analytical techniques on derived partial molar volumes Lange, Rebecca A.; Carmichael, Ian S. E. Geochimica et Cosmochimica Acta, Vol. 53, Issue 9 https://doi.org/10.1016/0016-7037(89)90343-8	journal	September 1989
Sulfur Speciation in Biochars by Very High Resolution Benchtop Kα X-ray Emission Spectroscopy Holden, William M.; Seidler, Gerald T.; Cheah, Singfoong The Journal of Physical Chemistry A, Vol. 122, Issue 23 https://doi.org/10.1021/acs.jpca.8b02816	journal	May 2018
The effect of oxidation state on the viscosity of melts in the system Na2O-FeO-Fe2O3-SiO2 Dingwell, Donald B.; Virgo, David Geochimica et Cosmochimica Acta, Vol. 51, Issue 2 https://doi.org/10.1016/0016-7037(87)90231-6	journal	February 1987
Resonant X-ray spectroscopy to study K absorption pre-edges in 3d transition metal compounds Glatzel, P.; Sikora, M.; Fernández-García, M. The European Physical Journal Special Topics, Vol. 169, Issue 1 https://doi.org/10.1140/epjst/e2009-00994-7	journal	March 2009
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy Weigend, Florian; Ahlrichs, Reinhart Physical Chemistry Chemical Physics, Vol. 7, Issue 18, p. 3297-3305 https://doi.org/10.1039/b508541a	journal	January 2005
Accurate predictions of iron redox state in silicate glasses: A multivariate approach using X-ray absorption spectroscopy Dyar, M. Darby; McCanta, Molly; Breves, Elly American Mineralogist, Vol. 101, Issue 3 https://doi.org/10.2138/am-2016-5555	journal	March 2016
Valence‐to‐core X‐ray emission spectroscopy of titanium compounds using energy dispersive detectors Miaja‐Avila, Luis; O'Neil, Galen C.; Joe, Young Il X-Ray Spectrometry, Vol. 50, Issue 1 https://doi.org/10.1002/xrs.3183	journal	July 2020
Emergent superconductivity in an iron-based honeycomb lattice initiated by pressure-driven spin-crossover Wang, Yonggang; Ying, Jianjun; Zhou, Zhengyang Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04326-1	journal	May 2018
Effective intermediate-spin iron in O ₂ -transporting heme proteins Schuth, Nils; Mebs, Stefan; Huwald, Dennis Proceedings of the National Academy of Sciences, Vol. 114, Issue 32 https://doi.org/10.1073/pnas.1706527114	journal	July 2017
Upper mantle oxidation state: Ferric iron contents of Iherzolite spinels by 57Fe Mössbauer spectroscopy and resultant oxygen fugacities J. Wood, Bernard; Virgo, David Geochimica et Cosmochimica Acta, Vol. 53, Issue 6 https://doi.org/10.1016/0016-7037(89)90062-8	journal	June 1989
Observation of iron spin-states using tabletop x-ray emission spectroscopy and microcalorimeter sensors Joe, Y. I.; O’Neil, G. C.; Miaja-Avila, L. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 49, Issue 2 https://doi.org/10.1088/0953-4075/49/2/024003	journal	December 2015
Probing Valence Orbital Composition with Iron Kβ X-ray Emission Spectroscopy Lee, Nicole; Petrenko, Taras; Bergmann, Uwe Journal of the American Chemical Society, Vol. 132, Issue 28 https://doi.org/10.1021/ja101281e	journal	July 2010
Spectroscopic and Quantum Chemical Investigation of Benzene-1,2-dithiolate-Coordinated Diiron Complexes with Relevance to Dinitrogen Activation Kalläne, Sabrina I.; Hahn, Anselm W.; Weyhermüller, Thomas Inorganic Chemistry, Vol. 58, Issue 8 https://doi.org/10.1021/acs.inorgchem.9b00177	journal	March 2019
Diluted Fe 3+ in silicate glasses: Structural effects of Fe-redox state and matrix composition. An optical absorption and X-band/Q-band EPR study Vercamer, Vincent; Lelong, Gérald; Hijiya, Hiroyuki Journal of Non-Crystalline Solids, Vol. 428 https://doi.org/10.1016/j.jnoncrysol.2015.08.010	journal	November 2015
X-ray K-edge absorption spectra of Fe minerals and model compounds: Near-edge structure Waychunas, Glenn A.; Apted, Michael J.; Brown, Gordon E. Physics and Chemistry of Minerals, Vol. 10, Issue 1 https://doi.org/10.1007/BF01204319	journal	January 1983
A novel von Hamos spectrometer for efficient X-ray emission spectroscopy in the laboratory Anklamm, Lars; Schlesiger, Christopher; Malzer, Wolfgang Review of Scientific Instruments, Vol. 85, Issue 5 https://doi.org/10.1063/1.4875986	journal	May 2014
XANES calibrations for the oxidation state of iron in a silicate glass Berry, Andrew J.; O’Neill, Hugh St. C.; Jayasuriya, Kasthuri D. American Mineralogist, Vol. 88, Issue 7 https://doi.org/10.2138/am-2003-0704	journal	July 2003
Oxidising agents in sub-arc mantle melts link slab devolatilisation and arc magmas Bénard, Antoine; Klimm, Kevin; Woodland, Alan B. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05804-2	journal	August 2018
The Fe3+/ΣFe ratios of MORB glasses and their implications for mantle melting Bézos, Antoine; Humler, Eric Geochimica et Cosmochimica Acta, Vol. 69, Issue 3 https://doi.org/10.1016/j.gca.2004.07.026	journal	February 2005
Determination of the iron oxidation state in basaltic glasses using XANES at the K-edge Wilke, Max; Partzsch, Georg M.; Bernhardt, Ralf Chemical Geology, Vol. 220, Issue 1-2 https://doi.org/10.1016/j.chemgeo.2005.03.004	journal	July 2005
Structural engineering of hydrated vanadium oxide cathode by K+ incorporation for high-capacity and long-cycling aqueous zinc ion batteries Tian, Meng; Liu, Chaofeng; Zheng, Jiqi Energy Storage Materials, Vol. 29 https://doi.org/10.1016/j.ensm.2020.03.024	journal	August 2020
A re-assessment of the oxidation state of iron in MORB glasses Berry, Andrew J.; Stewart, Glen A.; O'Neill, Hugh St. C. Earth and Planetary Science Letters, Vol. 483 https://doi.org/10.1016/j.epsl.2017.11.032	journal	February 2018
Charge-transfer effect on the linewidth of Fe K α x-ray fluorescence spectra Kawai, Jun; Suzuki, Chikashi; Adachi, Hirohiko Physical Review B, Vol. 50, Issue 16 https://doi.org/10.1103/PhysRevB.50.11347	journal	October 1994
The oxidation state of iron determined by Fe K-edge XANES—application to iron gall ink in historical manuscripts Wilke, Max; Hahn, Oliver; Woodland, Alan B. Journal of Analytical Atomic Spectrometry, Vol. 24, Issue 10 https://doi.org/10.1039/b904438h	journal	January 2009
A mail-in and user facility for X-ray absorption near-edge structure: the CEI-XANES laboratory X-ray spectrometer at the University of Washington Ditter, Alexander S.; Jahrman, Evan P.; Bradshaw, Liam R. Journal of Synchrotron Radiation, Vol. 26, Issue 6 https://doi.org/10.1107/S1600577519012839	journal	October 2019
The compressibility of silicate liquids containing Fe2O3 and the effect of composition, temperature, oxygen fugacity and pressure on their redox states Kress, Victor C.; Carmichael, Ian S. E. Contributions to Mineralogy and Petrology, Vol. 108, Issue 1-2 https://doi.org/10.1007/BF00307328	journal	July 1991
The effect of dissolved water on the oxidation state of iron in natural silicate liquids Moore, Gordon; Righter, Kevin; Carmichael, I. S. E. Contributions to Mineralogy and Petrology, Vol. 120, Issue 2 https://doi.org/10.1007/BF00287114	journal	June 1995
Iron K-edge X-ray absorption near-edge structure spectroscopy of aerodynamically levitated silicate melts and glasses Alderman, O. L. G.; Wilding, M. C.; Tamalonis, A. Chemical Geology, Vol. 453 https://doi.org/10.1016/j.chemgeo.2017.01.020	journal	March 2017
An improved laboratory-based x-ray absorption fine structure and x-ray emission spectrometer for analytical applications in materials chemistry research Jahrman, Evan P.; Holden, William M.; Ditter, Alexander S. Review of Scientific Instruments, Vol. 90, Issue 2 https://doi.org/10.1063/1.5049383	journal	February 2019
High resolution x‐ray absorption spectroscopy with absolute energy calibration for the determination of absorption edge energies Kraft, S.; Stümpel, J.; Becker, P. Review of Scientific Instruments, Vol. 67, Issue 3 https://doi.org/10.1063/1.1146657	journal	March 1996
In-situ X-Ray Absorption Near Edge Structure Spectroscopy of a Solid Catalyst using a Laboratory-Based Set-up Moya-Cancino, José G.; Honkanen, Ari-Pekka; van der Eerden, Ad M. J. ChemCatChem, Vol. 11, Issue 3 https://doi.org/10.1002/cctc.201801822	journal	January 2019
High-precision determination of iron oxidation state in silicate glasses using XANES Cottrell, Elizabeth; Kelley, Katherine A.; Lanzirotti, Antonio Chemical Geology, Vol. 268, Issue 3-4 https://doi.org/10.1016/j.chemgeo.2009.08.008	journal	November 2009
Effect of Batch Melting Temperature and Raw Material on Iron Redox State in Sodium Silicate Glasses Mirhadi, Bahman; Mehdikhani, Behzad Journal of the Korean Ceramic Society, Vol. 48, Issue 2 https://doi.org/10.4191/KCERS.2011.48.2.117	journal	March 2011
Fast and reversible zinc ion intercalation in Al-ion modified hydrated vanadate Zheng, Jiqi; Liu, Chaofeng; Tian, Meng Nano Energy, Vol. 70 https://doi.org/10.1016/j.nanoen.2020.104519	journal	April 2020
Tailoring Energy and Power Density through Controlling the Concentration of Oxygen Vacancies in V ₂ O ₅ /PEDOT Nanocable-Based Supercapacitors Bi, Wenchao; Jahrman, Evan; Seidler, Gerald ACS Applied Materials & Interfaces, Vol. 11, Issue 18 https://doi.org/10.1021/acsami.9b03830	journal	April 2019
Determination of Hexavalent Chromium Fractions in Plastics Using Laboratory-Based, High-Resolution X-ray Emission Spectroscopy Jahrman, Evan P.; Seidler, Gerald T.; Sieber, John R. Analytical Chemistry, Vol. 90, Issue 11 https://doi.org/10.1021/acs.analchem.8b00302	journal	April 2018

Similar Records

Iron redox analysis of silicate-based minerals and glasses using synchrotron X-ray absorption and laboratory X-ray emission spectroscopy

Journal Article · Sun Jan 01 00:00:00 EST 2023 · Journal of Non-Crystalline Solids · OSTI ID:1838401

Jahrman, E; Weaver, J.; Govind, N.; +2 more

Ultrafast x-ray pump x-ray probe transient absorption spectroscopy: A computational study and proposed experiment probing core-valence electronic correlations in solvated complexes

Journal Article · Wed Jun 02 00:00:00 EDT 2021 · Journal of Chemical Physics · OSTI ID:1838401

Liekhus-Schmaltz, Chelsea E.; Ho, Phay J.; Weakly, Robert B.; +4 more

Accurate predictions of iron redox state in silicate glasses: A multivariate approach using X-ray absorption spectroscopy

Journal Article · Tue Mar 08 00:00:00 EST 2016 · American Mineralogist · OSTI ID:1838401

Dyar, M. Darby; McCanta, Molly; Breves, Elly; +2 more

Title: Iron redox analysis of silicate-based minerals and glasses using synchrotron X-ray absorption and laboratory X-ray emission spectroscopy

Citation Formats

References (76)

Similar Records

Related Subjects