Amphipathic Binder Integrating Ultrathin and Highly Ion-Conductive Sulfide Membrane for Cell-Level High-Energy-Density All-Solid-State Batteries

Cao, Daxian; Li, Qiang; Sun, Xiao; Wang, Ying; Zhao, Xianhui; Cakmak, Ercan; Liang, Wentao; Anderson, Alexander; Ozcan, Soydan; Zhu, Hongli

doi:10.1002/adma.202105505

Amphipathic Binder Integrating Ultrathin and Highly Ion-Conductive Sulfide Membrane for Cell-Level High-Energy-Density All-Solid-State Batteries

Journal Article · Fri Oct 15 00:00:00 EDT 2021 · Advanced Materials

DOI:https://doi.org/10.1002/adma.202105505· OSTI ID:1837859

^[1]; Li, Qiang ^[1]; Sun, Xiao ^[1]; Wang, Ying ^[1]; Zhao, Xianhui ^[2]; ^[2]; Liang, Wentao ^[3]; Anderson, Alexander ^[1]; ^[2]; Zhu, Hongli ^[1]

Northeastern Univ., Boston, MA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Northeastern Univ., Burlington, MA (United States). Kostas Advanced Nanocharacterization Facility (KANCF)

Current sulfide solid-state electrolyte (SE) membranes utilized in all-solid-state lithium batteries (ASLBs) have a high thickness (0.5–1.0 mm) and low ion conductance (<25 mS), which limit the cell-level energy and power densities. Therefore, based on ethyl cellulose's unique amphipathic molecular structure, superior thermal stability, and excellent binding capability, this work fabricates a freestanding SE membrane with an ultralow thickness of 47 µm. With ethyl cellulose as an effective disperser and a binder, the Li₆PS₅Cl is uniformly dispersed in toluene and possesses superior film formability. In addition, an ultralow areal resistance of 4.32 Ω cm^-2 and a remarkable ion conductance of 291 mS (one order higher than the state-of-the-art sulfide SE membrane) are achieved. The ASLBs assembled with this SE membrane deliver cell-level high gravimetric and volumetric energy densities of 175 Wh kg^-1 and 675 Wh L^-1, individually.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1837859

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 52 Vol. 33; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (33)

Enhancement of the High-Rate Capability of Solid-State Lithium Batteries by Nanoscale Interfacial Modification Ohta, N.; Takada, K.; Zhang, L. Advanced Materials, Vol. 18, Issue 17, p. 2226-2229 https://doi.org/10.1002/adma.200502604	journal	September 2006
Solid‐State Batteries: Sulfide‐Based Solid‐State Electrolytes: Synthesis, Stability, and Potential for All‐Solid‐State Batteries (Adv. Mater. 44/2019) Zhang, Qing; Cao, Daxian; Ma, Yi Advanced Materials, Vol. 31, Issue 44 https://doi.org/10.1002/adma.201970311	journal	September 2019
In Situ Synthesis of a Hierarchical All-Solid-State Electrolyte Based on Nitrile Materials for High-Performance Lithium-Ion Batteries Zhou, Dong; He, Yan-Bing; Liu, Ruliang Advanced Energy Materials, Vol. 5, Issue 15 https://doi.org/10.1002/aenm.201500353	journal	May 2015
Slurry‐Fabricable Li ⁺ ‐Conductive Polymeric Binders for Practical All‐Solid‐State Lithium‐Ion Batteries Enabled by Solvate Ionic Liquids Oh, Dae Yang; Nam, Young Jin; Park, Kern Ho Advanced Energy Materials, Vol. 9, Issue 16 https://doi.org/10.1002/aenm.201802927	journal	February 2019
Solid‐State Li–Metal Batteries: Challenges and Horizons of Oxide and Sulfide Solid Electrolytes and Their Interfaces Kim, Kun Joong; Balaish, Moran; Wadaguchi, Masaki Advanced Energy Materials, Vol. 11, Issue 1 https://doi.org/10.1002/aenm.202002689	journal	November 2020
Water‐Mediated Synthesis of a Superionic Halide Solid Electrolyte Li, Xiaona; Liang, Jianwen; Chen, Ning Angewandte Chemie International Edition, Vol. 58, Issue 46 https://doi.org/10.1002/anie.201909805	journal	November 2019
Simulation of transverse wood compression using a large-deformation, hyperelastic–plastic material model Aimene, Yamina E.; Nairn, John A. Wood Science and Technology, Vol. 49, Issue 1 https://doi.org/10.1007/s00226-014-0676-6	journal	October 2014
Thermal runaway mechanism of lithium ion battery for electric vehicles: A review Feng, Xuning; Ouyang, Minggao; Liu, Xiang Energy Storage Materials, Vol. 10 https://doi.org/10.1016/j.ensm.2017.05.013	journal	January 2018
Toward practical all-solid-state lithium-ion batteries with high energy density and safety: Comparative study for electrodes fabricated by dry- and slurry-mixing processes Nam, Young Jin; Oh, Dae Yang; Jung, Sung Hoo Journal of Power Sources, Vol. 375 https://doi.org/10.1016/j.jpowsour.2017.11.031	journal	January 2018
All-solid-state lithium-ion and lithium metal batteries – paving the way to large-scale production Schnell, Joscha; Günther, Till; Knoche, Thomas Journal of Power Sources, Vol. 382 https://doi.org/10.1016/j.jpowsour.2018.02.062	journal	April 2018
Lithium Dendrite in All-Solid-State Batteries: Growth Mechanisms, Suppression Strategies, and Characterizations Cao, Daxian; Sun, Xiao; Li, Qiang Matter, Vol. 3, Issue 1 https://doi.org/10.1016/j.matt.2020.03.015	journal	July 2020
Interface-assisted in-situ growth of halide electrolytes eliminating interfacial challenges of all-inorganic solid-state batteries Wang, Changhong; Liang, Jianwen; Jiang, Ming Nano Energy, Vol. 76 https://doi.org/10.1016/j.nanoen.2020.105015	journal	October 2020
Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications Zhu, Hongli; Luo, Wei; Ciesielski, Peter N. Chemical Reviews, Vol. 116, Issue 16 https://doi.org/10.1021/acs.chemrev.6b00225	journal	July 2016
Stable Thiophosphate-Based All-Solid-State Lithium Batteries through Conformally Interfacial Nanocoating Cao, Daxian; Zhang, Yubin; Nolan, Adelaide M. Nano Letters, Vol. 20, Issue 3 https://doi.org/10.1021/acs.nanolett.9b02678	journal	September 2019
Hot Pressed, Fiber-Reinforced (Li ₂ S) ₇₀ (P ₂ S ₅ ) ₃₀ Solid-State Electrolyte Separators for Li Metal Batteries Yersak, Thomas; Salvador, James R.; Schmidt, Robert D. ACS Applied Energy Materials, Vol. 2, Issue 5 https://doi.org/10.1021/acsaem.9b00290	journal	April 2019
Interphase Formation of PEO ₂₀ :LiTFSI–Li ₆ PS ₅ Cl Composite Electrolytes with Lithium Metal Simon, Fabian J.; Hanauer, Matthias; Richter, Felix H. ACS Applied Materials & Interfaces, Vol. 12, Issue 10 https://doi.org/10.1021/acsami.9b22968	journal	February 2020
Thin and Flexible Solid Electrolyte Membranes with Ultrahigh Thermal Stability Derived from Solution-Processable Li Argyrodites for All-Solid-State Li-Ion Batteries Kim, Dong Hyeon; Lee, Yong-Hyeok; Song, Yong Bae ACS Energy Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acsenergylett.0c00251	journal	February 2020
Processing Strategies to Improve Cell-Level Energy Density of Metal Sulfide Electrolyte-Based All-Solid-State Li Metal Batteries and Beyond Cao, Daxian; Zhao, Yuyue; Sun, Xiao ACS Energy Letters, Vol. 5, Issue 11 https://doi.org/10.1021/acsenergylett.0c01905	journal	October 2020
Batteries and fuel cells for emerging electric vehicle markets Cano, Zachary P.; Banham, Dustin; Ye, Siyu Nature Energy, Vol. 3, Issue 4 https://doi.org/10.1038/s41560-018-0108-1	journal	April 2018
Benchmarking the performance of all-solid-state lithium batteries Randau, Simon; Weber, Dominik A.; Kötz, Olaf Nature Energy, Vol. 5, Issue 3 https://doi.org/10.1038/s41560-020-0565-1	journal	March 2020
High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes Lee, Yong-Gun; Fujiki, Satoshi; Jung, Changhoon Nature Energy, Vol. 5, Issue 4 https://doi.org/10.1038/s41560-020-0575-z	journal	March 2020
Linking void and interphase evolution to electrochemistry in solid-state batteries using operando X-ray tomography Lewis, John A.; Cortes, Francisco Javier Quintero; Liu, Yuhgene Nature Materials, Vol. 20, Issue 4 https://doi.org/10.1038/s41563-020-00903-2	journal	January 2021
Visualizing plating-induced cracking in lithium-anode solid-electrolyte cells Ning, Ziyang; Jolly, Dominic Spencer; Li, Guanchen Nature Materials, Vol. 20, Issue 8 https://doi.org/10.1038/s41563-021-00967-8	journal	April 2021
Ethyl cellulose nanodispersions as stabilizers for oil in water Pickering emulsions Wu, Xia; Zhang, Li; Zhang, Xingzhong Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-12386-4	journal	September 2017
Reviving lithium cobalt oxide-based lithium secondary batteries-toward a higher energy density Wang, Longlong; Chen, Bingbing; Ma, Jun Chemical Society Reviews, Vol. 47, Issue 17 https://doi.org/10.1039/C8CS00322J	journal	January 2018
Ultrafast solid-state lithium ion conductor through alloying induced lattice softening of Li ₆ PS ₅ Cl Xuan, Minjie; Xiao, Weidong; Xu, Hongjie Journal of Materials Chemistry A, Vol. 6, Issue 39 https://doi.org/10.1039/C8TA07240J	journal	January 2018
Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries Li, Xiaona; Liang, Jianwen; Yang, Xiaofei Energy & Environmental Science, Vol. 13, Issue 5 https://doi.org/10.1039/C9EE03828K	journal	January 2020
Pressure effects on sulfide electrolytes for all solid-state batteries Doux, Jean-Marie; Yang, Yangyuchen; Tan, Darren H. S. Journal of Materials Chemistry A, Vol. 8, Issue 10 https://doi.org/10.1039/C9TA12889A	journal	January 2020
Reducing the thickness of solid-state electrolyte membranes for high-energy lithium batteries Wu, Jingyi; Yuan, Lixia; Zhang, Wuxing Energy & Environmental Science, Vol. 14, Issue 1 https://doi.org/10.1039/D0EE02241A	journal	January 2021
Development of Ethyl Cellulose-based Formulations: A Perspective on the Novel Technical Methods Ahmadi, Parisa; Jahanban-Esfahlan, Ali; Ahmadi, Azam Food Reviews International https://doi.org/10.1080/87559129.2020.1741007	journal	April 2020
Printable, high-performance solid-state electrolyte films Ping, Weiwei; Wang, Chengwei; Wang, Ruiliu Science Advances, Vol. 6, Issue 47 https://doi.org/10.1126/sciadv.abc8641	journal	November 2020
Ethylcellulose - A Polymer Review Rekhi, Gurvinder Singh; Jambhekar, Sunil S. Drug Development and Industrial Pharmacy, Vol. 21, Issue 1 https://doi.org/10.3109/03639049509048096	journal	January 1995
Characterization of Cellulosic Fibers by FTIR Spectroscopy for Their Further Implementation to Building Materials Hospodarova, Viola; Singovszka, Eva; Stevulova, Nadezda American Journal of Analytical Chemistry, Vol. 09, Issue 06 https://doi.org/10.4236/ajac.2018.96023	journal	January 2018

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