Effect of sealing on the morphology of anodized aluminum oxide

Hu, Naiping; Dong, Xuecheng; He, Xueying; Browning, James F.; Schaefer, Dale W.

doi:10.1016/j.corsci.2015.03.021

Effect of sealing on the morphology of anodized aluminum oxide

Journal Article · Wed Jun 10 00:00:00 EDT 2015 · Corrosion Science

DOI:https://doi.org/10.1016/j.corsci.2015.03.021· OSTI ID:1836473

Hu, Naiping ^[1]; Dong, Xuecheng ^[1]; He, Xueying ^[1]; ^[2]; Schaefer, Dale W. ^[1]

Univ. of Cincinnati, OH (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Ultra-small angle X-ray scattering (USAXS), small-angle neutron scattering (SANS), X-ray reflectometry (XRR) and neutron reflectometry (NR) were used to probe structure evolution induced by sealing of anodized aluminum. While cold nickel acetate sealing and hot-water sealing decrease pore size, these methods do not alter the cylindrical porous framework of the anodic aluminum oxide layer. Hot nickel acetate both fills the pores and deposits on the air surface (air–oxide interface), leading to low porosity and small mean pore radius (39 Å). Finally, electrochemical impedance spectroscopy and direct current polarization show that samples sealed by hot nickel acetate outperform samples sealed by other sealing methods.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; AC05-00OR22725; W-7405-ENG-36

OSTI ID:: 1836473

Alternate ID(s):: OSTI ID: 22473257
OSTI ID: 1188830
OSTI ID: 1248435

Journal Information:: Corrosion Science, Journal Name: Corrosion Science Vol. 97; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (29)

Evaluation of the scale integrity in the Al2O3/MA956 system at different polarisation by using EIS García-Alonso, M. C.; Escudero, M. L.; González-Carrasco, J. L. Materials and Corrosion, Vol. 52, Issue 7 https://doi.org/10.1002/1521-4176(200107)52:7<524::AID-MACO524>3.0.CO;2-K	journal	July 2001
Electrochemical self-assembly of porous alumina templates Sadasivan, V.; Richter, C. P.; Menon, L. AIChE Journal, Vol. 51, Issue 2 https://doi.org/10.1002/aic.10332	journal	January 2005
Evaluation of different sealing methods for anodized aluminum-silicon carbide (Al/SiC) composites using EIS and SEM techniques Herrera-Hernandez, H.; Vargas-Garcia, J. R.; Hallen-Lopez, J. M. Materials and Corrosion, Vol. 58, Issue 11 https://doi.org/10.1002/maco.200704066	journal	November 2007
The sealing of porous anodic oxide films on aluminium Hoar, T. P.; Wood, G. C. Electrochimica Acta, Vol. 7, Issue 3 https://doi.org/10.1016/0013-4686(62)87009-1	journal	May 1962
The duplex nature of anodic barrier films formed on aluminium in aqueous borate and borate-glycol solutions Shimizu, K.; Thompson, G. E.; Wood, G. C. Thin Solid Films, Vol. 85, Issue 1 https://doi.org/10.1016/0040-6090(81)90054-7	journal	October 1981
Characterization of anodized and sealed aluminium by EIS Suay, J. J.; Giménez, E.; Rodrı́guez, T. Corrosion Science, Vol. 45, Issue 3 https://doi.org/10.1016/S0010-938X(02)00137-3	journal	March 2003
Overaging of sealed and unsealed aluminium oxide films Gonzalez, J. A.; Lopez, V.; Otero, E. Corrosion Science, Vol. 39, Issue 6 https://doi.org/10.1016/S0010-938X(97)00019-X	journal	June 1997
The response of anodized materials sealed in acetate-containing baths to atmospheric exposure López, V.; González, J. A.; Bautista, A. Corrosion Science, Vol. 40, Issue 4-5 https://doi.org/10.1016/S0010-938X(97)00171-6	journal	April 1998
Sealing processes of anodic coatings—Past, present, and future Hao, Ling; Cheng, B. Rachel Metal Finishing, Vol. 98, Issue 12 https://doi.org/10.1016/S0026-0576(01)80002-7	journal	December 2000
The influences of sealing methods on corrosion behavior of anodized aluminum alloys in NaCl solutions Zuo, Yu; Zhao, Peng-Hui; Zhao, Jing-Mao Surface and Coatings Technology, Vol. 166, Issue 2-3 https://doi.org/10.1016/S0257-8972(02)00779-X	journal	March 2003
Evaluation of the corrosion resistance of anodized aluminum 6061 using electrochemical impedance spectroscopy (EIS) Huang, Yuelong; Shih, Hong; Huang, Huochuan Corrosion Science, Vol. 50, Issue 12 https://doi.org/10.1016/j.corsci.2008.09.008	journal	December 2008
Evaluation of the properties of anodized aluminum 6061 subjected to thermal cycling treatment using electrochemical impedance spectroscopy (EIS) Huang, Yuelong; Shih, Hong; Daugherty, John Corrosion Science, Vol. 51, Issue 10 https://doi.org/10.1016/j.corsci.2009.06.031	journal	October 2009
RETRACTED: Cr2O3 Sealing of Anodized Aluminium Alloy by Heat Treatment Lee, Junghoon; Kim, Yonghwan; Jang, Heuiun Procedia Engineering, Vol. 10 https://doi.org/10.1016/j.proeng.2011.04.466	journal	January 2011
Characterization of aluminum anodized layers modified in sulfuric and phosphoric acid baths and their effect on conventional electrolytic coloring Hakimizad, A.; Raeissi, K.; Ashrafizadeh, F. Surface and Coatings Technology, Vol. 206, Issue 8-9 https://doi.org/10.1016/j.surfcoat.2011.10.046	journal	January 2012
A comparative study of corrosion performance of sealed anodized layers of conventionally colored and interference-colored aluminium Hakimizad, A.; Raeissi, K.; Ashrafizadeh, F. Surface and Coatings Technology, Vol. 206, Issue 22 https://doi.org/10.1016/j.surfcoat.2012.05.023	journal	June 2012
Corrosion inhibitors for anodised aluminium Whelan, M.; Barton, K.; Cassidy, J. Surface and Coatings Technology, Vol. 227 https://doi.org/10.1016/j.surfcoat.2013.02.029	journal	July 2013
Sol–gel sealing characteristics for corrosion resistance of anodised aluminium Whelan, M.; Cassidy, J.; Duffy, B. Surface and Coatings Technology, Vol. 235 https://doi.org/10.1016/j.surfcoat.2013.07.018	journal	November 2013
On the Growth of Highly Ordered Pores in Anodized Aluminum Oxide Li, Feiyue; Zhang, Lan; Metzger, Robert M. Chemistry of Materials, Vol. 10, Issue 9 https://doi.org/10.1021/cm980163a	journal	September 1998
Self-organized formation of hexagonal pore arrays in anodic alumina Jessensky, O.; Müller, F.; Gösele, U. Applied Physics Letters, Vol. 72, Issue 10 https://doi.org/10.1063/1.121004	journal	March 1998
Self-ordered pore structure of anodized aluminum on silicon and pattern transfer Crouse, D.; Lo, Yu-Hwa; Miller, A. E. Applied Physics Letters, Vol. 76, Issue 1 https://doi.org/10.1063/1.125652	journal	January 2000
Hexagonal pore arrays with a 50–420 nm interpore distance formed by self-organization in anodic alumina Li, A. P.; Müller, F.; Birner, A. Journal of Applied Physics, Vol. 84, Issue 11 https://doi.org/10.1063/1.368911	journal	December 1998
Co-refinement of multiple-contrast neutron/X-ray reflectivity data using MOTOFIT Nelson, Andrew Journal of Applied Crystallography, Vol. 39, Issue 2 https://doi.org/10.1107/S0021889806005073	journal	March 2006
Irena : tool suite for modeling and analysis of small-angle scattering Ilavsky, Jan; Jemian, Peter R. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889809002222	journal	February 2009
Interfacial morphology of low-voltage anodic aluminium oxide Hu, Naiping; Dong, Xuecheng; He, Xueying Journal of Applied Crystallography, Vol. 46, Issue 5 https://doi.org/10.1107/S0021889813018219	journal	August 2013
Self-Ordering of Cell Configuration of Anodic Porous Alumina with Large-Size Pores in Phosphoric Acid Solution Masuda, Hideki; Yada, Kouichi; Osaka, Atsushi Japanese Journal of Applied Physics, Vol. 37, Issue Part 2, No. 11A https://doi.org/10.1143/JJAP.37.L1340	journal	November 1998
Sealing of Anodized Aluminum Alloys with Rare Earth Metal Salt Solutions Mansfeld, F.; Chen, C.; Breslin, C. B. Journal of The Electrochemical Society, Vol. 145, Issue 8 https://doi.org/10.1149/1.1838716	journal	August 1998
Evaluation of Anodized Aluminum Surfaces with Electrochemical Impedance Spectroscopy Mansfeld, F.; Kendig, M. W. Journal of The Electrochemical Society, Vol. 135, Issue 4 https://doi.org/10.1149/1.2095786	journal	April 1988
Comparative studies on corrosion behaviour of sealed aluminium with cerium salt under bidirectional pulse electric field Zhao, J. M.; Chen, S. L.; Huo, P. Corrosion Engineering, Science and Technology, Vol. 47, Issue 3 https://doi.org/10.1179/1743278211Y.0000000025	journal	May 2012
EIS evolution of anodised aluminium by cerium salt sealing in NaCl solution with exposure time Zhao, J. M.; Liu, H. X.; Chen, S. L. Corrosion Engineering, Science and Technology, Vol. 48, Issue 1 https://doi.org/10.1179/1743278212Y.0000000045	journal	February 2013

Cited By (8)

Effect of NaAlO ₂ sealing on corrosion resistance of 2024 aluminum alloy anodized film Yang, Yingshuo; Cheng, Jie; Liu, Shengli Materials and Corrosion, Vol. 70, Issue 1 https://doi.org/10.1002/maco.201810327	journal	July 2018
Effect of concentration of Ce(NO ₃ ) ₃ · 6H ₂ O and temperature on the corrosion resistance of Al ₂ O ₃ /cerium oxide composite films on 1060 Al alloy Li, Zeyuan; Ying, Lixia; Jin, Qiu Materials and Corrosion, Vol. 70, Issue 7 https://doi.org/10.1002/maco.201810730	journal	January 2019
Corrosion and mechanical properties of plasma electrolytic oxidation‐coated AZ80 magnesium alloy Pezzato, Luca; Coelho, Leonardo Bertolucci; Bertolini, Rachele Materials and Corrosion, Vol. 70, Issue 11 https://doi.org/10.1002/maco.201910847	journal	May 2019
Application of experimental design for AA6351 aluminum alloy anodization and coloring Alves, Guilherme José Turcatel; Maia, Guilherme Arielo Rodrigues; Antunes, Sandra Regina Masetto Materials Research Express, Vol. 6, Issue 1 https://doi.org/10.1088/2053-1591/aae347	journal	October 2018
Nanoparticles deposition effects on 1050A aluminum alloy anodic layers Gaber, Gh A.; Hussein, W. A.; Ghanem, W. A. Materials Research Express, Vol. 7, Issue 1 https://doi.org/10.1088/2053-1591/ab6a59	journal	January 2020
Determination of the dye penetration rate in porous aluminum oxide using Raman spectroscopy Matijošius, Tadas; Asadauskas, Svajus J.; Bikulčius, Gedvidas Coloration Technology, Vol. 135, Issue 4 https://doi.org/10.1111/cote.12404	journal	May 2019
The Effect of Electrolyte Temperature and Sealing Solution in Anodizing Operation on Hardness and wear Behavior of 7075 -t6 Aluminum Alloy Niyazbakhsh, Saeed; Amini, Kamran; Gharavi, Farhad Surface Review and Letters, Vol. 26, Issue 02 https://doi.org/10.1142/s0218625x18501433	journal	February 2019
Influence of Concentration and pH of Hexafluorozirconic Acid on Corrosion Resistance of Anodized AA7075-T6 Pinheiro, Jéssica Salles; Regio, Gabriel; Cardoso, Henrique Ribeiro Piaggio Materials Research, Vol. 22, Issue suppl 1 https://doi.org/10.1590/1980-5373-mr-2019-0048	journal	January 2019

Similar Records

Interfacial morphology of low-voltage anodic aluminium oxide

Journal Article · Mon Dec 31 23:00:00 EST 2012 · Journal of Applied Crystallography · OSTI ID:1093098

Oxide structure of air-passivated U-6Nb alloy thin films

Journal Article · Mon Jun 29 20:00:00 EDT 2020 · Journal of Nuclear Materials · OSTI ID:1638634

Effect of post annealing on microstructure and mechanical properties in Ni-free N-containing ODS steel

Journal Article · Mon Jul 01 00:00:00 EDT 2019 · Materials Characterization · OSTI ID:1548292

Related Subjects

36 MATERIALS SCIENCE
EIS
aluminum
anodic films
interfaces
reflectivity
x-ray diffraction

Effect of sealing on the morphology of anodized aluminum oxide

Citation Formats

References (29)

Cited By (8)

Similar Records

Related Subjects