Oxidation kinetics and microstructure evolution of high Mn stainless-steel alloy in CO2 at 700&nbsp;°C

Abdallah, Iman; Kim, Taeho; Wu, Xueyang; Bailly-Salins, Louis; Elbakhshwan, Mohamed; Carroll, Mark; Tonks, Michael R.; Perepezko, John H.; Couet, Adrien

doi:10.1016/j.corsci.2021.110013

Oxidation kinetics and microstructure evolution of high Mn stainless-steel alloy in CO₂ at 700 °C

Journal Article · Sat Dec 11 00:00:00 EST 2021 · Corrosion Science

DOI:https://doi.org/10.1016/j.corsci.2021.110013· OSTI ID:1838241

^[1]; Kim, Taeho ^[2]; Wu, Xueyang ^[3]; Bailly-Salins, Louis ^[2]; Elbakhshwan, Mohamed ^[2]; Carroll, Mark ^[4]; Tonks, Michael R. ^[3]; Perepezko, John H. ^[2]; Couet, Adrien ^[2]

Univ. of Wisconsin, Madison, WI (United States); University of Wisconsin-Madison
Univ. of Wisconsin, Madison, WI (United States)
Univ. of Florida, Gainesville, FL (United States)
Federal-Mogul Powertrain Division Tenneco, Southfield, MI (United States)

Oxidation kinetics and scale formation were examined in 21–2N Stainless Steel alloys in a CO₂ environment at 700 °C. Several characterization techniques were used to identify the morphology, crystallographic structure, and chemical composition of the oxide scale formation during exposures up to 1925 h. High manganese content played an important role in homogenous oxide scale formation of Mn₃O₄ and MnCr₂O₄ at the scale/gas and scale/alloy interfaces and as an FCC stabilizer in the alloy. Depletion of Mn resulted in an FCC to BCC phase transformation at the scale/alloy interface. No carburization was observed, indicating that the oxide layer is preventing carbon uptake.

View Accepted Manuscript (DOE)

Research Organization:: Federal-Mogul Powertrain Division Tenneco, Southfield, MI (United States); Univ. of Florida, Gainesville, FL (United States); Univ. of Wisconsin, Madison, WI (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0008459

OSTI ID:: 1838241

Alternate ID(s):: OSTI ID: 1836393

Journal Information:: Corrosion Science, Journal Name: Corrosion Science Vol. 195; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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