Communication—Functional Conductive Polymer Binder for Practical Si-Based Electrodes

Zhu, Tianyu; Liu, Gao

doi:10.1149/1945-7111/abff01

Title: Communication—Functional Conductive Polymer Binder for Practical Si-Based Electrodes

Journal Article · Thu May 20 00:00:00 EDT 2021 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/1945-7111/abff01· OSTI ID:1835408

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Multifunctional conductive binders represent an emerging class of polymer materials to address inherent challenges of Si electrodes for high capacity lithium-ion batteries. Advanced binders with oriented functionalities are greatly desired to facilitate the battery chemistry. We here report stable capacity cycling of a practical composite anode comprising industrial available SiO _x (>60 wt%), carbon materials and a conductive polymer binder—poly(9,9-dioctylfluorene- co -fluorenonecomethylbenzoic ester) (PFM). This multifunctional polymer functions as both an interface modifier and an electrode binder for high-performing SiO _x composite electrodes. The viability of multifunctional conductive polymer binders was further validated in a practical full cell.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1835408

Alternate ID(s):: OSTI ID: 1814151

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Vol. 168 Journal Issue: 5; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (31)

Prospects of organic electrode materials for practical lithium batteries Lu, Yong; Chen, Jun Nature Reviews Chemistry, Vol. 4, Issue 3 https://doi.org/10.1038/s41570-020-0160-9	journal	February 2020
Electrolyte design for LiF-rich solid–electrolyte interfaces to enable high-performance microsized alloy anodes for batteries Chen, Ji; Fan, Xiulin; Li, Qin Nature Energy, Vol. 5, Issue 5 https://doi.org/10.1038/s41560-020-0601-1	journal	April 2020
Aqueous Binder for Nanostructured Carbon Anode Materials for Li-Ion Batteries Lis, Marcelina; Chudzik, Krystian; Bakierska, Monika Journal of The Electrochemical Society, Vol. 166, Issue 3 https://doi.org/10.1149/2.0591903jes	journal	January 2019
Material and Structural Design of Novel Binder Systems for High-Energy, High-Power Lithium-Ion Batteries Shi, Ye; Zhou, Xingyi; Yu, Guihua Accounts of Chemical Research, Vol. 50, Issue 11 https://doi.org/10.1021/acs.accounts.7b00402	journal	October 2017
Toward Practical Application of Functional Conductive Polymer Binder for a High-Energy Lithium-Ion Battery Design Zhao, Hui; Wang, Zhihui; Lu, Peng Nano Letters, Vol. 14, Issue 11 https://doi.org/10.1021/nl503490h	journal	October 2014
Toward an Ideal Polymer Binder Design for High-Capacity Battery Anodes Wu, Mingyan; Xiao, Xingcheng; Vukmirovic, Nenad Journal of the American Chemical Society, Vol. 135, Issue 32 https://doi.org/10.1021/ja4054465	journal	July 2013
Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes Liu, Gao; Xun, Shidi; Vukmirovic, Nenad Advanced Materials, Vol. 23, Issue 40, p. 4679-4683 https://doi.org/10.1002/adma.201102421	journal	September 2011
Particles and Polymer Binder Interaction: A Controlling Factor in Lithium-Ion Electrode Performance Liu, G.; Zheng, H.; Song, X. Journal of The Electrochemical Society, Vol. 159, Issue 3 https://doi.org/10.1149/2.024203jes	journal	January 2012
Three-Dimensional Hierarchical Ternary Nanostructures for High-Performance Li-Ion Battery Anodes Liu, Borui; Soares, Paulo; Checkles, Constantine Nano Letters, Vol. 13, Issue 7 https://doi.org/10.1021/nl401880v	journal	June 2013
Side-Chain Conducting and Phase-Separated Polymeric Binders for High-Performance Silicon Anodes in Lithium-Ion Batteries Park, Sang-Jae; Zhao, Hui; Ai, Guo Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja511181p	journal	February 2015
Combinatorial Studies of Si _{1− x} O _x as a Potential Negative Electrode Material for Li-Ion Battery Applications Al-Maghrabi, M. A.; Suzuki, Junji; Sanderson, R. J. Journal of The Electrochemical Society, Vol. 160, Issue 9 https://doi.org/10.1149/2.115309jes	journal	January 2013
Metallo-Polyelectrolytes: Correlating Macromolecular Architectures with Properties and Applications Zhu, Tianyu; Zhang, Jiuyang; Tang, Chuanbing Trends in Chemistry, Vol. 2, Issue 3 https://doi.org/10.1016/j.trechm.2019.12.004	journal	March 2020
Polymer Light-Emitting Electrochemical Cells Pei, Q.; Yu, G.; Zhang, C. Science, Vol. 269, Issue 5227 https://doi.org/10.1126/science.269.5227.1086	journal	August 1995
Ultra-efficient polymer binder for silicon anode in high-capacity lithium-ion batteries Gao, Shilun; Sun, Feiyuan; Brady, Alexander Nano Energy, Vol. 73 https://doi.org/10.1016/j.nanoen.2020.104804	journal	July 2020
Energy gels: A bio-inspired material platform for advanced energy applications Shi, Ye; Zhang, Jun; Pan, Lijia Nano Today, Vol. 11, Issue 6 https://doi.org/10.1016/j.nantod.2016.10.002	journal	December 2016
High-Rate LiFePO ₄ Lithium Rechargeable Battery Promoted by Electrochemically Active Polymers Huang, Yun-Hui; Goodenough, John B. Chemistry of Materials, Vol. 20, Issue 23 https://doi.org/10.1021/cm8012304	journal	December 2008
A Critical Size of Silicon Nano-Anodes for Lithium Rechargeable Batteries Kim, Hyejung; Seo, Minho; Park, Mi-Hee Angewandte Chemie International Edition, Vol. 49, Issue 12 https://doi.org/10.1002/anie.200906287	journal	March 2010
The emerging era of supramolecular polymeric binders in silicon anodes Kwon, Tae-woo; Choi, Jang Wook; Coskun, Ali Chemical Society Reviews, Vol. 47, Issue 6 https://doi.org/10.1039/C7CS00858A	journal	January 2018
Conductive polymer binder for nano-silicon/graphite composite electrode in lithium-ion batteries towards a practical application Zhao, Hui; Du, Allen; Ling, Min Electrochimica Acta, Vol. 209 https://doi.org/10.1016/j.electacta.2016.05.061	journal	August 2016
Silicon Microparticle Anodes with Self-Healing Multiple Network Binder Xu, Zhixin; Yang, Jun; Zhang, Tao Joule, Vol. 2, Issue 5 https://doi.org/10.1016/j.joule.2018.02.012	journal	May 2018
Molecular Spring Enabled High-Performance Anode for Lithium Ion Batteries Zheng, Tianyue; Jia, Zhe; Lin, Na Polymers, Vol. 9, Issue 12 https://doi.org/10.3390/polym9120657	journal	November 2017
Interconnected Silicon Hollow Nanospheres for Lithium-Ion Battery Anodes with Long Cycle Life Yao, Yan; McDowell, Matthew T.; Ryu, Ill Nano Letters, Vol. 11, Issue 7, p. 2949-2954 https://doi.org/10.1021/nl201470j	journal	July 2011
Exploring Chemical, Mechanical, and Electrical Functionalities of Binders for Advanced Energy-Storage Devices Chen, Hao; Ling, Min; Hencz, Luke Chemical Reviews, Vol. 118, Issue 18 https://doi.org/10.1021/acs.chemrev.8b00241	journal	August 2018
Conductive Polymer Binder for High-Tap-Density Nanosilicon Material for Lithium-Ion Battery Negative Electrode Application Zhao, Hui; Wei, Yang; Qiao, Ruimin Nano Letters, Vol. 15, Issue 12 https://doi.org/10.1021/acs.nanolett.5b03003	journal	November 2015
Surface Coating Constraint Induced Self-Discharging of Silicon Nanoparticles as Anodes for Lithium Ion Batteries Luo, Langli; Zhao, Peng; Yang, Hui Nano Letters, Vol. 15, Issue 10 https://doi.org/10.1021/acs.nanolett.5b03047	journal	September 2015
Interweaving 3D Network Binder for High-Areal-Capacity Si Anode through Combined Hard and Soft Polymers Liu, Tiefeng; Chu, Qiaoling; Yan, Cheng Advanced Energy Materials, Vol. 9, Issue 3 https://doi.org/10.1002/aenm.201802645	journal	November 2018
Silicon Anode with High Initial Coulombic Efficiency by Modulated Trifunctional Binder for High‐Areal‐Capacity Lithium‐Ion Batteries Li, Zeheng; Zhang, Yaping; Liu, Tiefeng Advanced Energy Materials, Vol. 10, Issue 20 https://doi.org/10.1002/aenm.201903110	journal	April 2020
Rational Design of a Multifunctional Binder for High-Capacity Silicon-Based Anodes Cao, Peng-Fei; Yang, Guang; Li, Bingrui ACS Energy Letters, Vol. 4, Issue 5 https://doi.org/10.1021/acsenergylett.9b00815	journal	April 2019
Mussel-Inspired Conductive Polymer Binder for Si-Alloy Anode in Lithium-Ion Batteries Zhao, Hui; Wei, Yang; Wang, Cheng ACS Applied Materials & Interfaces, Vol. 10, Issue 6 https://doi.org/10.1021/acsami.7b14645	journal	January 2018
A binder-free high silicon content flexible anode for Li-ion batteries Wang, Hanwei; Fu, Jinzhou; Wang, Chao Energy & Environmental Science, Vol. 13, Issue 3 https://doi.org/10.1039/C9EE02615K	journal	January 2020
Novel conductive binder for high-performance silicon anodes in lithium ion batteries Liu, Dong; Zhao, Yan; Tan, Rui Nano Energy, Vol. 36 https://doi.org/10.1016/j.nanoen.2017.04.043	journal	June 2017

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