Salt and Water Transport in Reverse Osmosis Membranes: Beyond the Solution-Diffusion Model

Wang, Li; Cao, Tianchi; Dykstra, Jouke E.; Porada, Slawomir; Biesheuvel, P. M.; Elimelech, Menachem

doi:10.1021/acs.est.1c05649

Salt and Water Transport in Reverse Osmosis Membranes: Beyond the Solution-Diffusion Model

Journal Article · Tue Dec 07 23:00:00 EST 2021 · Environmental Science and Technology

DOI:https://doi.org/10.1021/acs.est.1c05649· OSTI ID:1834671

^[1]; Cao, Tianchi ^[1]; ^[2]; ^[3]; ^[3]; ^[1]

Department of Chemical and Environmental Engineering, Yale University, New Haven, Connecticut 06520-8286, United States
Environmental Technology, Wageningen University, Bornse Weilanden 9, 6708 WG Wageningen, The Netherlands
Wetsus, European Centre of Excellence for Sustainable Water Technology, Oostergoweg 9, 8911 MA Leeuwarden, The Netherlands

Not Available

View Journal Article

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0019112

OSTI ID:: 1834671

Alternate ID(s):: OSTI ID: 1836949

Journal Information:: Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 24 Vol. 55; ISSN 0013-936X

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (59)

Membrane Technology and Applications Baker, Richard W. https://doi.org/10.1002/9781118359686	book	July 2012
A perspective on reverse osmosis water desalination: Quest for sustainability Cohen, Yoram; Semiat, Raphael; Rahardianto, Anditya AIChE Journal, Vol. 63, Issue 6 https://doi.org/10.1002/aic.15726	journal	April 2017
Hindered transport of large molecules in liquid-filled pores Deen, W. M. AIChE Journal, Vol. 33, Issue 9, p. 1409-1425 https://doi.org/10.1002/aic.690330902	journal	September 1987
Development of a space-charge transport model for ion-exchange membranes Guzmán-Garcia, Angel G.; Pintauro, Peter N.; Verbrugge, Mark W. AIChE Journal, Vol. 36, Issue 7 https://doi.org/10.1002/aic.690360713	journal	July 1990
Diafiltration by nanofiltration: Prediction and optimization Richard Bowen, W.; Wahab Mohammad, A. AIChE Journal, Vol. 44, Issue 8 https://doi.org/10.1002/aic.690440811	journal	August 1998
The role of membrane pressure in reverse osmosis Paul, D. R. Journal of Applied Polymer Science, Vol. 16, Issue 3 https://doi.org/10.1002/app.1972.070160320	journal	March 1972
The Importance of Dehydration in Determining Ion Transport in Narrow Pores Richards, Laura A.; Schäfer, Andrea I.; Richards, Bryce S. Small, Vol. 8, Issue 11 https://doi.org/10.1002/smll.201102056	journal	March 2012
Application of the Charge Regulation Model to Transport of Ions through Hydrophilic Membranes: One-Dimensional Transport Model for Narrow Pores (Nanofiltration) de Lint, W. B. Samuel; Biesheuvel, P. Maarten; Verweij, Henk Journal of Colloid and Interface Science, Vol. 251, Issue 1 https://doi.org/10.1006/jcis.2002.8363	journal	July 2002
Volumen und Hydratationswärme der Ionen Born, M. Zeitschrift für Physik, Vol. 1, Issue 1 https://doi.org/10.1007/BF01881023	journal	February 1920
Thermodynamic analysis of the permeability of biological membranes to non-electrolytes Kedem, O.; Katchalsky, A. Biochimica et Biophysica Acta, Vol. 27 https://doi.org/10.1016/0006-3002(58)90330-5	journal	January 1958
Electrolyte osmosis through capillaries Sasidhar, Varanasi; Ruckenstein, Eli Journal of Colloid and Interface Science, Vol. 82, Issue 2 https://doi.org/10.1016/0021-9797(81)90386-6	journal	August 1981
The solution-diffusion model: a review Wijmans, J. G.; Baker, R. W. Journal of Membrane Science, Vol. 107, Issue 1-2 https://doi.org/10.1016/0376-7388(95)00102-I	journal	November 1995
Effect of solution chemistry on the surface charge of polymeric reverse osmosis and nanofiltration membranes Childress, Amy E.; Elimelech, Menachem Journal of Membrane Science, Vol. 119, Issue 2 https://doi.org/10.1016/0376-7388(96)00127-5	journal	October 1996
Dielectric exclusion of ions from membranes Yaroshchuk, Andrij E. Advances in Colloid and Interface Science, Vol. 85, Issue 2-3 https://doi.org/10.1016/S0001-8686(99)00021-4	journal	March 2000
Nanofiltration modeling: the role of dielectric exclusion in membrane characterization Bandini, Serena; Vezzani, Daniele Chemical Engineering Science, Vol. 58, Issue 15 https://doi.org/10.1016/S0009-2509(03)00212-4	journal	August 2003
Salt rejection and flux in reverse osmosis with compactible membranes Henkens, W. C. M.; Smit, J. A. M. Desalination, Vol. 28, Issue 1 https://doi.org/10.1016/S0011-9164(00)88127-8	journal	January 1979
Simple technique for measuring the concentration polarization level in a reverse osmosis system Sutzkover, Iris; Hasson, David; Semiat, Raphael Desalination, Vol. 131, Issue 1-3 https://doi.org/10.1016/S0011-9164(00)90012-2	journal	December 2000
Review of the dielectric properties of nanofiltration membranes and verification of the single oriented layer approximation Oatley, Darren L.; Llenas, Laia; Pérez, Ramon Advances in Colloid and Interface Science, Vol. 173 https://doi.org/10.1016/j.cis.2012.02.001	journal	May 2012
Modelling nanofiltration of electrolyte solutions Yaroshchuk, Andriy; Bruening, Merlin L.; Zholkovskiy, Emiliy Advances in Colloid and Interface Science, Vol. 268 https://doi.org/10.1016/j.cis.2019.03.004	journal	June 2019
Ion partitioning and permeation in charged low-T* membranes Freger, Viatcheslav Advances in Colloid and Interface Science, Vol. 277 https://doi.org/10.1016/j.cis.2020.102107	journal	March 2020
State-of-the-art of reverse osmosis desalination Fritzmann, C.; Löwenberg, J.; Wintgens, T. Desalination, Vol. 216, Issue 1-3 https://doi.org/10.1016/j.desal.2006.12.009	journal	October 2007
Treatment of dairy industry wastewater by reverse osmosis for water reuse Vourch, Mickael; Balannec, Béatrice; Chaufer, Bernard Desalination, Vol. 219, Issue 1-3 https://doi.org/10.1016/j.desal.2007.05.013	journal	January 2008
Molecular simulations of polyamide reverse osmosis membranes Ding, Minxia; Ghoufi, Aziz; Szymczyk, Anthony Desalination, Vol. 343 https://doi.org/10.1016/j.desal.2013.09.024	journal	June 2014
Salt rejection behavior of carbon nanotube-polyamide nanocomposite reverse osmosis membranes in several salt solutions Takeuchi, Kenji; Takizawa, Yoshihiro; Kitazawa, Hidenori Desalination, Vol. 443 https://doi.org/10.1016/j.desal.2018.04.021	journal	October 2018
True driving force and characteristics of water transport in osmotic membranes Song, Lianfa; Heiranian, Mohammad; Elimelech, Menachem Desalination, Vol. 520 https://doi.org/10.1016/j.desal.2021.115360	journal	December 2021
Variation of free volume and thickness by high pressure applied on thin film composite reverse osmosis membrane Chu, Kyoung Hoon; Mang, Ji Sung; Lim, Jihun Desalination, Vol. 520 https://doi.org/10.1016/j.desal.2021.115365	journal	December 2021
Two-fluid model for the simultaneous flow of colloids and fluids in porous media Biesheuvel, P. M. Journal of Colloid and Interface Science, Vol. 355, Issue 2 https://doi.org/10.1016/j.jcis.2010.12.006	journal	March 2011
Treatment train approaches for the remediation of per- and polyfluoroalkyl substances (PFAS): A critical review Lu, Dingnan; Sha, Sha; Luo, Jiayue Journal of Hazardous Materials, Vol. 386 https://doi.org/10.1016/j.jhazmat.2019.121963	journal	March 2020
Reformulation of the solution-diffusion theory of reverse osmosis Paul, D. Journal of Membrane Science, Vol. 241, Issue 2 https://doi.org/10.1016/j.memsci.2004.05.026	journal	October 2004
Prediction of the concentration polarization in the nanofiltration/reverse osmosis of dilute multi-ionic solutions Geraldes, Vítor; Afonso, Maria Diná Journal of Membrane Science, Vol. 300, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.04.025	journal	August 2007
The role of the electrolyte on the mechanism of charge formation in polyamide nanofiltration membranes☆ Bruni, Luigi; Bandini, Serena Journal of Membrane Science, Vol. 308, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.09.061	journal	February 2008
Computer program for simulation of mass transport in nanofiltration membranes Geraldes, Vítor; Brites Alves, Ana Maria Journal of Membrane Science, Vol. 321, Issue 2 https://doi.org/10.1016/j.memsci.2008.04.054	journal	August 2008
Influence of concentration polarization and thermodynamic non-ideality on salt transport in reverse osmosis membranes Jang, Eui-Soung; Mickols, William; Sujanani, Rahul Journal of Membrane Science, Vol. 572 https://doi.org/10.1016/j.memsci.2018.11.006	journal	February 2019
Thin film composite membrane compaction in high-pressure reverse osmosis Davenport, Douglas M.; Ritt, Cody L.; Verbeke, Rhea Journal of Membrane Science, Vol. 610 https://doi.org/10.1016/j.memsci.2020.118268	journal	September 2020
On the presence of solute-solvent transport coupling in reverse osmosis Roy, Yagnaseni; Lienhard, John H. Journal of Membrane Science, Vol. 611 https://doi.org/10.1016/j.memsci.2020.118272	journal	October 2020
Modeling permeate pH in RO membranes by the extended Donnan steric partitioning pore model Zhang, L.; Hamelers, H. V. M.; Biesheuvel, P. M. Journal of Membrane Science, Vol. 613 https://doi.org/10.1016/j.memsci.2020.118511	journal	November 2020
Pore model for nanofiltration: History, theoretical framework, key predictions, limitations, and prospects Wang, Ruoyu; Lin, Shihong Journal of Membrane Science, Vol. 620 https://doi.org/10.1016/j.memsci.2020.118809	journal	February 2021
Tutorial review of reverse osmosis and electrodialysis Biesheuvel, P. M.; Porada, S.; Elimelech, M. Journal of Membrane Science, Vol. 647 https://doi.org/10.1016/j.memsci.2021.120221	journal	April 2022
Removal of pharmaceuticals and endocrine disrupting compounds in a water recycling process using reverse osmosis systems Al-Rifai, Jawad H.; Khabbaz, Hadi; Schäfer, Andrea I. Separation and Purification Technology, Vol. 77, Issue 1 https://doi.org/10.1016/j.seppur.2010.11.020	journal	February 2011
Selectivity and Mass Transfer Limitations in Pressure-Retarded Osmosis at High Concentrations and Increased Operating Pressures Straub, Anthony P.; Osuji, Chinedum O.; Cath, Tzahi Y. Environmental Science & Technology, Vol. 49, Issue 20 https://doi.org/10.1021/acs.est.5b01317	journal	October 2015
The Critical Need for Increased Selectivity, Not Increased Water Permeability, for Desalination Membranes Werber, Jay R.; Deshmukh, Akshay; Elimelech, Menachem Environmental Science & Technology Letters, Vol. 3, Issue 4 https://doi.org/10.1021/acs.estlett.6b00050	journal	March 2016
Ion Selectivity in Brackish Water Desalination by Reverse Osmosis: Theory, Measurements, and Implications Biesheuvel, P. M.; Zhang, L.; Gasquet, P. Environmental Science & Technology Letters, Vol. 7, Issue 1 https://doi.org/10.1021/acs.estlett.9b00686	journal	December 2019
Derivation of the Theoretical Minimum Energy of Separation of Desalination Processes Wang, Li; Violet, Camille; DuChanois, Ryan M. Journal of Chemical Education, Vol. 97, Issue 12 https://doi.org/10.1021/acs.jchemed.0c01194	journal	November 2020
Insights into the Water Transport Mechanism in Polymeric Membranes from Neutron Scattering Chan, Edwin P.; Frieberg, Bradley R.; Ito, Kanae Macromolecules, Vol. 53, Issue 4 https://doi.org/10.1021/acs.macromol.9b02195	journal	February 2020
Nanopore-Based Power Generation from Salinity Gradient: Why It Is Not Viable Wang, Li; Wang, Zhangxin; Patel, Sohum K. ACS Nano, Vol. 15, Issue 3 https://doi.org/10.1021/acsnano.0c08628	journal	January 2021
Relating Nanofiltration Membrane Performance to Membrane Charge (Electrokinetic) Characteristics Childress, Amy E.; Elimelech, Menachem Environmental Science & Technology, Vol. 34, Issue 17 https://doi.org/10.1021/es0008620	journal	September 2000
Quantification of Functional Groups and Modeling of Their Ionization Behavior in the Active Layer of FT30 Reverse Osmosis Membrane Coronell, Orlando; Mariñas, Benito J.; Zhang, Xijing Environmental Science & Technology, Vol. 42, Issue 14 https://doi.org/10.1021/es8002712	journal	July 2008
Hindrance Factors for Diffusion and Convection in Pores Dechadilok, Panadda; Deen, William M. Industrial & Engineering Chemistry Research, Vol. 45, Issue 21 https://doi.org/10.1021/ie051387n	journal	October 2006
In Situ Characterization of Dehydration during Ion Transport in Polymeric Nanochannels Lu, Chenghai; Hu, Chengzhi; Ritt, Cody L. Journal of the American Chemical Society, Vol. 143, Issue 35 https://doi.org/10.1021/jacs.1c05765	journal	August 2021
The Donnan Membrane Equilibrium Chaudhury, S. G. Nature, Vol. 152, Issue 3846 https://doi.org/10.1038/152076b0	journal	July 1943
Materials for next-generation desalination and water purification membranes Werber, Jay R.; Osuji, Chinedum O.; Elimelech, Menachem Nature Reviews Materials, Vol. 1, Issue 5 https://doi.org/10.1038/natrevmats.2016.18	journal	April 2016
Ionization behavior of nanoporous polyamide membranes Ritt, Cody L.; Werber, Jay R.; Wang, Mengyi Proceedings of the National Academy of Sciences, Vol. 117, Issue 48 https://doi.org/10.1073/pnas.2008421117	journal	November 2020
Theory of Ion and Water Transport in Electron-Conducting Membrane Pores with p H-Dependent Chemical Charge Zhang, L.; Biesheuvel, P. M.; Ryzhkov, I. I. Physical Review Applied, Vol. 12, Issue 1 https://doi.org/10.1103/PhysRevApplied.12.014039	journal	July 2019
Theory of Ion and Water Transport in Reverse-Osmosis Membranes Oren, Y. S.; Biesheuvel, P. M. Physical Review Applied, Vol. 9, Issue 2 https://doi.org/10.1103/PhysRevApplied.9.024034	journal	February 2018
Incorporating Born solvation energy into the three-dimensional Poisson-Nernst-Planck model to study ion selectivity in KcsA K + channels Liu, Xuejiao; Lu, Benzhuo Physical Review E, Vol. 96, Issue 6 https://doi.org/10.1103/PhysRevE.96.062416	journal	December 2017
The Future of Seawater Desalination: Energy, Technology, and the Environment Elimelech, M.; Phillip, W. A. Science, Vol. 333, Issue 6043 https://doi.org/10.1126/science.1200488	journal	August 2011
Polyamide membranes with nanoscale Turing structures for water purification Tan, Zhe; Chen, Shengfu; Peng, Xinsheng Science, Vol. 360, Issue 6388 https://doi.org/10.1126/science.aar6308	journal	May 2018
Ionic solution near an uncharged surface with image forces Croxton, T.; McQuarrie, D. A.; Patey, G. N. Canadian Journal of Chemistry, Vol. 59, Issue 13 https://doi.org/10.1139/v81-295	journal	July 1981
Reverse Osmosis for Direct Potable Reuse in California: Reverse Osmosis for Direct Potable Reuse in California Bernados, Brian Journal - American Water Works Association, Vol. 110, Issue 1 https://doi.org/10.5942/jawwa.2018.110.0006	journal	January 2018

Similar Records

The solution-diffusion model for water transport in reverse osmosis: What went wrong?

Journal Article · Mon Jul 01 00:00:00 EDT 2024 · Desalination · OSTI ID:2576569

Salt and Water Transport in Reverse Osmosis Membranes: Beyond the Solution-Diffusion Model

Citation Formats

References (59)

Similar Records

Related Subjects