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Title: Reduction of efficiency droop in c-plane InGaN/GaN light-emitting diodes using a thick single quantum well with doped barriers

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/5.0073741· OSTI ID:1834371

We report on c-plane InGaN/GaN single quantum well (QW) light-emitting diodes (LEDs) of different well widths (3 or 9 nm) with and without doped barriers. QW barriers were doped with the aim of reducing the internal electric field (FQW) in the QW to increase the electron-hole overlap, therefore increasing the recombination rates and resulting in the reduction of the efficiency droop. We, indeed, observed, through biased photocurrent spectroscopy, a reduction in FQW with doped barriers, with FQW being in the same direction of the p-n junction field at zero bias as opposed to the junction field for LEDs without doped barriers. Even with the improvement in the ground state wavefunction overlap, the ground state transition rate remains low for thick QWs. Transitions through excited states were observed for both thick QW LEDs with and without doped barriers. Here, the thick QW LED without doped barriers displayed low external quantum efficiency (EQE), likely as a result of the carrier overflow due to the poor confinement of carriers in the excited states. On the other hand, for LEDs with doped barriers, the flatter band in the QW resulting from the lower FQW reduces the energy separation between the eigenstates, leading to better confinement of carriers in the excited states. With doped barriers, we demonstrated a low efficiency droop 9-nm-thick single QW LED with a peak EQE of 42% at 40 A/cm2 and an EQE of 36% at 400 A/cm2.

Research Organization:
Univ. of California, Santa Barbara, CA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
EE0008204; 2150283
OSTI ID:
1834371
Alternate ID(s):
OSTI ID: 1832915
Journal Information:
Applied Physics Letters, Vol. 119, Issue 22; ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English

References (29)

Effects of macroscopic polarization in III-V nitride multiple quantum wells journal September 1999
Direct measurement of hot-carrier generation in a semiconductor barrier heterostructure: Identification of the dominant mechanism for thermal droop journal September 2019
New developments in green LEDs: New developments in green LEDs journal March 2009
Characterization of blue-green m-plane InGaN light emitting diodes journal June 2009
Bandgap determination based on electrical quantum efficiency journal July 2013
Exciton localization in InGaN quantum well devices journal July 1998
Localization landscape theory of disorder in semiconductors. III. Application to carrier transport and recombination in light emitting diodes journal April 2017
Field-assisted Shockley-Read-Hall recombinations in III-nitride quantum wells journal December 2017
Optimal number of quantum wells for blue InGaN/GaN light-emitting diodes journal June 2012
Localization landscape theory of disorder in semiconductors. II. Urbach tails of disordered quantum well layers journal April 2017
Polarization field screening in thick (0001) InGaN/GaN single quantum well light-emitting diodes journal February 2016
Luminescence spectra from InGaN multiquantum wells heavily doped with Si journal June 1998
The efficiency challenge of nitride light-emitting diodes for lighting: The efficiency challenge of nitride LEDs for lighting journal March 2015
Influence of polarization fields on carrier lifetime and recombination rates in InGaN-based light-emitting diodes journal July 2010
Color shift reduction of a multi-domain IPS-LCD using RGB-LED backlight journal January 2006
Semipolar III–nitride light-emitting diodes with negligible efficiency droop up to ∼1 W journal September 2016
Quantum-Confined Stark Effect due to Piezoelectric Fields in GaInN Strained Quantum Wells journal April 1997
Beyond Quantum Efficiency Limitations Originating from the Piezoelectric Polarization in Light-Emitting Devices journal July 2019
InGaN light-emitting diodes: Efficiency-limiting processes at high injection
  • Avrutin, Vitaliy; Hafiz, Shopan din Ahmad; Zhang, Fan
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 31, Issue 5 https://doi.org/10.1116/1.4810789
journal September 2013
Efficiency droop in light-emitting diodes: Challenges and countermeasures: Efficiency droop in light-emitting diodes: Challenges and countermeasures journal January 2013
Compensation between radiative and Auger recombinations in III-nitrides: The scaling law of separated-wavefunction recombinations journal November 2019
Carrier distribution in (0001)InGaN∕GaN multiple quantum well light-emitting diodes journal February 2008
Interplay of polarization fields and Auger recombination in the efficiency droop of nitride light-emitting diodes journal December 2012
Spontaneous polarization and piezoelectric field in G a N / A l 0.15 Ga 0.85 N quantum wells: Impact on the optical spectra journal January 2000
Blue-emitting InGaN–GaN double-heterostructure light-emitting diodes reaching maximum quantum efficiency above 200A∕cm2 journal December 2007
Photocurrent spectroscopy of GaAs/ Al x Ga 1 x As quantum wells in an electric field journal March 1986
The influence of Al composition on point defect incorporation in AlGaN journal January 2012
High-power low-droop violet semipolar (303¯1¯) InGaN/GaN light-emitting diodes with thick active layer design journal October 2014
Fully-screened polarization-induced electric fields in blue∕violet InGaN∕GaN light-emitting devices grown on bulk GaN journal July 2005