Degradation of Adsorbed Bisphenol A by Soluble Mn(III)

Sun, Yanchen; Im, Jeongdae; Shobnam, Nusrat; Fanourakis, Sofia K.; He, Lilin; Anovitz, Lawrence M.; Erickson, Paul R.; Sun, Huihui; Zhuang, Jie; Löffler, Frank E.

doi:10.1021/acs.est.1c03862

Degradation of Adsorbed Bisphenol A by Soluble Mn(III)

Journal Article · Fri Sep 24 00:00:00 EDT 2021 · Environmental Science and Technology

DOI:https://doi.org/10.1021/acs.est.1c03862· OSTI ID:1833924

^[1]; ^[2]; Shobnam, Nusrat ^[2]; Fanourakis, Sofia K. ^[3]; ^[4]; ^[4]; Erickson, Paul R. ^[5]; Sun, Huihui ^[6]; ^[6]; ^[1]

Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Kansas State Univ., Manhattan, KS (United States)
Univ. of Houston, TX (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
REGENESIS, San Clemente, CA (United States)
Univ. of Tennessee, Knoxville, TN (United States)

Bisphenol A (BPA), a high production volume chemical and potential endocrine disruptor, is found to be associated with sediments and soils due to its hydrophobicity (log K_OW of 3.42). Here, we used superfine powdered activated carbon (SPAC) with a particle size of 1.38 ± 0.03 μm as a BPA sorbent and assessed degradation of BPA by oxidized manganese (Mn) species. SPAC strongly sorbed BPA, and desorption required organic solvents. No degradation of adsorbed BPA (278.7 ± 0.6 mg BPA g^–1 SPAC) was observed with synthetic, solid α-MnO₂ with a particle size of 15.41 ± 1.35 μm; however, 89% mass reduction occurred following the addition of 0.5 mM soluble Mn(III). Small-angle neutron scattering data suggested that both adsorption and degradation of BPA occurred in SPAC pores. The findings demonstrate that Mn(III) mediates oxidative transformation of dissolved and adsorbed BPA, the latter observation challenging the paradigm that contaminant desorption and diffusion out of pore structures are required steps for degradation. Soluble Mn(III) is abundant near oxic-anoxic interfaces, and the observation that adsorbed BPA is susceptible to degradation has implications for predicting, and possibly managing, the fate and longevity of BPA in environmental systems.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1833924

Journal Information:: Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 19 Vol. 55; ISSN 0013-936X

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (75)

A new method for the detection and enumeration of manganese oxidizing and reducing microorganisms Krumbein, W. E.; Altmann, H. J. Helgoländer Wissenschaftliche Meeresuntersuchungen, Vol. 25, Issue 2-3 https://doi.org/10.1007/BF01611203	journal	September 1973
Characteristics, sources, and transport of tetrabromobisphenol A and bisphenol A in soils from a typical e-waste recycling area in South China Huang, De-Yin; Zhao, Hai-Qing; Liu, Chuan-Ping Environmental Science and Pollution Research, Vol. 21, Issue 9 https://doi.org/10.1007/s11356-014-2535-2	journal	January 2014
Biodegradation of bisphenol A by an algal-bacterial system Eio, Er Jin; Kawai, Minako; Niwa, Chiaki Environmental Science and Pollution Research, Vol. 22, Issue 19 https://doi.org/10.1007/s11356-015-4693-2	journal	May 2015
Purification and characterization of an extracellular Mn(II)-dependent peroxidase from the lignin-degrading basidiomycete, Phanerochaete chrysosporium Glenn, Jeffrey K.; Gold, Michael H. Archives of Biochemistry and Biophysics, Vol. 242, Issue 2, p. 329-341 https://doi.org/10.1016/0003-9861(85)90217-6	journal	November 1985
The biogeochemistry of manganese and iron reduction in marine sediments Burdige, David J. Earth-Science Reviews, Vol. 35, Issue 3 https://doi.org/10.1016/0012-8252(93)90040-E	journal	October 1993
Chemical and biological reduction of Mn (III)-pyrophosphate complexes: Potential importance of dissolved Mn (III) as an environmental oxidant Kostka, Joel E.; Luther, George W.; Nealson, Kenneth H. Geochimica et Cosmochimica Acta, Vol. 59, Issue 5 https://doi.org/10.1016/0016-7037(95)00007-0	journal	March 1995
Occurrence of phthalates and bisphenol A and F in the environment Fromme, Hermann; Küchler, Thomas; Otto, Thomas Water Research, Vol. 36, Issue 6 https://doi.org/10.1016/S0043-1354(01)00367-0	journal	March 2002
Fate of 14C-bisphenol A in soils Fent, Gunnar; Hein, Werner J.; Moendel, Martin J. Chemosphere, Vol. 51, Issue 8 https://doi.org/10.1016/S0045-6535(03)00100-0	journal	June 2003
A review of the environmental fate, effects, and exposures of bisphenol A Staples, Charles A.; Dome, Philip B.; Klecka, Gary M. Chemosphere, Vol. 36, Issue 10 https://doi.org/10.1016/S0045-6535(97)10133-3	journal	April 1998
Synthesis of ZnAlTi-LDO supported C60@AgCl nanoparticles and their photocatalytic activity for photo-degradation of Bisphenol A Ju, Liting; Wu, Pingxiao; Yang, Qiliang Applied Catalysis B: Environmental, Vol. 224 https://doi.org/10.1016/j.apcatb.2017.10.056	journal	May 2018
Sorption isotherms: A review on physical bases, modeling and measurement Limousin, G.; Gaudet, J. -P.; Charlet, L. Applied Geochemistry, Vol. 22, Issue 2 https://doi.org/10.1016/j.apgeochem.2006.09.010	journal	February 2007
Effects of temperature on adsorption and oxidative degradation of bisphenol A in an acid-treated iron-amended granular activated carbon Kim, Jihyun R.; Huling, Scott G.; Kan, Eunsung Chemical Engineering Journal, Vol. 262 https://doi.org/10.1016/j.cej.2014.10.065	journal	February 2015
4-Methylphenol produced in freshwater sediment microcosms is not a bisphenol A metabolite Im, Jeongdae; Prevatte, Carson W.; Lee, Hong Geun Chemosphere, Vol. 117 https://doi.org/10.1016/j.chemosphere.2014.09.008	journal	December 2014
Adsorptive removal of bisphenol A (BPA) from aqueous solution: A review Bhatnagar, Amit; Anastopoulos, Ioannis Chemosphere, Vol. 168 https://doi.org/10.1016/j.chemosphere.2016.10.121	journal	February 2017
Effect of the reduction degree of graphene oxide on the adsorption of Bisphenol A Bele, Sotiria; Samanidou, Victoria; Deliyanni, Eleni Chemical Engineering Research and Design, Vol. 109 https://doi.org/10.1016/j.cherd.2016.03.002	journal	May 2016
Simultaneous determination of pharmaceuticals, endocrine disrupting compounds and hormone in soils by gas chromatography–mass spectrometry Xu, Jian; Wu, Laosheng; Chen, Weiping Journal of Chromatography A, Vol. 1202, Issue 2 https://doi.org/10.1016/j.chroma.2008.07.001	journal	August 2008
Study on the removal of iron and manganese in groundwater by granular activated carbon bin Jusoh, Ahmad; Cheng, W. H.; Low, W. M. Desalination, Vol. 182, Issue 1-3 https://doi.org/10.1016/j.desal.2005.03.022	journal	November 2005
The hydraulic conductivity of sediments: A pore size perspective Ren, X. W.; Santamarina, J. C. Engineering Geology, Vol. 233 https://doi.org/10.1016/j.enggeo.2017.11.022	journal	January 2018
Estimation and modeling of coal pore accessibility using small angle neutron scattering Zhang, Rui; Liu, Shimin; Bahadur, Jitendra Fuel, Vol. 161 https://doi.org/10.1016/j.fuel.2015.08.067	journal	December 2015
Microbial Mn(IV) reduction requires an initial one-electron reductive solubilization step Lin, Hui; Szeinbaum, Nadia H.; DiChristina, Thomas J. Geochimica et Cosmochimica Acta, Vol. 99 https://doi.org/10.1016/j.gca.2012.09.020	journal	December 2012
Connecting particle interactions to agglomerate morphology and rheology of boehmite nanocrystal suspensions Weston, J. S.; Chun, J.; Schenter, G. Journal of Colloid and Interface Science, Vol. 572 https://doi.org/10.1016/j.jcis.2020.03.109	journal	July 2020
Correlating inter-particle forces and particle shape to shear-induced aggregation/fragmentation and rheology for dilute anisotropic particle suspensions: A complementary study via capillary rheometry and in-situ small and ultra-small angle X-ray scattering Krzysko, Anthony J.; Nakouzi, Elias; Zhang, Xin Journal of Colloid and Interface Science, Vol. 576 https://doi.org/10.1016/j.jcis.2020.04.016	journal	September 2020
Current state of in situ subsurface remediation by activated carbon-based amendments Fan, Dimin; Gilbert, Edward J.; Fox, Tom Journal of Environmental Management, Vol. 204 https://doi.org/10.1016/j.jenvman.2017.02.014	journal	December 2017
Influence of the coexisting contaminants on bisphenol A sorption and desorption in soil Li, Jinhua; Zhou, Baoxue; Liu, Yangqiao Journal of Hazardous Materials, Vol. 151, Issue 2-3 https://doi.org/10.1016/j.jhazmat.2007.06.001	journal	March 2008
Oxidative degradation kinetics and products of chlortetracycline by manganese dioxide Chen, Gao; Zhao, Ling; Dong, Yuan-hua Journal of Hazardous Materials, Vol. 193 https://doi.org/10.1016/j.jhazmat.2011.07.039	journal	October 2011
A novel manganese oxidizing bacterium-Aeromonas hydrophila strain DS02: Mn(II) oxidization and biogenic Mn oxides generation Zhang, Yue; Tang, Yankui; Qin, Zhiyi Journal of Hazardous Materials, Vol. 367 https://doi.org/10.1016/j.jhazmat.2019.01.012	journal	April 2019
Biologically mediated abiotic degradation (BMAD) of bisphenol A by manganese-oxidizing bacteria Shobnam, Nusrat; Sun, Yanchen; Mahmood, Maheen Journal of Hazardous Materials, Vol. 417 https://doi.org/10.1016/j.jhazmat.2021.125987	journal	September 2021
Extraction of organic compounds from representative shales and the effect on porosity DiStefano, Victoria H.; McFarlane, Joanna; Anovitz, Lawrence M. Journal of Natural Gas Science and Engineering, Vol. 35 https://doi.org/10.1016/j.jngse.2016.08.064	journal	September 2016
Adsorption and desorption behaviors of selected endocrine disrupting chemicals in simulated gastrointestinal fluids Fei, Ying-heng; Leung, Kenneth M. Y.; Li, Xiao-yan Marine Pollution Bulletin, Vol. 85, Issue 2 https://doi.org/10.1016/j.marpolbul.2014.01.047	journal	August 2014
Retention of a wide variety of organic pollutants by different nanofiltration/reverse osmosis membranes: controlling parameters of process Agenson, K. Journal of Membrane Science, Vol. 225, Issue 1-2 https://doi.org/10.1016/j.memsci.2003.08.006	journal	November 2003
Adsorption of heavy metal ions with carbon nanotubes Stafiej, A.; Pyrzynska, K. Separation and Purification Technology, Vol. 58, Issue 1 https://doi.org/10.1016/j.seppur.2007.07.008	journal	December 2007
Viruses in soil: Nano-scale undead drivers of microbial life, biogeochemical turnover and ecosystem functions Kuzyakov, Yakov; Mason-Jones, Kyle Soil Biology and Biochemistry, Vol. 127 https://doi.org/10.1016/j.soilbio.2018.09.032	journal	December 2018
A novel modification of manganese orthophosphate Mn3(PO4)2 Massa, Werner; Yakubovich, Olga V.; Dimitrova, Olga V. Solid State Sciences, Vol. 7, Issue 8 https://doi.org/10.1016/j.solidstatesciences.2005.03.005	journal	August 2005
Role of dissolved Mn(III) in transformation of organic contaminants: Non-oxidative versus oxidative mechanisms Hu, Erdan; Zhang, Ya; Wu, Shuyan Water Research, Vol. 111 https://doi.org/10.1016/j.watres.2017.01.013	journal	March 2017
Identification of 4-Hydroxycumyl Alcohol As the Major MnO ₂ -Mediated Bisphenol A Transformation Product and Evaluation of Its Environmental Fate Im, Jeongdae; Prevatte, Carson W.; Campagna, Shawn R. Environmental Science & Technology, Vol. 49, Issue 10 https://doi.org/10.1021/acs.est.5b00372	journal	May 2015
Fate of Tetrabromobisphenol A (TBBPA) and Formation of Ester- and Ether-Linked Bound Residues in an Oxic Sandy Soil Li, Fangjie; Wang, Jiajia; Jiang, Bingqi Environmental Science & Technology, Vol. 49, Issue 21 https://doi.org/10.1021/acs.est.5b01900	journal	October 2015
Activation of Manganese Oxidants with Bisulfite for Enhanced Oxidation of Organic Contaminants: The Involvement of Mn(III) Sun, Bo; Guan, Xiaohong; Fang, Jingyun Environmental Science & Technology, Vol. 49, Issue 20 https://doi.org/10.1021/acs.est.5b03111	journal	October 2015
Fate of Bisphenol A in Terrestrial and Aquatic Environments Im, Jeongdae; Löffler, Frank E. Environmental Science & Technology, Vol. 50, Issue 16 https://doi.org/10.1021/acs.est.6b00877	journal	August 2016
Cell Surface Display Fungal Laccase as a Renewable Biocatalyst for Degradation of Persistent Micropollutants Bisphenol A and Sulfamethoxazole Chen, Yingying; Stemple, Brooke; Kumar, Manish Environmental Science & Technology, Vol. 50, Issue 16 https://doi.org/10.1021/acs.est.6b01641	journal	July 2016
Manganese-Driven Carbon Oxidation at Oxic–Anoxic Interfaces Jones, Morris E.; Nico, Peter S.; Ying, Samantha Environmental Science & Technology, Vol. 52, Issue 21 https://doi.org/10.1021/acs.est.8b03791	journal	September 2018
Influence of Pyrophosphate on the Generation of Soluble Mn(III) from Reactions Involving Mn Oxides and Mn(VII) Liu, Weifan; Sun, Bo; Qiao, Junlian Environmental Science & Technology, Vol. 53, Issue 17 https://doi.org/10.1021/acs.est.9b03456	journal	August 2019
Mn(III) Center Availability as a Rate Controlling Factor in the Oxidation of Phenol and Sulfide on δ-MnO ₂ Nico, Peter S.; Zasoski, Robert J. Environmental Science & Technology, Vol. 35, Issue 16 https://doi.org/10.1021/es001848q	journal	August 2001
Oxidative Transformation of Triclosan and Chlorophene by Manganese Oxides Zhang, Huichun; Huang, Ching-Hua Environmental Science & Technology, Vol. 37, Issue 11 https://doi.org/10.1021/es026190q	journal	June 2003
Sorption of Oxytetracycline to Iron Oxides and Iron Oxide-Rich Soils Figueroa, Raquel A.; MacKay, Allison A. Environmental Science & Technology, Vol. 39, Issue 17 https://doi.org/10.1021/es048044l	journal	July 2005
Transformation and Removal of Bisphenol A from Aqueous Phase via Peroxidase-Mediated Oxidative Coupling Reactions: Efficacy, Products, and Pathways Huang, Qingguo; Weber, Walter J. Environmental Science & Technology, Vol. 39, Issue 16 https://doi.org/10.1021/es050036x	journal	July 2005
Occurrence of Eight Bisphenol Analogues in Indoor Dust from the United States and Several Asian Countries: Implications for Human Exposure Liao, Chunyang; Liu, Fang; Guo, Ying Environmental Science & Technology, Vol. 46, Issue 16 https://doi.org/10.1021/es302004w	journal	July 2012
Bisphenol Analogues in Sediments from Industrialized Areas in the United States, Japan, and Korea: Spatial and Temporal Distributions Liao, Chunyang; Liu, Fang; Moon, Hyo-Bang Environmental Science & Technology, Vol. 46, Issue 21 https://doi.org/10.1021/es303191g	journal	October 2012
Reduction of Carbadox Mediated by Reaction of Mn(III) with Oxalic Acid Chen, Wan-Ru; Liu, Cun; Boyd, Stephen A. Environmental Science & Technology, Vol. 47, Issue 3 https://doi.org/10.1021/es303895w	journal	January 2013
Oxidative UO ₂ Dissolution Induced by Soluble Mn(III) Wang, Zimeng; Xiong, Wei; Tebo, Bradley M. Environmental Science & Technology, Vol. 48, Issue 1 https://doi.org/10.1021/es4037308	journal	December 2013
Reductive Dissolution of Manganese(III/Iv) Oxides by Substituted Phenols Stone, Alan T. Environmental Science & Technology, Vol. 21, Issue 10 https://doi.org/10.1021/es50001a011	journal	October 1987
Effects of Temperature and Acidic Pre-Treatment on Fenton-Driven Oxidation of MTBE-Spent Granular Activated Carbon Kan, Eunsung; Huling, Scott G. Environmental Science & Technology, Vol. 43, Issue 5 https://doi.org/10.1021/es802360f	journal	January 2009
Oxidative Removal of Bisphenol A by Manganese Dioxide: Efficacy, Products, and Pathways Lin, Kunde; Liu, Weiping; Gan, Jay Environmental Science & Technology, Vol. 43, Issue 10 https://doi.org/10.1021/es900235f	journal	May 2009
The Mechanism of the Permanganate-Oxalate Reaction Adler, Seymour J.; Noyes, Richard M. Journal of the American Chemical Society, Vol. 77, Issue 8 https://doi.org/10.1021/ja01613a002	journal	April 1955
Aqueous Solubilities of Estrone, 17β-Estradiol, 17α-Ethynylestradiol, and Bisphenol A Shareef, Ali; Angove, Michael J.; Wells, John D. Journal of Chemical & Engineering Data, Vol. 51, Issue 3 https://doi.org/10.1021/je050318c	journal	April 2006
Three manganese oxide-rich marine sediments harbor similar communities of acetate-oxidizing manganese-reducing bacteria Vandieken, Verona; Pester, Michael; Finke, Niko The ISME Journal, Vol. 6, Issue 11 https://doi.org/10.1038/ismej.2012.41	journal	May 2012
Chemical contaminants — a toxic mixture for neurodevelopment Hernandez, Morgan E.; Gore, Andrea C. Nature Reviews Endocrinology, Vol. 13, Issue 6 https://doi.org/10.1038/nrendo.2017.40	journal	April 2017
Light-driven anaerobic microbial oxidation of manganese Daye, Mirna; Klepac-Ceraj, Vanja; Pajusalu, Mihkel Nature, Vol. 576, Issue 7786 https://doi.org/10.1038/s41586-019-1804-0	journal	December 2019
Bacterial chemolithoautotrophy via manganese oxidation Yu, Hang; Leadbetter, Jared R. Nature, Vol. 583, Issue 7816 https://doi.org/10.1038/s41586-020-2468-5	journal	July 2020
Characterizing polymer structure with small-angle neutron scattering: A Tutorial Wei, Yuan; Hore, Michael J. A. Journal of Applied Physics, Vol. 129, Issue 17 https://doi.org/10.1063/5.0045841	journal	May 2021
Evidence for the presence of Mn(III) intermediates in the bacterial oxidation of Mn(II) Webb, S. M.; Dick, G. J.; Bargar, J. R. Proceedings of the National Academy of Sciences, Vol. 102, Issue 15 https://doi.org/10.1073/pnas.0409119102	journal	March 2005
Low-dose exposure to bisphenol A and replacement bisphenol S induces precocious hypothalamic neurogenesis in embryonic zebrafish Kinch, Cassandra D.; Ibhazehiebo, Kingsley; Jeong, Joo-Hyun Proceedings of the National Academy of Sciences, Vol. 112, Issue 5 https://doi.org/10.1073/pnas.1417731112	journal	January 2015
Manganese oxide minerals: Crystal structures and economic and environmental significance Post, J. E. Proceedings of the National Academy of Sciences, Vol. 96, Issue 7 https://doi.org/10.1073/pnas.96.7.3447	journal	March 1999
The Reflection of X-rays by Crystals Bragg, W. H.; Bragg, W. L. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 88, Issue 605 https://doi.org/10.1098/rspa.1913.0040	journal	July 1913
PRINSAS – a Windows-based computer program for the processing and interpretation of small-angle scattering data tailored to the analysis of sedimentary rocks Hinde, Alan L. Journal of Applied Crystallography, Vol. 37, Issue 6 https://doi.org/10.1107/S0021889804021260	journal	November 2004
Irena : tool suite for modeling and analysis of small-angle scattering Ilavsky, Jan; Jemian, Peter R. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889809002222	journal	February 2009
Approximations Leading to a Unified Exponential/Power-Law Approach to Small-Angle Scattering Beaucage, G. Journal of Applied Crystallography, Vol. 28, Issue 6 https://doi.org/10.1107/S0021889895005292	journal	December 1995
The suite of small-angle neutron scattering instruments at Oak Ridge National Laboratory Heller, William T.; Cuneo, Matthew; Debeer-Schmitt, Lisa Journal of Applied Crystallography, Vol. 51, Issue 2 https://doi.org/10.1107/S1600576718001231	journal	February 2018
Soluble Mn(III) in Suboxic Zones Trouwborst, R. E. Science, Vol. 313, Issue 5795 https://doi.org/10.1126/science.1132876	journal	September 2006
Manganese Redox Chemistry Revisited Johnson, Kenneth S. Science, Vol. 313, Issue 5795 https://doi.org/10.1126/science.1133496	journal	September 2006
Manganese- and Iron-Dependent Marine Methane Oxidation Beal, E. J.; House, C. H.; Orphan, V. J. Science, Vol. 325, Issue 5937 https://doi.org/10.1126/science.1169984	journal	July 2009
Abundant Porewater Mn(III) Is a Major Component of the Sedimentary Redox System Madison, A. S.; Tebo, B. M.; Mucci, A. Science, Vol. 341, Issue 6148 https://doi.org/10.1126/science.1241396	journal	August 2013
Characterization and Analysis of Porosity and Pore Structures Anovitz, Lawrence M.; Cole, David R. Reviews in Mineralogy and Geochemistry, Vol. 80, Issue 1 https://doi.org/10.2138/rmg.2015.80.04	journal	January 2015
Oxidative Formation and Removal of Complexed Mn(III) by Pseudomonas Species Wright, Mitchell H.; Geszvain, Kati; Oldham, Véronique E. Frontiers in Microbiology, Vol. 9 https://doi.org/10.3389/fmicb.2018.00560	journal	April 2018
Kinetics of microbial manganese oxidation and trace metal binding in sediments: Results from an in situ dialysis technique: Microbial trace metal binding Kepkay, Paul E. Limnology and Oceanography, Vol. 30, Issue 4 https://doi.org/10.4319/lo.1985.30.4.0713	journal	July 1985
Vertical transport of heavy metals by settling particles in Lake Zurich: Metals and settling particles Sigg, Laura; Sturm, Michael; Kistler, David Limnology and Oceanography, Vol. 32, Issue 1 https://doi.org/10.4319/lo.1987.32.1.0112	journal	January 1987

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Mn(III)
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activated carbon
adsorption
bisphenol A degradation
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small-angle neutron scattering (SANS)

Degradation of Adsorbed Bisphenol A by Soluble Mn(III)

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