Development of CuFeMnAlO4+δ oxygen carrier with high attrition resistance and 50-kWth methane/air chemical looping combustion tests

Siriwardane, Ranjani; Riley, Jarrett; Benincosa, William; Bayham, Samuel; Bobek, Michael; Straub, Douglas; Weber, Justin

doi:10.1016/j.apenergy.2021.116507

Development of CuFeMnAlO_4+δ oxygen carrier with high attrition resistance and 50-kWth methane/air chemical looping combustion tests

Journal Article · Mon Jan 25 00:00:00 EST 2021 · Applied Energy

DOI:https://doi.org/10.1016/j.apenergy.2021.116507· OSTI ID:1833597

Siriwardane, Ranjani ^[1]; Riley, Jarrett ^[2]; Benincosa, William ^[3]; Bayham, Samuel ^[1]; Bobek, Michael ^[3]; Straub, Douglas ^[1]; Weber, Justin ^[1]

National Energy Technology Lab. (NETL), Morgantown, WV (United States)
National Energy Technology Lab. (NETL), Morgantown, WV (United States); Leidos Research Support, Morgantown, WV (United States)
National Energy Technology Lab. (NETL), Morgantown, WV (United States); Oak Ridge Inst. for Science and Education (ORISE), Morgantown, WV (United States)

A Copper-Ferri-Manganese-Aluminate spinel (CuFeMnAlO_4+δ) oxygen carrier, developed at the US Department of Energy’s (DOE) National Energy Technology Laboratory (NETL), shows promising results for chemical looping combustion with methane. Attrition resistance of the spinel oxygen carrier (160–600 µm) produced by a wet agglomeration method was significantly higher than that observed previously with a Copper-Ferri-Aluminate (CuFeAlO₄) oxygen carrier. Improved attrition resistance of the novel carrier can be attributed to minimal alumina phase segregation and minimal carbon formation. Heats of reaction measured by differential scanning calorimetry indicated exothermicity during reduction with methane. The total oxygen transfer capacity of the material was about 10.5 wt% at 850 °C. The attrition resistance and the oxygen transfer capacity of the carrier prepared at a commercial manufacturing facility (180 kg) were very similar to observed values during the development phase with the lab scale preparations. The material displays satisfactory methane conversion and significantly high particle durability during a 54 h test campaign conducted in NETL’s 50-kWth chemical looping dual fluid bed reactor unit at temperatures ranging from 700 to 900 °C. Low oxygen carrier make-up cost, due to the use of natural ore and pigment grade raw materials during synthesis and very low attrition rates, exceeded the performance goals determined by systems studies.

View Accepted Manuscript (DOE)

Research Organization:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)

Sponsoring Organization:: USDOE; USDOE Office of Fossil Energy (FE)

OSTI ID:: 1833597

Alternate ID(s):: OSTI ID: 2325416
OSTI ID: 23187418

Report Number(s):: DOE/NETL--2021/2836

Journal Information:: Applied Energy, Journal Name: Applied Energy Vol. 286; ISSN 0306-2619

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (35)

Chemical Looping Combustion Using Two Different Perovskite Based Oxygen Carriers: A Pilot Study Mayer, Karl; Piesenberger, Stephan; Penthor, Stefan Energy Technology, Vol. 6, Issue 12 https://doi.org/10.1002/ente.201800244	journal	November 2018
Chemical looping technology for energy and chemical production: Chemical looping technology Bayham, Samuel C.; Tong, Andrew; Kathe, Mandar Wiley Interdisciplinary Reviews: Energy and Environment, Vol. 5, Issue 2 https://doi.org/10.1002/wene.173	journal	April 2015
Interaction of iron–copper mixed metal oxide oxygen carriers with simulated synthesis gas derived from steam gasification of coal Siriwardane, Ranjani V.; Ksepko, Ewelina; Tian, Hanjing Applied Energy, Vol. 107 https://doi.org/10.1016/j.apenergy.2013.01.063	journal	July 2013
Combined oxides as oxygen-carrier material for chemical-looping with oxygen uncoupling Rydén, Magnus; Leion, Henrik; Mattisson, Tobias Applied Energy, Vol. 113 https://doi.org/10.1016/j.apenergy.2013.06.016	journal	January 2014
Investigation of the performance of a copper based oxygen carrier for chemical looping combustion in a 120 kW pilot plant for gaseous fuels Penthor, Stefan; Zerobin, Florian; Mayer, Karl Applied Energy, Vol. 145 https://doi.org/10.1016/j.apenergy.2015.01.079	journal	May 2015
Parametric and dynamic studies of an iron-based 25-kWth coal direct chemical looping unit using sub-bituminous coal Bayham, Samuel; McGiveron, Omar; Tong, Andrew Applied Energy, Vol. 145 https://doi.org/10.1016/j.apenergy.2015.02.026	journal	May 2015
Iron oxide looping for natural gas conversion in a countercurrent moving bed reactor Zeng, Liang; Tong, Andrew; Kathe, Mandar Applied Energy, Vol. 157 https://doi.org/10.1016/j.apenergy.2015.06.029	journal	November 2015
Chemical looping combustion of hard coal in a 1 MWth pilot plant using ilmenite as oxygen carrier Ströhle, Jochen; Orth, Matthias; Epple, Bernd Applied Energy, Vol. 157 https://doi.org/10.1016/j.apenergy.2015.06.035	journal	November 2015
Synthesis and characterization of geopolymer oxygen carriers for chemical looping combustion Miccio, Francesco; Natali Murri, Annalisa; Landi, Elena Applied Energy, Vol. 194 https://doi.org/10.1016/j.apenergy.2017.03.005	journal	May 2017
Unique phase identification of trimetallic copper iron manganese oxygen carrier using simultaneous differential scanning calorimetry/thermogravimetric analysis during chemical looping combustion reactions with methane Benincosa, William; Siriwardane, Ranjani; Tian, Hanjing Applied Energy, Vol. 203 https://doi.org/10.1016/j.apenergy.2017.06.061	journal	October 2017
50-kWth methane/air chemical looping combustion tests with commercially prepared CuO-Fe2O3-alumina oxygen carrier with two different techniques Siriwardane, Ranjani; Riley, Jarrett; Bayham, Samuel Applied Energy, Vol. 213 https://doi.org/10.1016/j.apenergy.2018.01.016	journal	March 2018
Particle scale modeling of CuFeAlO4 during reduction with CO in chemical looping applications Riley, Jarrett; Siriwardane, Ranjani; Tian, Hanjing Applied Energy, Vol. 251 https://doi.org/10.1016/j.apenergy.2019.04.174	journal	October 2019
A particle-scale reduction model of copper iron manganese oxide with CO for chemical looping combustion Benincosa, William; Siriwardane, Ranjani; Tian, Hanjing Applied Energy, Vol. 262 https://doi.org/10.1016/j.apenergy.2019.114407	journal	March 2020
Natural minerals as oxygen carriers for chemical looping combustion in a dual circulating fluidized bed system Pröll, Tobias; Mayer, Karl; Bolhàr-Nordenkampf, Johannes Energy Procedia, Vol. 1, Issue 1 https://doi.org/10.1016/j.egypro.2009.01.006	journal	February 2009
Chemical Looping Combustion in a Bed of Iron Loaded Geopolymers Miccio, Francesco; Landi, Elena; Murri, Annalisa Natali Energy Procedia, Vol. 114 https://doi.org/10.1016/j.egypro.2017.03.1180	journal	July 2017
Synergetic effects of mixed copper–iron oxides oxygen carriers in chemical looping combustion Siriwardane, Ranjani; Tian, Hanjing; Simonyi, Thomas Fuel, Vol. 108 https://doi.org/10.1016/j.fuel.2013.01.023	journal	June 2013
Chemical-looping combustion in a 100-kW unit using a mixture of ilmenite and manganese ore as oxygen carrier Linderholm, Carl; Schmitz, Matthias; Knutsson, Pavleta Fuel, Vol. 166 https://doi.org/10.1016/j.fuel.2015.11.015	journal	February 2016
Recent developments in oxygen carrier materials for hydrogen production via chemical looping processes Protasova, Lidia; Snijkers, Frans Fuel, Vol. 181 https://doi.org/10.1016/j.fuel.2016.04.110	journal	October 2016
Operating experience with chemical looping combustion in a 120kW dual circulating fluidized bed (DCFB) unit Kolbitsch, P.; Bolhàr-Nordenkampf, J.; Pröll, T. International Journal of Greenhouse Gas Control, Vol. 4, Issue 2 https://doi.org/10.1016/j.ijggc.2009.09.014	journal	March 2010
Operation of a 50-kWth chemical looping combustion test facility under autothermal conditions Bayham, Samuel; Straub, Douglas; Weber, Justin International Journal of Greenhouse Gas Control, Vol. 87 https://doi.org/10.1016/j.ijggc.2019.05.022	journal	August 2019
11,000 h of chemical-looping combustion operation—Where are we and where do we want to go? Lyngfelt, Anders; Brink, Anders; Langørgen, Øyvind International Journal of Greenhouse Gas Control, Vol. 88 https://doi.org/10.1016/j.ijggc.2019.05.023	journal	September 2019
Chemical-looping combustion of solid fuels in a 100 kW dual circulating fluidized bed system using iron ore as oxygen carrier Linderholm, Carl; Schmitz, Matthias Journal of Environmental Chemical Engineering, Vol. 4, Issue 1 https://doi.org/10.1016/j.jece.2016.01.006	journal	March 2016
Progress in Chemical-Looping Combustion and Reforming technologies Adanez, Juan; Abad, Alberto; Garcia-Labiano, Francisco Progress in Energy and Combustion Science, Vol. 38, Issue 2, p. 215-282 https://doi.org/10.1016/j.pecs.2011.09.001	journal	April 2012
Chemical looping combustion of solid fuels Adánez, J.; Abad, A.; Mendiara, T. Progress in Energy and Combustion Science, Vol. 65 https://doi.org/10.1016/j.pecs.2017.07.005	journal	March 2018
Particulate solid attrition in CFB systems – An assessment for emerging technologies Bayham, Samuel C.; Breault, Ronald; Monazam, Esmail Powder Technology, Vol. 302 https://doi.org/10.1016/j.powtec.2016.08.016	journal	November 2016
CLC, a promising concept with challenging development issues Gauthier, T.; Yazdanpanah, M.; Forret, A. Powder Technology, Vol. 316 https://doi.org/10.1016/j.powtec.2017.01.003	journal	July 2017
Bench scale analysis of the physical attrition properties for copper-ferri-aluminate oxygen carriers during chemical looping combustion Riley, Jarrett; Siriwardane, Ranjani; Poston, James Powder Technology, Vol. 366 https://doi.org/10.1016/j.powtec.2020.02.067	journal	April 2020
Investigation of chemical looping combustion of natural gas at 1 MWth scale Ohlemüller, Peter; Reitz, Michael; Ströhle, Jochen Proceedings of the Combustion Institute, Vol. 37, Issue 4 https://doi.org/10.1016/j.proci.2018.07.035	journal	January 2019
Present status and overview of Chemical Looping Combustion technology Nandy, Anirban; Loha, Chanchal; Gu, Sai Renewable and Sustainable Energy Reviews, Vol. 59 https://doi.org/10.1016/j.rser.2016.01.003	journal	June 2016
Trimetallic Oxygen Carriers CuFeMnO ₄ , CuFeMn ₂ O ₄ , and CuFe _0.5 Mn _1.5 O ₄ for Chemical Looping Combustion Fan, Yueying; Siriwardane, Ranjani; Tian, Hanjing Energy & Fuels, Vol. 29, Issue 10 https://doi.org/10.1021/acs.energyfuels.5b01388	journal	September 2015
CO 2 Capture with Chemical Looping Combustion of Gaseous Fuels: An Overview Li, Jing; Zhang, Hedong; Gao, Zuopeng Energy & Fuels, Vol. 31, Issue 4 https://doi.org/10.1021/acs.energyfuels.6b03204	journal	March 2017
Novel New Oxygen Carriers for Chemical Looping Combustion of Solid Fuels Fan, Yueying; Siriwardane, Ranjani Energy & Fuels, Vol. 28, Issue 3 https://doi.org/10.1021/ef402528g	journal	February 2014
Chemical-Looping Combustion of Hard Coal: Autothermal Operation of a 1 MWth Pilot Plant Ohlemüller, Peter; Busch, Jan-Peter; Reitz, Michael Journal of Energy Resources Technology, Vol. 138, Issue 4 https://doi.org/10.1115/1.4032357	journal	January 2016
Chemical Looping Technology: Oxygen Carrier Characteristics Luo, Siwei; Zeng, Liang; Fan, Liang-Shih Annual Review of Chemical and Biomolecular Engineering, Vol. 6, Issue 1 https://doi.org/10.1146/annurev-chembioeng-060713-040334	journal	July 2015
Chemical Looping Pilot Plant Results Using a Nickel-Based Oxygen Carrier Pröll, T.; Kolbitsch, P.; Bolhàr-Nordenkampf, J. Oil & Gas Science and Technology – Revue d’IFP Energies nouvelles, Vol. 66, Issue 2 https://doi.org/10.2516/ogst/2010036	journal	March 2011

Similar Records

Operation of a 50-kW_th chemical looping combustion test facility under autothermal conditions

Journal Article · Sat May 25 20:00:00 EDT 2019 · International Journal of Greenhouse Gas Control · OSTI ID:1582387

Encapsulation method for preparation of pellets with high attrition resistance

Patent · Tue Sep 06 00:00:00 EDT 2022 · OSTI ID:1925049

50-kWth methane/air chemical looping combustion tests with commercially prepared CuO-Fe₂O₃-alumina oxygen carrier with two different techniques

Journal Article · Sat Jan 27 19:00:00 EST 2018 · Applied Energy · OSTI ID:1461079

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Attrition resistant oxygen carrier
CuFeMnAlO4+δ oxygen carrier
Methane chemical looping combustion t
Oxygen carrier commercial preparation

Development of CuFeMnAlO4+δ oxygen carrier with high attrition resistance and 50-kWth methane/air chemical looping combustion tests

Citation Formats

References (35)

Similar Records

Related Subjects

Development of CuFeMnAlO_4+δ oxygen carrier with high attrition resistance and 50-kWth methane/air chemical looping combustion tests