On-surface cyclodehydrogenation reaction pathway determined by selective molecular deuterations

Ma, Chuanxu; Xiao, Zhongcan; Bonnesen, Peter V.; Liang, Liangbo; Puretzky, Alexander A.; Huang, Jingsong; Kolmer, Marek; Sumpter, Bobby G.; Lu, Wenchang; Hong, Kunlun; Bernholc, Jerzy; Li, An-Ping

doi:10.1039/D1SC04908A

On-surface cyclodehydrogenation reaction pathway determined by selective molecular deuterations

Journal Article · Tue Dec 07 23:00:00 EST 2021 · Chemical Science

DOI:https://doi.org/10.1039/D1SC04908A· OSTI ID:1832076

^[1]; ^[2]; Bonnesen, Peter V. ^[3]; ^[3]; Puretzky, Alexander A. ^[3]; ^[3]; Kolmer, Marek ^[4]; ^[3]; Lu, Wenchang ^[5]; Hong, Kunlun ^[3]; ^[5]; ^[3]

Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA, Hefei National Laboratory for Physical Sciences at the Microscale, Synergetic Innovation Center of Quantum Information & Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026, China
Department of Physics, North Carolina State University, Raleigh, NC 27695, USA
Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA
Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA, Ames Laboratory, U.S. Department of Energy, Ames, IA 50011, USA
Department of Physics, North Carolina State University, Raleigh, NC 27695, USA, Computational Sciences and Engineering Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA

Selective deuterations were exploited to synthesize graphene nanoribbons on Au(111) surface with a specific H/D pattern on edges, allowing the determination of cyclodehydrogenation reaction pathway within the framework of pericyclic reactions.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; AC02-07CH11358; AC05-00OR22725

OSTI ID:: 1832076

Alternate ID(s):: OSTI ID: 1837415
OSTI ID: 1837757

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 47 Vol. 12; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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