Oxygen redox chemistry in P2-Na0.6Li0.11Fe0.27Mn0.62O2 cathode for high-energy Na-ion batteries

Cao, Ming-Hui; Li, Ren-Yan; Lin, Shi-Ya; Zheng, Shao-Di; Ma, Lu; Tan, Sha; Hu, Enyuan; Shadike, Zulipiya; Yang, Xiao-Qing; Fu, Zheng-Wen

doi:10.1039/d1ta08471b

Title: Oxygen redox chemistry in P2-Na_0.6Li_0.11Fe_0.27Mn_0.62O₂ cathode for high-energy Na-ion batteries

Journal Article · Fri Jan 01 00:00:00 EST 2021 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/d1ta08471b· OSTI ID:1831453

Cao, Ming-Hui ^[1]; Li, Ren-Yan ^[2]; Lin, Shi-Ya ^[2]; Zheng, Shao-Di ^[2]; Ma, Lu ^[3]; Tan, Sha ^[4]; Hu, Enyuan ^[4]; Shadike, Zulipiya ^[5];

^[4];

^[6]

East China University of Technology, Nanchang (China); Fudan Univ., Shanghai (China)
East China University of Technology, Nanchang (China)
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Shanghai Jiao Tong Univ. (China)
Fudan Univ., Shanghai (China)

Owing to the abundance of raw material reserves and low cost, Na-ion batteries (NIBs) have successfully gained widespread attention from academic and industrial communities in the past few decades. However, the insufficient cathode energy density is still one of the critical bottlenecks restricting the development of NIBs. Following a strategy of introducing Li+ into the transition-metal (TM) layer to enhance the oxygen redox reaction, a novel layered cathode material P2-Na_0.6Li_0.11Fe_0.27Mn_0.62O₂ (NLFMO) was designed and successfully synthesized. This NLFMO cathode not only delivers a large initial reversible capacity of 207.3 mA h g^-1, but also shows a good cycling performance (104.2 mA h g^-1 after 80 cycles) and rate capability (126.2 mA h g^-1 at 1C). The ultrahigh capacity is contributed by both cationic (Fe³⁺/Fe⁴⁺ and Mn³⁺/Mn⁴⁺) and partially reversible anionic redox (O^2-/O^n-) reactions, revealed by in situ X-ray absorption spectroscopy (XAS) and X-ray photoelectron spectroscopy (XPS) techniques. Moreover, no detrimental P2–O2 phase transition was observed in ex situ X-ray diffraction (XRD) patterns, confirming the high structural stability during Na⁺ deintercalation/intercalation processes. These results provide valuable information about the high-energy density layered cathode materials based on anionic redox reactions for NIBs.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; National Natural Science Foundation of China (NSFC); Shanghai Science and Technology Committee; Doctoral Scientific Research Foundation of East China University of Technology; USDOE

Grant/Contract Number:: SC0012704; 22005047; 19DZ2270100; DHBK2019121; S202110405024

OSTI ID:: 1831453

Alternate ID(s):: OSTI ID: 1833909

Report Number(s):: BNL-222420-2021-JAAM

Journal Information:: Journal of Materials Chemistry. A, Vol. 9, Issue 48; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Oxygen redox chemistry in P2-Na0.6Li0.11Fe0.27Mn0.62O2 cathode for high-energy Na-ion batteries

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Title: Oxygen redox chemistry in P2-Na_0.6Li_0.11Fe_0.27Mn_0.62O₂ cathode for high-energy Na-ion batteries