Direct Optical Lithography of CsPbX3 Nanocrystals via Photoinduced Ligand Cleavage with Postpatterning Chemical Modification and Electronic Coupling

Pan, Jia-Ahn; Ondry, Justin C.; Talapin, Dmitri V.

doi:10.1021/acs.nanolett.1c02249

Title: Direct Optical Lithography of CsPbX₃ Nanocrystals via Photoinduced Ligand Cleavage with Postpatterning Chemical Modification and Electronic Coupling

Journal Article · Fri Sep 03 00:00:00 EDT 2021 · Nano Letters

DOI:https://doi.org/10.1021/acs.nanolett.1c02249· OSTI ID:1831420

Pan, Jia-Ahn ^[1];

^[1];

^[2]

Univ. of Chicago, IL (United States)
Univ. of Chicago, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)

Microscale patterning of solution-processed nanomaterials is important for integration in functional devices. Colloidal lead halide perovskite (LHP) nanocrystals (NCs) can be particularly challenging to pattern due to their incompatibility with polar solvents and lability of surface ligands. Here, we introduce a direct photopatterning approach for LHP NCs through the binding and subsequent cleavage of a photosensitive oxime sulfonate ester (-C=N-OSOO-). The photosensitizer binds to the NCs through its sulfonate group and is cleaved at the N-O bond during photoirradiation with 405 nm light. This bond cleavage decreases the solubility of the NCs, which allows patterns to emerge upon development with toluene. Postpatterning ligand exchange results in photoluminescence quantum yields of up to 79%, while anion exchange provides tunability in the emission wavelength. Finally, the patterned NC films show photoconductive behavior, demonstrating that good electrical contact between the NCs can be established.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Science Foundation (NSF); US Air Force Office of Scientific Research (AFOSR)

Grant/Contract Number:: AC02-06CH11357; ECCS-2025633; CHE-1905290; FA9550-18-1-0099; DMR-2011854

OSTI ID:: 1831420

Journal Information:: Nano Letters, Vol. 21, Issue 18; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (56)

Essentially Trap-Free CsPbBr ₃ Colloidal Nanocrystals by Postsynthetic Thiocyanate Surface Treatment Koscher, Brent A.; Swabeck, Joseph K.; Bronstein, Noah D. Journal of the American Chemical Society, Vol. 139, Issue 19 https://doi.org/10.1021/jacs.7b02817	journal	May 2017
Ligand Mediated Transformation of Cesium Lead Bromide Perovskite Nanocrystals to Lead Depleted Cs ₄ PbBr ₆ Nanocrystals Liu, Zeke; Bekenstein, Yehonadav; Ye, Xingchen Journal of the American Chemical Society, Vol. 139, Issue 15 https://doi.org/10.1021/jacs.7b01409	journal	April 2017
Polymer Zwitterions for Stabilization of CsPbBr ₃ Perovskite Nanoparticles and Nanocomposite Films Kim, Hyunki; Hight‐Huf, Nicholas; Kang, Ji‐Hwan Angewandte Chemie International Edition, Vol. 59, Issue 27 https://doi.org/10.1002/anie.201916492	journal	April 2020
Design of Chemically Stable Organic Perovskite Quantum Dots for Micropatterned Light‐Emitting Diodes through Kinetic Control of a Cross‐Linkable Ligand System Lee, Hanleem; Jeong, Ji Won; So, Mo Geun Advanced Materials, Vol. 33, Issue 23 https://doi.org/10.1002/adma.202007855	journal	May 2021
Self‐Healing Lithographic Patterning of Perovskite Nanocrystals for Large‐Area Single‐Mode Laser Array Xing, Di; Lin, Cheng‐Chieh; Ho, Ya‐Lun Advanced Functional Materials, Vol. 31, Issue 1 https://doi.org/10.1002/adfm.202006283	journal	October 2020
Boosting the Photoluminescence of CsPbX ₃ (X = Cl, Br, I) Perovskite Nanocrystals Covering a Wide Wavelength Range by Postsynthetic Treatment with Tetrafluoroborate Salts Ahmed, Tasnim; Seth, Sudipta; Samanta, Anunay Chemistry of Materials, Vol. 30, Issue 11 https://doi.org/10.1021/acs.chemmater.8b01235	journal	May 2018
Benzoyl Halides as Alternative Precursors for the Colloidal Synthesis of Lead-Based Halide Perovskite Nanocrystals Imran, Muhammad; Caligiuri, Vincenzo; Wang, Mengjiao Journal of the American Chemical Society, Vol. 140, Issue 7 https://doi.org/10.1021/jacs.7b13477	journal	January 2018
Ligand-engineered bandgap stability in mixed-halide perovskite LEDs Hassan, Yasser; Park, Jong Hyun; Crawford, Michael L. Nature, Vol. 591, Issue 7848 https://doi.org/10.1038/s41586-021-03217-8	journal	March 2021
In Situ Patterning Perovskite Quantum Dots by Direct Laser Writing Fabrication Zhan, Wenjie; Meng, Linghai; Shao, Chendi ACS Photonics, Vol. 8, Issue 3 https://doi.org/10.1021/acsphotonics.1c00118	journal	March 2021
Efficient, fast and reabsorption-free perovskite nanocrystal-based sensitized plastic scintillators Gandini, Marina; Villa, Irene; Beretta, Mattia Nature Nanotechnology, Vol. 15, Issue 6 https://doi.org/10.1038/s41565-020-0683-8	journal	May 2020
Microfabricable ratiometric gaseous oxygen sensors based on inorganic perovskite nanocrystals and PtTFPP Wu, Shanshan; Fan, Zengju; Wang, Weichuan Sensors and Actuators B: Chemical, Vol. 271 https://doi.org/10.1016/j.snb.2018.05.074	journal	October 2018
Simultaneous Cationic and Anionic Ligand Exchange For Colloidally Stable CsPbBr ₃ Nanocrystals Imran, Muhammad; Ijaz, Palvasha; Goldoni, Luca ACS Energy Letters, Vol. 4, Issue 4 https://doi.org/10.1021/acsenergylett.9b00140	journal	March 2019
Monodisperse Long-Chain Sulfobetaine-Capped CsPbBr ₃ Nanocrystals and Their Superfluorescent Assemblies Krieg, Franziska; Sercel, Peter C.; Burian, Max ACS Central Science, Vol. 7, Issue 1 https://doi.org/10.1021/acscentsci.0c01153	journal	December 2020
Colloidal CsPbX ₃ (X = Cl, Br, I) Nanocrystals 2.0: Zwitterionic Capping Ligands for Improved Durability and Stability Krieg, Franziska; Ochsenbein, Stefan T.; Yakunin, Sergii ACS Energy Letters, Vol. 3, Issue 3 https://doi.org/10.1021/acsenergylett.8b00035	journal	February 2018
Spatially resolved multicolor CsPbX ₃ nanowire heterojunctions via anion exchange Dou, Letian; Lai, Minliang; Kley, Christopher S. Proceedings of the National Academy of Sciences, Vol. 114, Issue 28 https://doi.org/10.1073/pnas.1703860114	journal	June 2017
Elucidating the Weakly Reversible Cs–Pb–Br Perovskite Nanocrystal Reaction Network with High-Throughput Maps and Transformations Dahl, Jakob C.; Wang, Xingzhi; Huang, Xiao Journal of the American Chemical Society, Vol. 142, Issue 27 https://doi.org/10.1021/jacs.0c04997	journal	June 2020
All‐Solution Processed Multicolor Patterning Technique of Perovskite Nanocrystal for Color Pixel Array and Flexible Optoelectronic Devices Jeon, Sanghyun; Lee, Sang Yeop; Kim, Su‐Kyung Advanced Optical Materials, Vol. 8, Issue 17 https://doi.org/10.1002/adom.202000501	journal	May 2020
Direct Optical Patterning of Quantum Dot Light‐Emitting Diodes via In Situ Ligand Exchange Cho, Himchan; Pan, Jia‐Ahn; Wu, Haoqi Advanced Materials, Vol. 32, Issue 46 https://doi.org/10.1002/adma.202003805	journal	October 2020
Improving All-Inorganic Perovskite Photodetectors by Preferred Orientation and Plasmonic Effect Dong, Yuhui; Gu, Yu; Zou, Yousheng Small, Vol. 12, Issue 40 https://doi.org/10.1002/smll.201602366	journal	August 2016
All-inorganic perovskite nanocrystal scintillators Chen, Qiushui; Wu, Jing; Ou, Xiangyu Nature, Vol. 561, Issue 7721 https://doi.org/10.1038/s41586-018-0451-1	journal	August 2018
Healing All-Inorganic Perovskite Films via Recyclable Dissolution-Recyrstallization for Compact and Smooth Carrier Channels of Optoelectronic Devices with High Stability Li, Xiaoming; Yu, Dejian; Cao, Fei Advanced Functional Materials, Vol. 26, Issue 32 https://doi.org/10.1002/adfm.201601571	journal	June 2016
Quantum dot-induced phase stabilization of -CsPbI3 perovskite for high-efficiency photovoltaics Swarnkar, A.; Marshall, A. R.; Sanehira, E. M. Science, Vol. 354, Issue 6308 https://doi.org/10.1126/science.aag2700	journal	October 2016
Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite Nanocrystals De Roo, Jonathan; Ibáñez, Maria; Geiregat, Pieter ACS Nano, Vol. 10, Issue 2 https://doi.org/10.1021/acsnano.5b06295	journal	January 2016
X-ray Lithography on Perovskite Nanocrystals Films: From Patterning with Anion-Exchange Reactions to Enhanced Stability in Air and Water Palazon, Francisco; Akkerman, Quinten A.; Prato, Mirko ACS Nano, Vol. 10, Issue 1 https://doi.org/10.1021/acsnano.5b06536	journal	December 2015
Perovskite Nanoparticle Composite Films by Size Exclusion Lithography Minh, Duong Nguyen; Eom, Sangwon; Nguyen, Lan Anh Thi Advanced Materials, Vol. 30, Issue 39 https://doi.org/10.1002/adma.201802555	journal	July 2018
The Infrared Spectra of Alpha and beta Oximes Palm, Ann; Werbin, Harold Canadian Journal of Chemistry, Vol. 31, Issue 11 https://doi.org/10.1139/v53-132	journal	November 1953
Direct Optical Lithography of Colloidal Metal Oxide Nanomaterials for Diffractive Optical Elements with 2π Phase Control Pan, Jia-Ahn; Rong, Zichao; Wang, Yuanyuan Journal of the American Chemical Society, Vol. 143, Issue 5 https://doi.org/10.1021/jacs.0c12447	journal	January 2021
Large-Area Lasing and Multicolor Perovskite Quantum Dot Patterns Lin, Chun Hao; Zeng, Qingji; Lafalce, Evan Advanced Optical Materials, Vol. 6, Issue 16 https://doi.org/10.1002/adom.201800474	journal	May 2018
All-inorganic cesium lead halide perovskite nanocrystals for photodetector applications Ramasamy, Parthiban; Lim, Da-Hye; Kim, Bumjin Chemical Communications, Vol. 52, Issue 10 https://doi.org/10.1039/C5CC08643D	journal	January 2016
Direct optical lithography of functional inorganic nanomaterials Wang, Yuanyuan; Fedin, Igor; Zhang, Hao Science, Vol. 357, Issue 6349 https://doi.org/10.1126/science.aan2958	journal	July 2017
Fluorescent Microarrays of in Situ Crystallized Perovskite Nanocomposites Fabricated for Patterned Applications by Using Inkjet Printing Liu, Yang; Li, Fushan; Qiu, Lichun ACS Nano https://doi.org/10.1021/acsnano.8b08582	journal	February 2019
Multiplexed patterning of cesium lead halide perovskite nanocrystals by additive jet printing for efficient white light generation Altintas, Yemliha; Torun, Ilker; Yazici, Ahmet Faruk Chemical Engineering Journal, Vol. 380 https://doi.org/10.1016/j.cej.2019.122493	journal	January 2020
Chlorine Vacancy Passivation in Mixed Halide Perovskite Quantum Dots by Organic Pseudohalides Enables Efficient Rec. 2020 Blue Light-Emitting Diodes Zheng, Xiaopeng; Yuan, Shuai; Liu, Jiakai ACS Energy Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acsenergylett.0c00057	journal	February 2020
Properties and potential optoelectronic applications of lead halide perovskite nanocrystals Kovalenko, Maksym V.; Protesescu, Loredana; Bodnarchuk, Maryna I. Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam7093	journal	November 2017
Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals Akkerman, Quinten A.; Rainò, Gabriele; Kovalenko, Maksym V. Nature Materials, Vol. 17, Issue 5 https://doi.org/10.1038/s41563-018-0018-4	journal	February 2018
Direct Photolithographic Patterning of Colloidal Quantum Dots Enabled by UV-Crosslinkable and Hole-Transporting Polymer Ligands Ko, Jaewan; Chang, Jun Hyuk; Jeong, Byeong Guk ACS Applied Materials & Interfaces, Vol. 12, Issue 37 https://doi.org/10.1021/acsami.0c11988	journal	August 2020
Beitr�ge zur Kenntnis der Stickstoff?Sauerstoff-Bindung. I. N?O-Bindungen ohne Mesomerie Goubeau, J.; Fromme, Inge Zeitschrift f�r anorganische Chemie, Vol. 258, Issue 1-2 https://doi.org/10.1002/zaac.19492580104	journal	February 1949
Tuning the Optical Properties of Cesium Lead Halide Perovskite Nanocrystals by Anion Exchange Reactions Akkerman, Quinten A.; D’Innocenzo, Valerio; Accornero, Sara Journal of the American Chemical Society, Vol. 137, Issue 32 https://doi.org/10.1021/jacs.5b05602	journal	August 2015
Reversible 3D laser printing of perovskite quantum dots inside a transparent medium Huang, Xiongjian; Guo, Qianyi; Yang, Dandan Nature Photonics, Vol. 14, Issue 2 https://doi.org/10.1038/s41566-019-0538-8	journal	November 2019
Simultaneous enhancement of luminescence and stability of CsPbBr3 perovskite nanocrystals via formation of perhydropolysilazane-derived nanopatterned film Park, Shulgi; Cho, Junhee; Jeong, Dawoon Chemical Engineering Journal, Vol. 393 https://doi.org/10.1016/j.cej.2020.124767	journal	August 2020
Fast Anion-Exchange in Highly Luminescent Nanocrystals of Cesium Lead Halide Perovskites (CsPbX ₃ , X = Cl, Br, I) Nedelcu, Georgian; Protesescu, Loredana; Yakunin, Sergii Nano Letters, Vol. 15, Issue 8 https://doi.org/10.1021/acs.nanolett.5b02404	journal	July 2015
Metal Halide Perovskite Nanocrystal Solar Cells: Progress and Challenges Liu, Chongming; Zeng, Qingsen; Wei, Haotong Small Methods, Vol. 4, Issue 10 https://doi.org/10.1002/smtd.202000419	journal	September 2020
All-Inorganic Colloidal Perovskite Quantum Dots: A New Class of Lasing Materials with Favorable Characteristics Wang, Yue; Li, Xiaoming; Song, Jizhong Advanced Materials, Vol. 27, Issue 44 https://doi.org/10.1002/adma.201503573	journal	October 2015
Low-threshold amplified spontaneous emission and lasing from colloidal nanocrystals of caesium lead halide perovskites Yakunin, Sergii; Protesescu, Loredana; Krieg, Franziska Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9056	journal	August 2015
Multilayer Diffraction Reveals That Colloidal Superlattices Approach the Structural Perfection of Single Crystals Toso, Stefano; Baranov, Dmitry; Altamura, Davide ACS Nano, Vol. 15, Issue 4 https://doi.org/10.1021/acsnano.0c08929	journal	January 2021
Coherent single-photon emission from colloidal lead halide perovskite quantum dots Utzat, Hendrik; Sun, Weiwei; Kaplan, Alexander E. K. Science, Vol. 363, Issue 6431 https://doi.org/10.1126/science.aau7392	journal	February 2019
Comprehensive defect suppression in perovskite nanocrystals for high-efficiency light-emitting diodes Kim, Young-Hoon; Kim, Sungjin; Kakekhani, Arvin Nature Photonics, Vol. 15, Issue 2 https://doi.org/10.1038/s41566-020-00732-4	journal	January 2021
CsPbBr ₃ Quantum Dots 2.0: Benzenesulfonic Acid Equivalent Ligand Awakens Complete Purification Yang, Dandan; Li, Xiaoming; Zhou, Wenhan Advanced Materials https://doi.org/10.1002/adma.201900767	journal	June 2019
Direct Wavelength-Selective Optical and Electron-Beam Lithography of Functional Inorganic Nanomaterials Wang, Yuanyuan; Pan, Jia-Ahn; Wu, Haoqi ACS Nano, Vol. 13, Issue 12 https://doi.org/10.1021/acsnano.9b05491	journal	October 2019
Near-Unity Photoluminescence Quantum Yield in CsPbBr ₃ Nanocrystal Solid-State Films via Postsynthesis Treatment with Lead Bromide Di Stasio, Francesco; Christodoulou, Sotirios; Huo, Nengjie Chemistry of Materials, Vol. 29, Issue 18 https://doi.org/10.1021/acs.chemmater.7b02834	journal	September 2017
Alternative low-cost approach to the synthesis of magnetic iron oxide nanoparticles by thermal decomposition of organic precursors Perez De Berti, I. O.; Cagnoli, M. V.; Pecchi, G. Nanotechnology, Vol. 24, Issue 17 https://doi.org/10.1088/0957-4484/24/17/175601	journal	April 2013
Ligand-Assisted Direct Photolithography of Perovskite Nanocrystals Encapsulated with Multifunctional Polymer Ligands for Stable, Full-Colored, High-Resolution Displays Ko, Jaewan; Ma, Kyungyeon; Joung, Joonyoung F. Nano Letters, Vol. 21, Issue 5 https://doi.org/10.1021/acs.nanolett.1c00134	journal	March 2021
Metal Halide Perovskite Nanocrystals: Synthesis, Post-Synthesis Modifications, and Their Optical Properties Shamsi, Javad; Urban, Alexander S.; Imran, Muhammad Chemical Reviews, Vol. 119, Issue 5 https://doi.org/10.1021/acs.chemrev.8b00644	journal	February 2019
Design Principles for Trap-Free CsPbX ₃ Nanocrystals: Enumerating and Eliminating Surface Halide Vacancies with Softer Lewis Bases Nenon, David P.; Pressler, Kimo; Kang, Jun Journal of the American Chemical Society, Vol. 140, Issue 50 https://doi.org/10.1021/jacs.8b11035	journal	November 2018
Nanocrystals of Cesium Lead Halide Perovskites (CsPbX ₃ , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I. Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/nl5048779	journal	February 2015
Superfluorescence from lead halide perovskite quantum dot superlattices Rainò, Gabriele; Becker, Michael A.; Bodnarchuk, Maryna I. Nature, Vol. 563, Issue 7733 https://doi.org/10.1038/s41586-018-0683-0	journal	November 2018

Similar Records

Direct Optical Lithography of Colloidal Metal Oxide Nanomaterials for Diffractive Optical Elements with 2π Phase Control

Journal Article · Thu Jan 28 00:00:00 EST 2021 · Journal of the American Chemical Society · OSTI ID:1831420

Pan, Jia-Ahn; Rong, Zichao; Wang, Yuanyuan; +4 more

Direct Wavelength-Selective Optical and Electron-Beam Lithography of Functional Inorganic Nanomaterials

Journal Article · Mon Oct 14 00:00:00 EDT 2019 · ACS Nano · OSTI ID:1831420

Wang, Yuanyuan; Pan, Jia-Ahn; Wu, Haoqi; +1 more

Synthesis of Zwitterionic CsPbBr ₃ Nanocrystals with Controlled Anisotropy using Surface‐Selective Ligand Pairs

Journal Article · Sun Jul 30 00:00:00 EDT 2023 · Advanced Materials · OSTI ID:1831420

Zhu, Hua; Kick, Matthias; Ginterseder, Matthias; +7 more

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY
Direct optical lithography
perovskite nanocrystal
photosensitive ligand
anion exchange
ligand exchange

Title: Direct Optical Lithography of CsPbX3 Nanocrystals via Photoinduced Ligand Cleavage with Postpatterning Chemical Modification and Electronic Coupling

Citation Formats

References (56)

Similar Records

Related Subjects

Title: Direct Optical Lithography of CsPbX₃ Nanocrystals via Photoinduced Ligand Cleavage with Postpatterning Chemical Modification and Electronic Coupling