Chemical Vapor Transport Route toward Black Phosphorus Nanobelts and Nanoribbons

Macewicz, Lukasz; Pyrchla, Krzysztof; Bogdanowicz, Robert; Sumanasekera, Gamini; Jasinski, Jacek B.

doi:10.1021/acs.jpclett.1c02064

Title: Chemical Vapor Transport Route toward Black Phosphorus Nanobelts and Nanoribbons

Journal Article · Wed Aug 25 00:00:00 EDT 2021 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.1c02064· OSTI ID:1831409

Macewicz, Lukasz ^[1]; Pyrchla, Krzysztof ^[2];

^[2]; Sumanasekera, Gamini ^[3];

^[3]

Gdańsk University of Technology, Gdańsk (Poland); Univ. of Louisville, KY (United States)
Gdańsk University of Technology, Gdańsk (Poland)
Univ. of Louisville, KY (United States)

Chemical vapor transport (CVT) method is widely used for bulk black phosphorus (BP) fabrication. In this work, we demonstrate that CVT provides a route for the fabrication of BP nanoribbons and nanobelts. This method consists of a two-step procedure, including initial BP column growth using the CVT technique, followed by ultrasonic treatment and centrifugation. The obtained nanostructures preserve BP column dimensions, forming ultralong ribbon-like structures with the length to the width aspect ratio of up to 500. Computational modeling of the growth mechanism of a BP flake is also presented in support of the observed columnar growth. Calculation of the average energy of the molecule in the asymmetric flakes shows that the growth of the structure in the zigzag direction is more energetically favorable than in the armchair direction.

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Research Organization:: University of Louisville, Louisville, KY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Poland National Science Centre; European Social Fund

Grant/Contract Number:: SC0019348

OSTI ID:: 1831409

Journal Information:: Journal of Physical Chemistry Letters, Vol. 12, Issue 34; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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