Electrical and structural properties of VO2 in an electric field

Hwang, In-Hui; Jin, Zhenlan; Park, Chang-In; Sun, Cheng-Jun; Brewe, Dale L.; Han, Sang-Wook

doi:10.1016/j.cap.2021.05.010

Electrical and structural properties of VO₂ in an electric field

Journal Article · Thu Jun 10 00:00:00 EDT 2021 · Current Applied Physics

DOI:https://doi.org/10.1016/j.cap.2021.05.010· OSTI ID:1831185

Hwang, In-Hui ^[1]; Jin, Zhenlan ^[2]; Park, Chang-In ^[2]; Sun, Cheng-Jun ^[3]; Brewe, Dale L. ^[3]; ^[2]

Jeonbuk National Univ., Jeonju (South Korea); Argonne National Lab. (ANL), Argonne, IL (United States)
Jeonbuk National Univ., Jeonju (South Korea)
Argonne National Lab. (ANL), Argonne, IL (United States)

We examined the electrical and local structural properties of a VO₂ film at different electric fields using electrical resistance and x-ray absorption fine structure (XAFS) measurements at the V K edge in the temperature range of 30–100 °C. The T_c value of the metal-to-insulator transition (MIT) during both heating and cooling decreases with electric field. When the electric field exceeds a certain value, the MIT becomes sharper due to Joule heating. Furthermore, the MIT, the structural phase transition (SPT), and the pre-edge peak transition of the VO₂ do not congruently occur at a uniform temperature. A metallic VO₂ is observed in only the rutile (or M2) symmetry. An electric field induces a substantial amount of conduction electrons in insulating VO₂. Simultaneously measured resistance and XAFS reveal that Joule heating caused by an external electric field significantly affects the MIT and SPT of VO₂.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1831185

Journal Information:: Current Applied Physics, Journal Name: Current Applied Physics Vol. 30; ISSN 1567-1739

Publisher:: Korean Physical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Electrical and structural properties of VO2 in an electric field

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