Extended catalyst lifetime testing for HTL biocrude hydrotreating to produce fuel blendstocks from wet wastes

Subramaniam, Senthil; Santosa, Daniel M.; Brady, Casper O.; Swita, Marie S.; Kallupalayam Ramasamy, Karthikeyan; Thorson, Michael R.

doi:10.1021/acssuschemeng.1c02743

Extended catalyst lifetime testing for HTL biocrude hydrotreating to produce fuel blendstocks from wet wastes

Journal Article · Mon Sep 27 04:00:00 EDT 2021 · ACS Sustainable Chemistry & Engineering

DOI:https://doi.org/10.1021/acssuschemeng.1c02743· OSTI ID:1829675

Subramaniam, Senthil ^[1]; Santosa, Daniel M. ^[1]; Brady, Casper O. ^[1]; Swita, Marie S. ^[1]; Kallupalayam Ramasamy, Karthikeyan ^[1]; Thorson, Michael R. ^[1]

BATTELLE (PACIFIC NW LAB)

This paper presents the upgrading of HTL (Hydrothermal Liquefaction) bio oil produced by from various sources such as sewage sludge and food wastes. The HTL oil was hydrotreated over a CoMo/Al2O3 (guardbed) and NiMo/Al2O3 (mainbed) catalysts at WHSV 0.5hr-1, 400°C and 1500 psi. The steady state densities (at 40°C) were 0.79 and 0.81 g/ml for HTL biocrude derived from sewage sludge and food waste, respectively. After 1500 hours of steady state operation, variations in process conditions that affect the hydrotreating performance had been identified in the following order; Pressure>WHSV>Temperature. Pressure had huge impact on the hydrotreating performance. The hydrotreating efficiency was reestablished to base line conditions with minimal deactivation of catalyst at 2000 hours run time.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1829675

Report Number(s):: PNNL-SA-161175

Journal Information:: ACS Sustainable Chemistry & Engineering, Journal Name: ACS Sustainable Chemistry & Engineering Journal Issue: 38 Vol. 9

Country of Publication:: United States

Language:: English

References (33)

Bio-oil Stabilization by Hydrogenation over Reduced Metal Catalysts at Low Temperatures Wang, Huamin; Lee, Suh-Jane; Olarte, Mariefel V. ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 10 https://doi.org/10.1021/acssuschemeng.6b01270	journal	August 2016
Catalytic upgrading of hydrothermal liquefaction biocrudes: Different challenges for different feedstocks Castello, Daniele; Haider, Muhammad Salman; Rosendahl, Lasse Aistrup Renewable Energy, Vol. 141 https://doi.org/10.1016/j.renene.2019.04.003	journal	October 2019
Thermochemical production of bio-oil: A review of downstream processing technologies for bio-oil upgrading, production of hydrogen and high value-added products Kumar, R.; Strezov, V. Renewable and Sustainable Energy Reviews, Vol. 135 https://doi.org/10.1016/j.rser.2020.110152	journal	January 2021
Chemical properties of biocrude oil from the hydrothermal liquefaction of Spirulina algae, swine manure, and digested anaerobic sludge Vardon, Derek R.; Sharma, B. K.; Scott, John Bioresource Technology, Vol. 102, Issue 17 https://doi.org/10.1016/j.biortech.2011.06.041	journal	September 2011
Technology advancements in hydroprocessing of bio-oils Zacher, Alan H.; Elliott, Douglas C.; Olarte, Mariefel V. Biomass and Bioenergy, Vol. 125 https://doi.org/10.1016/j.biombioe.2019.04.015	journal	June 2019
Peer Reviewed: Pathogen Risks From Applying Sewage Sludge to Land Lewis, David L.; Gattie, David K. Environmental Science & Technology, Vol. 36, Issue 13 https://doi.org/10.1021/es0223426	journal	July 2002
Hydrothermal Liquefaction Biocrude Compositions Compared to Petroleum Crude and Shale Oil Jarvis, Jacqueline M.; Billing, Justin M.; Hallen, Richard T. Energy & Fuels, Vol. 31, Issue 3 https://doi.org/10.1021/acs.energyfuels.6b03022	journal	February 2017
Stabilization of Softwood-Derived Pyrolysis Oils for Continuous Bio-oil Hydroprocessing Olarte, Mariefel V.; Zacher, Alan H.; Padmaperuma, Asanga B. Topics in Catalysis, Vol. 59, Issue 1 https://doi.org/10.1007/s11244-015-0505-7	journal	October 2015
Hydroprocessing of bio-crude from continuous hydrothermal liquefaction of microalgae Biller, Patrick; Sharma, Brajendra K.; Kunwar, Bidhya Fuel, Vol. 159 https://doi.org/10.1016/j.fuel.2015.06.077	journal	November 2015
Wet Waste Hydrothermal Liquefaction and Biocrude Upgrading to Hydrocarbon Fuels: 2019 State of Technology Snowden-Swan, Lesley J.; Billing, Justin M.; Thorson, Michael R. https://doi.org/10.2172/1617028 PNNL-29882	report	April 2020
Hydrotreatment of biocrudes derived from hydrothermal liquefaction and lipid extraction of the high-lipid Scenedesmus Tang, Shun; Shi, Ze; Tang, Xiaohan Green Chemistry, Vol. 21, Issue 12 https://doi.org/10.1039/C9GC00673G	journal	January 2019
The Art of Smooth Continuous Hydroprocessing of Biocrudes Obtained from Hydrothermal Liquefaction: Hydrodemetallization and Propensity for Coke Formation Haider, Muhammad Salman; Castello, Daniele; Rosendahl, Lasse Aistrup Energy & Fuels, Vol. 35, Issue 13 https://doi.org/10.1021/acs.energyfuels.1c01228	journal	June 2021
Catalytic Hydrotreatment of Microalgae Biocrude from Continuous Hydrothermal Liquefaction: Heteroatom Removal and Their Distribution in Distillation Cuts Haider, Muhammad; Castello, Daniele; Michalski, Karol Energies, Vol. 11, Issue 12 https://doi.org/10.3390/en11123360	journal	December 2018
Process development for hydrothermal liquefaction of algae feedstocks in a continuous-flow reactor Elliott, Douglas C.; Hart, Todd R.; Schmidt, Andrew J. Algal Research, Vol. 2, Issue 4, p. 445-454 https://doi.org/10.1016/j.algal.2013.08.005	journal	October 2013
Impact of iron porphyrin complexes when hydroprocessing algal HTL biocrude Jarvis, Jacqueline M.; Sudasinghe, Nilusha M.; Albrecht, Karl O. Fuel, Vol. 182 https://doi.org/10.1016/j.fuel.2016.05.107	journal	October 2016
Catalytic hydrotreatment of bio-crude produced from the hydrothermal liquefaction of aspen wood: a catalyst screening and parameter optimization study Yu, Jinlong; Biller, Patrick; Mamahkel, Aref Sustainable Energy & Fuels, Vol. 1, Issue 4 https://doi.org/10.1039/C7SE00090A	journal	January 2017
Toxic metals in sewage sludge-amended soils: has promotion of beneficial use discounted the risks? McBride, M. B. Advances in Environmental Research, Vol. 8, Issue 1 https://doi.org/10.1016/S1093-0191(02)00141-7	journal	October 2003
FT-ICR MS analysis of blended pine-microalgae feedstock HTL biocrudes Jarvis, Jacqueline M.; Billing, Justin M.; Corilo, Yuri E. Fuel, Vol. 216 https://doi.org/10.1016/j.fuel.2017.12.016	journal	March 2018
Historical Developments in Hydroprocessing Bio-oils Elliott, Douglas C. Energy & Fuels, Vol. 21, Issue 3, p. 1792-1815 https://doi.org/10.1021/ef070044u	journal	May 2007
Synthetic fibers as an indicator of land application of sludge Zubris, Kimberly Ann V.; Richards, Brian K. Environmental Pollution, Vol. 138, Issue 2 https://doi.org/10.1016/j.envpol.2005.04.013	journal	November 2005
Hydrothermal liquefaction of biomass: A review of subcritical water technologies Toor, Saqib Sohail; Rosendahl, Lasse; Rudolf, Andreas Energy, Vol. 36, Issue 5, p. 2328-2342 https://doi.org/10.1016/j.energy.2011.03.013	journal	May 2011
Assessment of Hydrotreatment for Hydrothermal Liquefaction Biocrudes from Sewage Sludge, Microalgae, and Pine Feedstocks Jarvis, Jacqueline M.; Albrecht, Karl O.; Billing, Justin M. Energy & Fuels, Vol. 32, Issue 8 https://doi.org/10.1021/acs.energyfuels.8b01445	journal	June 2018
Conversion of a wet waste feedstock to biocrude by hydrothermal processing in a continuous-flow reactor: grape pomace Elliott, Douglas C.; Schmidt, Andrew J.; Hart, Todd R. Biomass Conversion and Biorefinery, Vol. 7, Issue 4 https://doi.org/10.1007/s13399-017-0264-8	journal	May 2017
Recent Advances in Hydrotreating of Pyrolysis Bio-Oil and Its Oxygen-Containing Model Compounds Wang, Huamin; Male, Jonathan; Wang, Yong ACS Catalysis, Vol. 3, Issue 5 https://doi.org/10.1021/cs400069z	journal	April 2013
Prediction of microalgae hydrothermal liquefaction products from feedstock biochemical composition Leow, Shijie; Witter, John R.; Vardon, Derek R. Green Chemistry, Vol. 17, Issue 6 https://doi.org/10.1039/C5GC00574D	journal	January 2015
Hydrothermal liquefaction of biomass: Developments from batch to continuous process Elliott, Douglas C.; Biller, Patrick; Ross, Andrew B. Bioresource Technology, Vol. 178, p. 147-156 https://doi.org/10.1016/j.biortech.2014.09.132	journal	February 2015
Effects of Environmental Factors and Nutrient Availability on the Biochemical Composition of Algae for Biofuels Production: A Review Juneja, Ankita; Ceballos, Ruben; Murthy, Ganti Energies, Vol. 6, Issue 9 https://doi.org/10.3390/en6094607	journal	September 2013
Impact of heterotrophically stressed algae for biofuel production via hydrothermal liquefaction and catalytic hydrotreating in continuous-flow reactors Albrecht, Karl O.; Zhu, Yunhua; Schmidt, Andrew J. Algal Research, Vol. 14 https://doi.org/10.1016/j.algal.2015.12.008	journal	March 2016
Continuous Hydrothermal Liquefaction of Biomass: A Critical Review Castello, Daniele; Pedersen, Thomas; Rosendahl, Lasse Energies, Vol. 11, Issue 11 https://doi.org/10.3390/en11113165	journal	November 2018
Analysis and comparison of bio-oils obtained by hydrothermal liquefaction and fast pyrolysis of beech wood Haarlemmer, Geert; Guizani, Chamseddine; Anouti, Suzanne Fuel, Vol. 174 https://doi.org/10.1016/j.fuel.2016.01.082	journal	June 2016
Contribution of primary and secondary treatment on the removal of benzothiazoles, benzotriazoles, endocrine disruptors, pharmaceuticals and perfluorinated compounds in a sewage treatment plant Stasinakis, Athanasios S.; Thomaidis, Nikolaos S.; Arvaniti, Olga S. Science of The Total Environment, Vol. 463-464 https://doi.org/10.1016/j.scitotenv.2013.06.087	journal	October 2013
Heterogeneous catalytic upgrading of biocrude oil produced by hydrothermal liquefaction of microalgae: State of the art and own experiments López Barreiro, Diego; Gómez, Blanca Ríos; Ronsse, Frederik Fuel Processing Technology, Vol. 148 https://doi.org/10.1016/j.fuproc.2016.02.034	journal	July 2016
A review on the upgradation techniques of pyrolysis oil Gollakota, Anjani R. K.; Reddy, Madhurima; Subramanyam, Malladi D. Renewable and Sustainable Energy Reviews, Vol. 58 https://doi.org/10.1016/j.rser.2015.12.180	journal	May 2016

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