Influence of Reduced Na Vacancy Concentrations in the Sodium Superionic Conductors Na11+xSn2P1–xMxS12 (M = Sn, Ge)

Kraft, Marvin A.; Gronych, Lara M.; Famprikis, Theodosios; Zeier, Wolfgang G.

doi:10.1021/acsaem.1c01367

Title: Influence of Reduced Na Vacancy Concentrations in the Sodium Superionic Conductors Na_11+xSn₂P_1–xM_xS₁₂ (M = Sn, Ge)

Journal Article · Thu Jul 01 00:00:00 EDT 2021 · ACS Applied Energy Materials

DOI:https://doi.org/10.1021/acsaem.1c01367· OSTI ID:1828964

Kraft, Marvin A.; Gronych, Lara M.; Famprikis, Theodosios; Zeier, Wolfgang G.

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: DOE - Office Of Science; FOREIGN

OSTI ID:: 1828964

Journal Information:: ACS Applied Energy Materials, Vol. 4, Issue 7; ISSN 2574-0962

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: ENGLISH

References (48)

Materials design of ionic conductors for solid state batteries Ohno, Saneyuki; Banik, Ananya; Dewald, Georg F. Progress in Energy, Vol. 2, Issue 2 https://doi.org/10.1088/2516-1083/ab73dd	journal	March 2020
Planting Repulsion Centers for Faster Ionic Diffusion in Superionic Conductors Oh, Kyungbae; Kang, Kisuk Angewandte Chemie International Edition, Vol. 59, Issue 42 https://doi.org/10.1002/anie.202007447	journal	August 2020
High-Throughput Screening of Solid-State Li-Ion Conductors Using Lattice-Dynamics Descriptors Muy, Sokseiha; Voss, Johannes; Schlem, Roman iScience, Vol. 16 https://doi.org/10.1016/j.isci.2019.05.036	journal	June 2019
A highly stable sodium solid-state electrolyte based on a dodeca/deca-borate equimolar mixture Duchêne, L.; Kühnel, R. -S.; Rentsch, D. Chemical Communications, Vol. 53, Issue 30 https://doi.org/10.1039/c7cc00794a	journal	January 2017
Local Charge Inhomogeneity and Lithium Distribution in the Superionic Argyrodites Li ₆ PS ₅ X (X = Cl, Br, I) Minafra, Nicolò; Kraft, Marvin A.; Bernges, Tim Inorganic Chemistry, Vol. 59, Issue 15 https://doi.org/10.1021/acs.inorgchem.0c01504	journal	July 2020
Synthesis, structure determination, and ionic conductivity of sodium tetrathiophosphate Jansen, M.; Henseler, U. Journal of Solid State Chemistry, Vol. 99, Issue 1 https://doi.org/10.1016/0022-4596(92)90295-7	journal	July 1992
Boosting Solid-State Diffusivity and Conductivity in Lithium Superionic Argyrodites by Halide Substitution Adeli, Parvin; Bazak, J. David; Park, Kern Ho Angewandte Chemie International Edition, Vol. 58, Issue 26 https://doi.org/10.1002/anie.201814222	journal	May 2019
Na3.8[Sn0.67Si0.33]0.8Sb0.2S4: A quinary sodium fast ionic conductor for all-solid-state sodium battery Jia, Huanhuan; Peng, Linfeng; Zhang, Zhuoran Journal of Energy Chemistry, Vol. 48 https://doi.org/10.1016/j.jechem.2019.12.021	journal	September 2020
Structure and Sodium Ion Transport in Na _{11+ x} Sn _{2+ x} (Sb _{1– y} P _y ) _{1– x} S ₁₂ Kraft, Marvin A.; Gronych, Lara M.; Famprikis, Theodosios Chemistry of Materials, Vol. 32, Issue 15 https://doi.org/10.1021/acs.chemmater.0c01964	journal	July 2020
VESTA : a three-dimensional visualization system for electronic and structural analysis Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 41, Issue 3 https://doi.org/10.1107/s0021889808012016	journal	May 2008
Benchmarking the performance of all-solid-state lithium batteries Randau, Simon; Weber, Dominik A.; Kötz, Olaf Nature Energy, Vol. 5, Issue 3 https://doi.org/10.1038/s41560-020-0565-1	journal	March 2020
Survey of the transport properties of sodium superionic conductor materials for use in sodium batteries Guin, M.; Tietz, F. Journal of Power Sources, Vol. 273 https://doi.org/10.1016/j.jpowsour.2014.09.137	journal	January 2015
A solid future for battery development Janek, Jürgen; Zeier, Wolfgang G. Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.141	journal	September 2016
Superion Conductor Na _11.1 Sn _2.1 P _0.9 Se ₁₂ : Lowering the Activation Barrier of Na ⁺ Conduction in Quaternary 1–4–5–6 Electrolytes Duchardt, Marc; Neuberger, Sven; Ruschewitz, Uwe Chemistry of Materials, Vol. 30, Issue 12 https://doi.org/10.1021/acs.chemmater.8b01656	journal	May 2018
First-Principles Investigations on Sodium Superionic Conductor Na ₁₁ Sn ₂ PS ₁₂ Oh, Kyungbae; Chang, Donghee; Park, Inchul Chemistry of Materials, Vol. 31, Issue 16 https://doi.org/10.1021/acs.chemmater.8b04965	journal	June 2019
Design and synthesis of the superionic conductor Na10SnP2S12 Richards, William D.; Tsujimura, Tomoyuki; Miara, Lincoln J. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11009	journal	March 2016
SoftBV – a software tool for screening the materials genome of inorganic fast ion conductors Chen, Haomin; Wong, Lee Loong; Adams, Stefan Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 75, Issue 1 https://doi.org/10.1107/s2052520618015718	journal	January 2019
Tuning mobility and stability of lithium ion conductors based on lattice dynamics Muy, Sokseiha; Bachman, John C.; Giordano, Livia Energy & Environmental Science, Vol. 11, Issue 4 https://doi.org/10.1039/c7ee03364h	journal	January 2018
Room-Temperature All-solid-state Rechargeable Sodium-ion Batteries with a Cl-doped Na3PS4 Superionic Conductor Chu, Iek-Heng; Kompella, Christopher S.; Nguyen, Han Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep33733	journal	September 2016
Na ₁₁ Sn ₂ PS ₁₂ : a new solid state sodium superionic conductor Zhang, Z.; Ramos, E.; Lalère, F. Energy & Environmental Science, Vol. 11, Issue 1 https://doi.org/10.1039/c7ee03083e	journal	January 2018
Rethinking the Design of Ionic Conductors Using Meyer–Neldel–Conductivity Plot Gao, Yirong; Li, Nana; Wu, Yifan Advanced Energy Materials, Vol. 11, Issue 13 https://doi.org/10.1002/aenm.202100325	journal	February 2021
Vacancy-Controlled Na ⁺ Superion Conduction in Na ₁₁ Sn ₂ PS ₁₂ Duchardt, Marc; Ruschewitz, Uwe; Adams, Stefan Angewandte Chemie International Edition, Vol. 57, Issue 5 https://doi.org/10.1002/anie.201712769	journal	January 2018
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
Structure du tetrathiophosphate de lithium Mercier, R.; Malugani, J. -P.; Fahys, B. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 38, Issue 7 https://doi.org/10.1107/s0567740882007535	journal	July 1982
Synthesis and understanding of Na11Sn2PSe12 with enhanced ionic conductivity for all-solid-state Na-ion battery Yu, Zhaoxin; Shang, Shun-Li; Wang, Daiwei Energy Storage Materials, Vol. 17 https://doi.org/10.1016/j.ensm.2018.11.027	journal	February 2019
How Certain Are the Reported Ionic Conductivities of Thiophosphate-Based Solid Electrolytes? An Interlaboratory Study Ohno, Saneyuki; Bernges, Tim; Buchheim, Johannes ACS Energy Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acsenergylett.9b02764	journal	February 2020
A stable cathode-solid electrolyte composite for high-voltage, long-cycle-life solid-state sodium-ion batteries Wu, Erik A.; Banerjee, Swastika; Tang, Hanmei Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-21488-7	journal	February 2021
Coupled Cation–Anion Dynamics Enhances Cation Mobility in Room-Temperature Superionic Solid-State Electrolytes Zhang, Zhizhen; Roy, Pierre-Nicholas; Li, Hui Journal of the American Chemical Society, Vol. 141, Issue 49 https://doi.org/10.1021/jacs.9b09343	journal	November 2019
Anion Reorientations in the Superionic Conducting Phase of Na ₂ B ₁₂ H ₁₂ Verdal, Nina; Udovic, Terrence J.; Stavila, Vitalie The Journal of Physical Chemistry C, Vol. 118, Issue 31 https://doi.org/10.1021/jp506252c	journal	July 2014
Structural and transport properties of lithium-conducting NASICON materials Rossbach, Andreas; Tietz, Frank; Grieshammer, Steffen Journal of Power Sources, Vol. 391 https://doi.org/10.1016/j.jpowsour.2018.04.059	journal	July 2018
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/s0567739476001551	journal	September 1976
Experimental Assessment of the Practical Oxidative Stability of Lithium Thiophosphate Solid Electrolytes Dewald, Georg F.; Ohno, Saneyuki; Kraft, Marvin A. Chemistry of Materials, Vol. 31, Issue 20 https://doi.org/10.1021/acs.chemmater.9b01550	journal	September 2019
Origin of fast ion diffusion in super-ionic conductors He, Xingfeng; Zhu, Yizhou; Mo, Yifei Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15893	journal	June 2017
Die Kristallstruktur von Lithiumphosphat, Li ₃ PO ₄ Zemann, J. Acta Crystallographica, Vol. 13, Issue 11 https://doi.org/10.1107/s0365110x60002132	journal	November 1960
Electroceramics: Characterization by Impedance Spectroscopy Irvine, John T. S.; Sinclair, Derek C.; West, Anthony R. Advanced Materials, Vol. 2, Issue 3 https://doi.org/10.1002/adma.19900020304	journal	March 1990
Positron annihilation studies on nasicon analogues containing cation vacancies Sreeramalu, V.; Sreepad, H. R.; Chandrashekara, A. Bulletin of Materials Science, Vol. 13, Issue 3 https://doi.org/10.1007/bf02744948	journal	June 1990
New Na-Ion Solid Electrolytes Na ₄₋ _x Sn ₁₋ _x Sb _x S ₄ (0.02 ≤ x ≤ 0.33) for All-Solid-State Na-Ion Batteries Heo, Jongwook W.; Banerjee, Abhik; Park, Kern Ho Advanced Energy Materials, Vol. 8, Issue 11 https://doi.org/10.1002/aenm.201702716	journal	January 2018
Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries Hayashi, Akitoshi; Noi, Kousuke; Sakuda, Atsushi Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1843	journal	January 2012
The analysis of electrode impedances complicated by the presence of a constant phase element Brug, G. J.; van den Eeden, A. L. G.; Sluyters-Rehbach, M. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 176, Issue 1-2 https://doi.org/10.1016/s0022-0728(84)80324-1	journal	September 1984
Halide-Stabilized LiBH ₄ , a Room-Temperature Lithium Fast-Ion Conductor Maekawa, Hideki; Matsuo, Motoaki; Takamura, Hitoshi Journal of the American Chemical Society, Vol. 131, Issue 3 https://doi.org/10.1021/ja807392k	journal	January 2009
Na _{3– x} Er _{1– x} Zr _x Cl ₆ —A Halide-Based Fast Sodium-Ion Conductor with Vacancy-Driven Ionic Transport Schlem, Roman; Banik, Ananya; Eckardt, Mirco ACS Applied Energy Materials, Vol. 3, Issue 10 https://doi.org/10.1021/acsaem.0c01870	journal	September 2020
Neue schnelle Ionenleiter vom Typ MI3MIIICl6 (MI = Li, Na, Ag; MIII = In, Y) Steiner, H. -J.; Lutz, H. D. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 613, Issue 7 https://doi.org/10.1002/zaac.19926130104	journal	July 1992
Li6PS5X: A Class of Crystalline Li-Rich Solids With an Unusually High Li+ Mobility Deiseroth, Hans-Jörg; Kong, Shiao-Tong; Eckert, Hellmut Angewandte Chemie International Edition, Vol. 47, Issue 4 https://doi.org/10.1002/anie.200703900	journal	January 2008
Group 14 element based sodium chalcogenide Na4Sn0.67Si0.33S4 as structure template for exploring sodium superionic conductors Jia, Huanhuan; Sun, Yulong; Zhang, Zhuoran Energy Storage Materials, Vol. 23 https://doi.org/10.1016/j.ensm.2019.04.011	journal	December 2019
Lithium Ionic Conductor Thio-LISICON: The Li₂S-GeS₂-P₂S₅ System Kanno, Ryoji; Murayama, Masahiro Journal of The Electrochemical Society, Vol. 148, Issue 7, p. A742-A746 https://doi.org/10.1149/1.1379028	journal	January 2001
First-principles study of superionic Na _9+x Sn _x M _3−x S ₁₂ (M = P, Sb) Sorkin, Anastassia; Adams, Stefan Materials Advances, Vol. 1, Issue 2 https://doi.org/10.1039/d0ma00177e	journal	January 2020
Inducing High Ionic Conductivity in the Lithium Superionic Argyrodites Li _{6+ x} P _{1– x} Ge _x S ₅ I for All-Solid-State Batteries Kraft, Marvin A.; Ohno, Saneyuki; Zinkevich, Tatiana Journal of the American Chemical Society, Vol. 140, Issue 47 https://doi.org/10.1021/jacs.8b10282	journal	October 2018
The Crystal Structure of NaM2IV(PO4)3; MeIV = Ge, Ti, Zr. Hagman, Lars-Ove; Kierkegaard, Peder; Karvonen, Pertti Acta Chemica Scandinavica, Vol. 22 https://doi.org/10.3891/acta.chem.scand.22-1822	journal	January 1968

Similar Records

Influence of Reduced Na Vacancy Concentrations in the Sodium Superionic Conductors Na_11+xS_n2P_1–xM_xS₁₂ (M = Sn, Ge)

Journal Article · Thu Jul 01 00:00:00 EDT 2021 · ACS Applied Energy Materials · OSTI ID:1828964

Kraft, Marvin A.; Gronych, Lara M.; Famprikis, Theodosios; +1 more

Evidence for a Solid-Electrolyte Inductive Effect in the Superionic Conductor Li₁₀Ge_1–xSn_xP₂S₁₂

Journal Article · Mon Dec 07 00:00:00 EST 2020 · Journal of the American Chemical Society · OSTI ID:1828964

Culver, Sean P.; Squires, Alexander G.; Minafra, Nicolò; +6 more

Structure and Sodium Ion Transport in Na_11+xSn_2+x(Sb_1–yP_y)_1–xS₁₂

Journal Article · Wed Jul 01 00:00:00 EDT 2020 · Chemistry of Materials · OSTI ID:1828964

Kraft, Marvin A.; Gronych, Lara M.; Famprikis, Theodosios; +2 more

Title: Influence of Reduced Na Vacancy Concentrations in the Sodium Superionic Conductors Na11+xSn2P1–xMxS12 (M = Sn, Ge)

Citation Formats

References (48)

Similar Records

Related Subjects

Title: Influence of Reduced Na Vacancy Concentrations in the Sodium Superionic Conductors Na_11+xSn₂P_1–xM_xS₁₂ (M = Sn, Ge)