Calorimetric Study of Functionalized Uranyl Peroxide Nanoclusters and Their Monomeric Building Block

Traustason, Hrafn; Caranto, Kiana; Burns, Peter C.

doi:10.1002/ejic.202100307

Calorimetric Study of Functionalized Uranyl Peroxide Nanoclusters and Their Monomeric Building Block

Journal Article · Thu Jul 01 00:00:00 EDT 2021 · European Journal of Inorganic Chemistry

DOI:https://doi.org/10.1002/ejic.202100307· OSTI ID:1828746

Traustason, Hrafn ^[1]; Caranto, Kiana ^[2]; ^[2]

Univ. of Notre Dame, IN (United States); University of Notre Dame
Univ. of Notre Dame, IN (United States)

The description of the energy landscape of polyoxometalates (POMs) enriches our understanding of their solution behavior through quantitative information that can be used to predict their existence, stability, and properties. Herein, we report thermodynamic values that describe the energy landscape of four uranyl peroxide nanoclusters (UPCs) (LiRb–U@U₂₄, LiNa–U₂₄Pp₁₂, NaK–U₂₄Pp₁₂, and U₆₀Ox₃₀) and a building block of UPCs, lithium uranyl triperoxide monomer (Li–UT). Furthermore, the results reveal relationships between the affinity of counter cations and the anionic uranyl peroxide units, enthalpy of dissolution, as well as enthalpy of crystallization and cluster solubility. Additionally, the calorimetric measurements of Li–UT allowed us to calculate a favorable enthalpy of formation of Li–U₂₄ and Li–U₂₈ from their monomeric units.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Notre Dame, IN (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0003763

OSTI ID:: 1828746

Journal Information:: European Journal of Inorganic Chemistry, Journal Name: European Journal of Inorganic Chemistry Journal Issue: 28 Vol. 2021; ISSN 1434-1948

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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