Exploring the Pb 1− x Sr x HfO 3 System and Potential for High Capacitive Energy Storage Density and Efficiency

Acharya, Megha; Banyas, Ella; Ramesh, Maya; Jiang, Yizhe; Fernandez, Abel; Dasgupta, Arvind; Ling, Handong; Hanrahan, Brendan; Persson, Kristin; Neaton, Jeffrey B.; Martin, Lane W.

doi:10.1002/adma.202105967

Exploring the Pb ₁₋ _x Sr _x HfO ₃ System and Potential for High Capacitive Energy Storage Density and Efficiency

Journal Article · Fri Oct 15 00:00:00 EDT 2021 · Advanced Materials

DOI:https://doi.org/10.1002/adma.202105967· OSTI ID:1826630

^[1]; Banyas, Ella ^[2]; Ramesh, Maya ^[3]; Jiang, Yizhe ^[3]; Fernandez, Abel ^[3]; Dasgupta, Arvind ^[3]; Ling, Handong ^[3]; Hanrahan, Brendan ^[4]; Persson, Kristin ^[5]; Neaton, Jeffrey B. ^[6]; ^[1]

Department of Materials Science and Engineering University of California, Berkeley Berkeley CA 94720 USA, Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
Department of Materials Science and Engineering University of California, Berkeley Berkeley CA 94720 USA
U.S. Army Research Laboratory Adelphi MD 20783 USA
Department of Materials Science and Engineering University of California, Berkeley Berkeley CA 94720 USA, Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA, Molecular Foundry Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA, Molecular Foundry Lawrence Berkeley National Laboratory Berkeley CA 94720 USA, Department of Physics University of California, Berkeley Berkeley CA 94720 USA, Kavli Energy Nanosciences Institute University of California Berkeley CA 94720 USA

Abstract

The hafnate perovskites PbHfO ₃ (antiferroelectric) and SrHfO ₃ (“potential” ferroelectric) are studied as epitaxial thin films on SrTiO ₃ (001) substrates with the added opportunity of observing a morphotropic phase boundary (MPB) in the Pb ₁₋ _x Sr _x HfO ₃ system. The resulting (240)‐oriented PbHfO ₃ ( Pba 2) films exhibited antiferroelectric switching with a saturation polarization ≈53 µC cm ⁻² at 1.6 MV cm ⁻¹ , weak‐field dielectric constant ≈186 at 298 K, and an antiferroelectric‐to‐paraelectric phase transition at ≈518 K. (002)‐oriented SrHfO ₃ films exhibited neither ferroelectric behavior nor evidence of a polar P 4 mm phase . Instead, the SrHfO ₃ films exhibited a weak‐field dielectric constant ≈25 at 298 K and no signs of a structural transition to a polar phase as a function of temperature (77–623 K) and electric field (–3 to 3 MV cm ⁻¹ ). While the lack of ferroelectric order in SrHfO ₃ removes the potential for MPB, structural and property evolution of the Pb ₁₋ _x Sr _x HfO ₃ (0 ≤ x < 1) system is explored. Strontium alloying increased the electric‐breakdown strength ( E _B ) and decreased hysteresis loss, thus enhancing the capacitive energy storage density ( U _r ) and efficiency (η). The composition, Pb _0.5 Sr _0.5 HfO ₃ produced the best combination of E _B = 5.12 ± 0.5 MV cm ⁻¹ , U _r = 77 ± 5 J cm ⁻³ , and η = 97 ± 2%, well out‐performing PbHfO ₃ and other antiferroelectric oxides.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1826630

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 1 Vol. 34; ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (69)

High-Performance Dielectric Ceramic Films for Energy Storage Capacitors: Progress and Outlook Palneedi, Haribabu; Peddigari, Mahesh; Hwang, Geon-Tae Advanced Functional Materials, Vol. 28, Issue 42 https://doi.org/10.1002/adfm.201803665	journal	August 2018
Enhanced Electrical Resistivity and Properties via Ion Bombardment of Ferroelectric Thin Films Saremi, Sahar; Xu, Ruijuan; Dedon, Liv R. Advanced Materials, Vol. 28, Issue 48 https://doi.org/10.1002/adma.201603968	journal	October 2016
Theory‐Guided Synthesis of a Metastable Lead‐Free Piezoelectric Polymorph Garten, Lauren M.; Dwaraknath, Shyam; Walker, Julian Advanced Materials, Vol. 30, Issue 25 https://doi.org/10.1002/adma.201800559	journal	May 2018
Electronic Transport and Ferroelectric Switching in Ion-Bombarded, Defect-Engineered BiFeO ₃ Thin Films Saremi, Sahar; Xu, Ruijuan; Dedon, Liv R. Advanced Materials Interfaces, Vol. 5, Issue 3 https://doi.org/10.1002/admi.201700991	journal	November 2017
Thin Hf _x Zr _{1- x} O ₂ Films: A New Lead-Free System for Electrostatic Supercapacitors with Large Energy Storage Density and Robust Thermal Stability Park, Min Hyuk; Kim, Han Joon; Kim, Yu Jin Advanced Energy Materials, Vol. 4, Issue 16 https://doi.org/10.1002/aenm.201400610	journal	July 2014
Raman study of temperature-induced phase transitions in lead hafnate (PbHfO3) Sharma, Shiv K.; Jayaraman, A.; Chowdhury, C. Pal Journal of Raman Spectroscopy, Vol. 25, Issue 5 https://doi.org/10.1002/jrs.1250250508	journal	May 1994
Lattice dynamics and thermal properties of SrHfO ₃ by first-principles calculations: Lattice dynamics and thermal properties of SrHfO ₃ Murata, Hidenobu; Yamamoto, Tomoyuki; Moriwake, Hiroki physica status solidi (b), Vol. 246, Issue 7 https://doi.org/10.1002/pssb.200945041	journal	June 2009
PLZT film capacitors for power electronics and energy storage applications Ma, Beihai; Hu, Zhongqiang; Koritala, Rachel E. Journal of Materials Science: Materials in Electronics, Vol. 26, Issue 12 https://doi.org/10.1007/s10854-015-3025-0	journal	April 2015
Enhanced electrocaloric effect and energy-storage performance in PBLZT films with various Ba2+ content Gao, Hongcheng; Sun, Ningning; Li, Yong Ceramics International, Vol. 42, Issue 15 https://doi.org/10.1016/j.ceramint.2016.08.054	journal	November 2016
High energy storage density at low electric field of ABO3 antiferroelectric films with ionic pair doping Zhang, Tiandong; Zhao, Yu; Li, Weili Energy Storage Materials, Vol. 18 https://doi.org/10.1016/j.ensm.2018.09.011	journal	March 2019
Relaxor-ferroelectric thin film heterostructure with large imprint for high energy-storage performance at low operating voltage Nguyen, Minh D.; Houwman, Evert P.; Do, Minh T. Energy Storage Materials, Vol. 25 https://doi.org/10.1016/j.ensm.2019.10.015	journal	March 2020
Controlling microstructure and film growth of relaxor-ferroelectric thin films for high break-down strength and energy-storage performance Nguyen, Minh D.; Nguyen, Chi T. Q.; Vu, Hung N. Journal of the European Ceramic Society, Vol. 38, Issue 1 https://doi.org/10.1016/j.jeurceramsoc.2017.08.027	journal	January 2018
High energy storage performance in Ca-doped PbZrO3 antiferroelectric films Li, Yi Zhuo; Wang, Zhan Jie; Bai, Yu Journal of the European Ceramic Society, Vol. 40, Issue 4 https://doi.org/10.1016/j.jeurceramsoc.2019.11.063	journal	April 2020
Tailoring energy-storage performance in antiferroelectric PbHfO3 thin films Huang, Xian-Xiong; Zhang, Tian-Fu; Wang, Wei Materials & Design, Vol. 204 https://doi.org/10.1016/j.matdes.2021.109666	journal	June 2021
Toward a multifunctional monolithic device based on pyroelectricity and the electrocaloric effect of thin antiferroelectric Hf x Zr 1−x O 2 films Park, Min Hyuk; Kim, Han Joon; Kim, Yu Jin Nano Energy, Vol. 12 https://doi.org/10.1016/j.nanoen.2014.09.025	journal	March 2015
Mechanism of enhanced energy storage density in AgNbO3-based lead-free antiferroelectrics Lu, Zhilun; Bao, Weichao; Wang, Ge Nano Energy, Vol. 79 https://doi.org/10.1016/j.nanoen.2020.105423	journal	January 2021
Structural phases of SrHfO3 Vali, R. Solid State Communications, Vol. 148, Issue 1-2 https://doi.org/10.1016/j.ssc.2008.07.018	journal	October 2008
Structural properties of epitaxial SrHfO3 thin films on Si (001) Sawkar-Mathur, Monica; Marchiori, Chiara; Fompeyrine, Jean Thin Solid Films, Vol. 518, Issue 6 https://doi.org/10.1016/j.tsf.2009.10.068	journal	January 2010
Searching for New Ferroelectric Materials Using High-Throughput Databases: An Experimental Perspective on BiAlO ₃ and BiInO ₃ Acharya, Megha; Mack, Stephanie; Fernandez, Abel Chemistry of Materials, Vol. 32, Issue 17 https://doi.org/10.1021/acs.chemmater.0c01770	journal	August 2020
Origin of Disorder Tolerance in Piezoelectric Materials and Design of Polar Systems Ling, Handong; Dwaraknath, Shyam S.; Persson, Kristin A. Chemistry of Materials, Vol. 32, Issue 7 https://doi.org/10.1021/acs.chemmater.9b04614	journal	March 2020
Large Room Temperature Negative Electrocaloric Effect in Novel Antiferroelectric PbHfO ₃ Films Huang, Xian-Xiong; Zhang, Tian-Fu; Gao, Rong-Zhen ACS Applied Materials & Interfaces, Vol. 13, Issue 18 https://doi.org/10.1021/acsami.1c03079	journal	April 2021
Large Energy Storage Density and High Thermal Stability in a Highly Textured (111)-Oriented Pb _0.8 Ba _0.2 ZrO ₃ Relaxor Thin Film with the Coexistence of Antiferroelectric and Ferroelectric Phases Peng, Biaolin; Zhang, Qi; Li, Xing ACS Applied Materials & Interfaces, Vol. 7, Issue 24 https://doi.org/10.1021/acsami.5b02790	journal	June 2015
Antiferroelectric Thin-Film Capacitors with High Energy-Storage Densities, Low Energy Losses, and Fast Discharge Times Ahn, Chang Won; Amarsanaa, Gantsooj; Won, Sung Sik ACS Applied Materials & Interfaces, Vol. 7, Issue 48 https://doi.org/10.1021/acsami.5b08786	journal	November 2015
Ultrahigh-Energy Storage Properties of (PbCa)ZrO ₃ Antiferroelectric Thin Films via Constructing a Pyrochlore Nanocrystalline Structure Li, Yi Zhuo; Lin, Jun Liang; Bai, Yu ACS Nano, Vol. 14, Issue 6 https://doi.org/10.1021/acsnano.0c00791	journal	May 2020
SrHfO ₃ Films Grown on Si(100) by Plasma-Assisted Atomic Layer Deposition. Black, K.; Werner, M.; Rowlands–Jones, R. Chemistry of Materials, Vol. 23, Issue 10 https://doi.org/10.1021/cm200315u	journal	April 2011
An automatically curated first-principles database of ferroelectrics Smidt, Tess E.; Mack, Stephanie A.; Reyes-Lillo, Sebastian E. Scientific Data, Vol. 7, Issue 1 https://doi.org/10.1038/s41597-020-0407-9	journal	March 2020
High dielectric constant and capacitance in ultrasmall (2.5 nm) SrHfO ₃ perovskite nanoparticles produced in a low temperature non-aqueous sol–gel route Karmaoui, Mohamed; Ramana, E. Venkata; Tobaldi, David M. RSC Advances, Vol. 6, Issue 57 https://doi.org/10.1039/C6RA06990H	journal	January 2016
Enhanced energy-storage performance of an all-inorganic flexible bilayer-like antiferroelectric thin film via using electric field engineering Shen, Bingzhong; Li, Yong; Sun, Ningning Nanoscale, Vol. 12, Issue 16 https://doi.org/10.1039/C9NR10616B	journal	January 2020
Ultra-high energy storage density and scale-up of antiferroelectric TiO ₂ /ZrO ₂ /TiO ₂ stacks for supercapacitors Yi, Sheng-Han; Lin, Hsin-Chih; Chen, Miin-Jang Journal of Materials Chemistry A, Vol. 9, Issue 14 https://doi.org/10.1039/D0TA11991A	journal	January 2021
Achieving high energy efficiency and energy density in PbHfO ₃ -based antiferroelectric ceramics Chao, Wenna; Yang, Tongqing; Li, Yongxiang Journal of Materials Chemistry C, Vol. 8, Issue 47 https://doi.org/10.1039/D0TC04617E	journal	January 2020
Optical properties of epitaxial SrHfO3 thin films grown on Si Sousa, M.; Rossel, C.; Marchiori, C. Journal of Applied Physics, Vol. 102, Issue 10 https://doi.org/10.1063/1.2812425	journal	November 2007
Enhancement of charge and energy storage in sol-gel derived pure and La-modified PbZrO3 thin films Parui, Jayanta; Krupanidhi, S. B. Applied Physics Letters, Vol. 92, Issue 19 https://doi.org/10.1063/1.2928230	journal	May 2008
High energy-storage performance in Pb _0.91 La _0.09 (Ti _0.65 Zr _0.35 )O ₃ relaxor ferroelectric thin films Hao, Xihong; Wang, Ying; Yang, Jichun Journal of Applied Physics, Vol. 112, Issue 11 https://doi.org/10.1063/1.4768461	journal	December 2012
Enhanced polarization switching and energy storage properties of Pb _0.97 La _0.02 (Zr _0.95 Ti _0.05 )O ₃ antiferroelectric thin films with LaNiO ₃ oxide top electrodes Ge, Jun; Dong, Xianlin; Chen, Ying Applied Physics Letters, Vol. 102, Issue 14 https://doi.org/10.1063/1.4801517	journal	April 2013
Composition-dependent dielectric and energy-storage properties of (Pb,La)(Zr,Sn,Ti)O ₃ antiferroelectric thick films Hao, Xihong; Wang, Ying; Zhang, Le Applied Physics Letters, Vol. 102, Issue 16 https://doi.org/10.1063/1.4802794	journal	April 2013
Effect of growth induced (non)stoichiometry on the thermal conductivity, permittivity, and dielectric loss of LaAlO ₃ films Breckenfeld, E.; Wilson, R. B.; Martin, L. W. Applied Physics Letters, Vol. 103, Issue 8 https://doi.org/10.1063/1.4818718	journal	August 2013
Rayleigh-like nonlinear dielectric response and its evolution during electrical fatigue in antiferroelectric (Pb,La)(Zr,Ti)O ₃ thin film Luo, Zhengdong; Lou, Xiaojie; Zhang, Fuping Applied Physics Letters, Vol. 104, Issue 14 https://doi.org/10.1063/1.4870992	journal	April 2014
Atomic layer deposition of crystalline SrHfO ₃ directly on Ge (001) for high- k dielectric applications McDaniel, Martin D.; Hu, Chengqing; Lu, Sirong Journal of Applied Physics, Vol. 117, Issue 5 https://doi.org/10.1063/1.4906953	journal	February 2015
Silicon-doped hafnium oxide anti-ferroelectric thin films for energy storage Ali, Faizan; Liu, Xiaohua; Zhou, Dayu Journal of Applied Physics, Vol. 122, Issue 14 https://doi.org/10.1063/1.4989908	journal	October 2017
Flexible high energy density capacitors using La-doped PbZrO ₃ anti-ferroelectric thin films Lee, Hye Ji; Won, Sung Sik; Cho, Kyung Ho Applied Physics Letters, Vol. 112, Issue 9 https://doi.org/10.1063/1.5018003	journal	February 2018
La-doped Hf _0.5 Zr _0.5 O ₂ thin films for high-efficiency electrostatic supercapacitors Kozodaev, Maxim G.; Chernikova, Anna G.; Khakimov, Roman R. Applied Physics Letters, Vol. 113, Issue 12 https://doi.org/10.1063/1.5045288	journal	September 2018
Effect of ferroelectric domain walls on the dielectric properties of PbZrO ₃ thin films Coulibaly, Mamadou D.; Borderon, Caroline; Renoud, Raphaël Applied Physics Letters, Vol. 117, Issue 14 https://doi.org/10.1063/5.0017984	journal	October 2020
The other model antiferroelectric: PbHfO ₃ thin films from ALD precursors Hanrahan, Brendan; Milesi-Brault, Cosme; Leff, Asher APL Materials, Vol. 9, Issue 2 https://doi.org/10.1063/5.0035730	journal	February 2021
Evidence of residual ferroelectric contribution in antiferroelectric lead-zirconate thin films by first-order reversal curves Nadaud, Kevin; Borderon, Caroline; Renoud, Raphaël Applied Physics Letters, Vol. 118, Issue 4 https://doi.org/10.1063/5.0043293	journal	January 2021
Dielectric spectroscopy of the antiferroelectric PbHfO ₃ Roleder, K.; Maglione, M.; Fontana, M. D. Ferroelectrics, Vol. 238, Issue 1 https://doi.org/10.1080/00150190008008777	journal	February 2000
Temperature Dependence of Order Parameters in the Antiferroelectric Phases of Perovskite PbHfO 3 Fujishita, Hideshi; Ishikawa, Yuya Ferroelectrics, Vol. 269, Issue 1 https://doi.org/10.1080/00150190211175	journal	January 2002
The temperature-electric field phase diagram of lead hafnate Fesenko, O. E.; Balyunis, L. E. Ferroelectrics, Vol. 29, Issue 1 https://doi.org/10.1080/00150198008009017	journal	August 1980
Peculiar electric and photoelectric behavior of lead-containing perovskite-type oxides Prokopalo, O. I.; Raevskii, I. P.; Malitskaya, M. A. Ferroelectrics, Vol. 45, Issue 1 https://doi.org/10.1080/00150198208208286	journal	August 1982
Antiferroelectric lead zirconate, a material for energy storage Singh, K. Ferroelectrics, Vol. 94, Issue 1 https://doi.org/10.1080/00150198908014299	journal	June 1989
The study on the dielectric property and structure of perovskite titanate CdTiO ₃ Sun, Pai-Hsuan; Nakamura, Tetsuro; Shan, Yue Jin Ferroelectrics, Vol. 217, Issue 1 https://doi.org/10.1080/00150199808015031	journal	September 1998
Structural study of PbTiO ₃ , PbZrO ₃ and PbHfO ₃ Kuprianov, M. F.; Zaitsev, S. M.; Gagarina, E. S. Phase Transitions, Vol. 4, Issue 1 https://doi.org/10.1080/01411598308218847	journal	December 1983
Ferroelectric, dielectric and piezoelectric properties of ferroelectric thin films and ceramics Damjanovic, Dragan Reports on Progress in Physics, Vol. 61, Issue 9 https://doi.org/10.1088/0034-4885/61/9/002	journal	September 1998
X-Ray and Neutron Diffraction Study of Antiferroelectric Lead Zirconate, PbZr O 3 Jona, F.; Shirane, G.; Mazzi, F. Physical Review, Vol. 105, Issue 3 https://doi.org/10.1103/PhysRev.105.849	journal	February 1957
Ferroelectricity and Antiferroelectricity in Ceramic PbZr O 3 Containing Ba or Sr Shirane, Gen Physical Review, Vol. 86, Issue 2 https://doi.org/10.1103/PhysRev.86.219	journal	April 1952
Improved tetrahedron method for Brillouin-zone integrations Blöchl, Peter E.; Jepsen, O.; Andersen, O. K. Physical Review B, Vol. 49, Issue 23 https://doi.org/10.1103/PhysRevB.49.16223	journal	June 1994
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
First-principles determination of a ferroelectric instability in SrHfO 3 Stachiotti, M. G.; Fabricius, G.; Alonso, R. Physical Review B, Vol. 58, Issue 13 https://doi.org/10.1103/PhysRevB.58.8145	journal	October 1998
High-temperature phase transitions in SrHfO 3 Kennedy, Brendan J.; Howard, Christopher J.; Chakoumakos, Bryan C. Physical Review B, Vol. 60, Issue 5 https://doi.org/10.1103/PhysRevB.60.2972	journal	August 1999
Hybrid exchange-correlation functional for accurate prediction of the electronic and structural properties of ferroelectric oxides Bilc, D. I.; Orlando, R.; Shaltaf, R. Physical Review B, Vol. 77, Issue 16 https://doi.org/10.1103/PhysRevB.77.165107	journal	April 2008
Comparative first-principles studies of prototypical ferroelectric materials by LDA, GGA, and SCAN meta-GGA Zhang, Yubo; Sun, Jianwei; Perdew, John P. Physical Review B, Vol. 96, Issue 3 https://doi.org/10.1103/PhysRevB.96.035143	journal	July 2017
Investigation into the Crystal Structure of the Perovskite Lead Hafnate, PbHfO ₃ Corker, D. L.; Glazer, A. M.; Kaminsky, W. Acta Crystallographica Section B Structural Science, Vol. 54, Issue 1 https://doi.org/10.1107/S0108768197009208	journal	February 1998
Crystallographic and optical study of PbHfO ₃ crystals Huband, S.; Glazer, A. M.; Roleder, K. Journal of Applied Crystallography, Vol. 50, Issue 2 https://doi.org/10.1107/S1600576717000309	journal	February 2017
Effect of the ac Field Level on the Aging of the Dielectric Response in Polycrystalline BaTiO3 Wu, Kaiwen; Schulze, Walter A. Journal of the American Ceramic Society, Vol. 75, Issue 12 https://doi.org/10.1111/j.1151-2916.1992.tb04438.x	journal	December 1992
Improved Energy Storage Performance and Fatigue Endurance of Sr-Doped PbZrO ₃ Antiferroelectric Thin Films Hao, Xihong; Zhai, Jiwei; Yao, Xi Journal of the American Ceramic Society, Vol. 92, Issue 5 https://doi.org/10.1111/j.1551-2916.2009.03015.x	journal	May 2009
Effect of Eu Doping on the Electrical Properties and Energy Storage Performance of PbZrO ₃ Antiferroelectric Thin Films Ye, Mao; Sun, Qiu; Chen, Xiangqun Journal of the American Ceramic Society, Vol. 94, Issue 10 https://doi.org/10.1111/j.1551-2916.2011.04814.x	journal	September 2011
A Statistical Distribution Function of Wide Applicability Weibull, Waloddi Journal of Applied Mechanics, Vol. 18, Issue 3 https://doi.org/10.1115/1.4010337	journal	September 1951
High-temperature phase transitions in SrHfO ₃ : A Raman scattering study Singh, Manoj K.; Singh, Gulab; Kim, Tae Hyun EPL (Europhysics Letters), Vol. 107, Issue 2 https://doi.org/10.1209/0295-5075/107/26004	journal	July 2014
Review and perspective on ferroelectric HfO2-based thin films for memory applications Park, Min Hyuk; Lee, Young Hwan; Mikolajick, Thomas MRS Communications, Vol. 8, Issue 03 https://doi.org/10.1557/mrc.2018.175	journal	August 2018
Importance of interface engineering for synthesis of SrHfO ₃ perovskite thin films on Si substrates through crystallization of amorphous films and control of flat-band voltages of metal–oxide–semiconductor capacitors Migita, Shinji; Morita, Yukinori; Masahara, Meishoku Japanese Journal of Applied Physics, Vol. 53, Issue 4S https://doi.org/10.7567/JJAP.53.04EA03	journal	January 2014

Similar Records

DIELECTRIC BEHAVIOR IN THE SYSTEMS PbHfO$sub 3$-BaHfO$sub 3$ AND PbHfO$sub 3$-SrHfO$sub 3$

Journal Article · Sat Mar 31 23:00:00 EST 1962 · Dissertation Abstr. · OSTI ID:4806457

THE FERROELECTRIC-ANTIFERROELECTRIC TRANSITION AND DIELECTRIC PROPERTIES IN THE TERNARY SYSTEM PbZrO$sub 3$-PbHfO$sub 3$-PbTiO$sub 3$

Thesis/Dissertation · Sun Dec 31 23:00:00 EST 1961 · OSTI ID:4711752

Dielectric Behavior in the Systems PbHfO ₃ -BaHfO ₃ and PbHfO ₃ -SrHfO ₃

Journal Article · Mon Jul 01 00:00:00 EDT 1963 · Journal of the American Ceramic Society · OSTI ID:4704126

Exploring the Pb 1− x Sr x HfO 3 System and Potential for High Capacitive Energy Storage Density and Efficiency

Citation Formats

References (69)

Similar Records

Related Subjects

Exploring the Pb ₁₋ _x Sr _x HfO ₃ System and Potential for High Capacitive Energy Storage Density and Efficiency