Coupling morphological and magnetic anisotropy for assembling tetragonal colloidal crystals

Li, Zhiwei; Qian, Chang; Xu, Wenjing; Zhu, Chenhui; Yin, Yadong

doi:10.1126/sciadv.abh1289

Coupling morphological and magnetic anisotropy for assembling tetragonal colloidal crystals

Journal Article · Fri Sep 10 00:00:00 EDT 2021 · Science Advances

DOI:https://doi.org/10.1126/sciadv.abh1289· OSTI ID:1826345

^[1]; ^[1]; Xu, Wenjing ^[1]; ^[2]; ^[1]

Univ. of California, Riverside, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Morphological and magnetic anisotropy can be combined in colloidal assembly to create unconventional secondary structures. We show here that magnetite nanorods interact along a critical angle, depending on their aspect ratios and assemble into body-centered tetragonal colloidal crystals. Under a magnetic field, size-dependent attractive and repulsive domains develop on the ends and center of the nanorods, respectively. Our joint experiment-computational multiscale study demonstrates the presence of a critical angle in the attractive domain, which defines the equilibrium bonding states of interacting rods and leads to the formation of non–close-packed yet hard-contact tetragonal crystals. Small-angle x-ray scattering measurement attributes the perfect tetragonal phase to the slow assembly kinetics. The crystals exhibit brilliant structural colors, which can be actively tuned by changing the magnetic field direction. These highly ordered frameworks and well-defined three-dimensional nanochannels may offer new opportunities for manipulating nanoscale chemical transformation, mass transportation, and wave propagation.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1826345

Journal Information:: Science Advances, Journal Name: Science Advances Journal Issue: 37 Vol. 7; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

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