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Sustainable energy and fuels from biomass: a review focusing on hydrothermal biomass processing

Journal Article · · Sustainable Energy & Fuels
DOI:https://doi.org/10.1039/d0se00784f· OSTI ID:1826009
Fossil fuels are being replaced with renewable energy resources (biomass and biomass waste, solar, geothermal, wind, etc.) to ensure sustainable development, reduce the dependence on fossil fuels, address environmental challenges including climate change. Today, biomass produces 5 × 1019 kJ of energy/year, which corresponds to 10% of the annual global energy consumption. Considering the variety of biomass resources, this value is predicted to reach 150 × 1019 kJ by 2050. Biomass may become even more important for use as an energy resource and chemical raw material in the 21st century. Hydrothermal biomass conversion stands out as a promising and alternative technology. Methods such as traditional gasification and pyrolysis require dry biomass. Hydrothermal techniques have been developed to eliminate the cost and time required for drying biomass. The purpose of this process is to decompose biomass with a high moisture content into small molecules and reduce its oxygen content to obtain liquid fuels or valuable chemicals. Finally, this review presents the current and future state of energy, energy sources, biomass properties and biomass conversion technologies with a focus on hydrothermal technologies.
Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1826009
Journal Information:
Sustainable Energy & Fuels, Journal Name: Sustainable Energy & Fuels Journal Issue: 9 Vol. 4; ISSN 2398-4902
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English

References (182)

Chemistry in Supercritical Water journal October 1999
Cellulose: Fascinating Biopolymer and Sustainable Raw Material journal May 2005
Supercritical Water as a Solvent journal April 2005
The Future of Energy Supply: Challenges and Opportunities journal January 2007
Biofuels and Biomass-To-Liquid Fuels in the Biorefinery: Catalytic Conversion of Lignocellulosic Biomass using Porous Materials journal October 2008
Beyond Petrochemicals: The Renewable Chemicals Industry journal October 2011
Hydrothermal carbonization of biomass: A summary and discussion of chemical mechanisms for process engineering journal March 2010
Direct Liquefaction of Biomass journal May 2008
Further aspects of powdered poplar wood liquefaction by aqueous pyrolysis journal August 1985
Catalytic upgrading of biomass-derived oils to transportation fuels and chemicals journal October 1991
Cellulose Conversion under Heterogeneous Catalysis journal December 2008
Subcritical Water as Reaction Environment: Fundamentals of Hydrothermal Biomass Transformation journal February 2011
Reactive Extraction of Levulinate Esters and Conversion to γ-Valerolactone for Production of Liquid Fuels journal January 2011
Hydrothermal Liquefaction of α‐O‐4 Aryl Ether Linkages in Lignin journal February 2020
Distributions of organic compounds to the products from hydrothermal liquefaction of microalgae journal October 2016
A review on the operating conditions of producing bio-oil from hydrothermal liquefaction of biomass: Producing bio-oil from hydrothermal liquefaction of biomass journal January 2016
Hydrothermal catalytic production of fuels and chemicals from aquatic biomass: Production of fuels and chemicals from aquatic biomass journal October 2012
Progress in Renewable Polymers from Natural Terpenes, Terpenoids, and Rosin journal October 2012
t-BuOK catalyzed bio-oil production from woody biomass under sub-critical water conditions journal July 2012
Pretreatment and Lignocellulosic Chemistry journal May 2012
Two-stage alkaline hydrothermal liquefaction of wood to biocrude in a continuous bench-scale system journal February 2017
Fundamentals of Hydrofaction™: Renewable crude oil from woody biomass journal February 2017
Conversion of a wet waste feedstock to biocrude by hydrothermal processing in a continuous-flow reactor: grape pomace journal May 2017
Hydrothermal and supercritical ethanol processing of woody biomass with a high-silica zeolite catalyst journal February 2019
The hydrothermolysis of cellobiose and its reaction-product d-glucose journal December 1983
Rapid hydrothermolysis of cellulose and related carbohydrates journal December 1986
The role of deoxyhexonic acids in the hydrothermal decarboxylation of carbohydrates journal August 1995
Liquid fuels from biomass via a hydrothermal process journal January 1990
Oil production from algal cells of Dunaliella tertiolecta by direct thermochemical liquefaction journal December 1995
Catalysis in thermal biomass conversion journal September 1994
Monodispersed hard carbon spherules with uniform nanopores journal November 2001
Assessment of simulated biogas as a fuel for the spark ignition engine journal December 1998
Composites reinforced with cellulose based fibres journal May 1999
Beech leaf litter lignin degradation and transformation as influenced by mineral phases journal May 1998
An overview of fast pyrolysis of biomass journal December 1999
Energy education: breaking up the rational energy use barriers journal July 2004
Energy education journal September 1999
Ionic reactions and pyrolysis of glycerol as competing reaction pathways in near- and supercritical water journal January 2002
Cellulose hydrolysis in subcritical and supercritical water journal June 1998
Hydrolysis of esters in subcritical and supercritical water journal January 2000
Production of monomeric phenols by thermochemical conversion of biomass: a review journal September 2001
Energy production from biomass (part 1): overview of biomass journal May 2002
Energy production from biomass (part 2): conversion technologies journal May 2002
Energy production from biomass (part 3): gasification technologies journal May 2002
An assessment of supercritical water oxidation (SCWO) journal August 2001
Hydrothermal liquefaction of microalgae: Effect on the product yields of the addition of an organic solvent to separate the aqueous phase and the biocrude oil journal November 2015
Chemocatalytic hydrolysis of cellulose into glucose over solid acid catalysts journal September 2015
Hydrothermal liquefaction of cellulose to bio-oil under acidic, neutral and alkaline conditions journal April 2012
Continuous hydrothermal co-liquefaction of aspen wood and glycerol with water phase recirculation journal January 2016
Review of fast pyrolysis of biomass and product upgrading journal March 2012
Hydrothermal conversion of lignin compounds. A detailed study of fragmentation and condensation reaction pathways journal November 2012
Hydrothermal liquefaction (HTL) of microalgae for biofuel production: State of the art review and future prospects journal June 2013
Hydrothermal liquefaction of spent coffee grounds in water medium for bio-oil production journal March 2016
Subcritical hydrothermal liquefaction of cattle manure to bio-oil: Effects of conversion parameters on bio-oil yield and characterization of bio-oil journal May 2010
Hydrothermal liquefaction of the brown macro-alga Laminaria Saccharina: Effect of reaction conditions on product distribution and composition journal April 2011
Hydrothermal carbonization of anaerobically digested maize silage journal October 2011
Preparation and characteristics of bio-oil from the marine brown alga Sargassum patens C. Agardh journal January 2012
Hydrothermal liquefaction of cornelian cherry stones for bio-oil production journal April 2012
Hydrothermal liquefaction of Spirulina and Nannochloropsis salina under subcritical and supercritical water conditions journal March 2013
Influence of strain-specific parameters on hydrothermal liquefaction of microalgae journal October 2013
Effect of operating conditions on yield and quality of biocrude during hydrothermal liquefaction of halophytic microalga Tetraselmis sp. journal October 2014
Reductive de-polymerization of kraft lignin for chemicals and fuels using formic acid as an in-situ hydrogen source journal November 2014
Hydrothermal liquefaction of biomass: Developments from batch to continuous process journal February 2015
A comparison of product yields and inorganic content in process streams following thermal hydrolysis and hydrothermal processing of microalgae, manure and digestate journal January 2016
Fast hydrothermal liquefaction for production of chemicals and biofuels from wet biomass – The need to develop a plug-flow reactor journal August 2016
Hydrothermal liquefaction of agricultural and forestry wastes: state-of-the-art review and future prospects journal December 2017
Hydrothermal liquefaction of high- and low-lipid algae: Mass and energy balances journal June 2018
Hydrothermal upgrading of biomass to biofuel; studies on some monosaccharide model compounds journal July 2004
Hydrothermal conversion of biomass to fuels and energetic materials journal June 2013
Recovery of phenolic compounds through the decomposition of lignin in near and supercritical water journal September 2008
Non-catalytic Hydrothermal Liquefaction of Biomass: An Experimental Design Approach journal May 2017
Effects of various solvents on the liquefaction of biomass to produce fuels and chemical feedstocks journal December 2008
Analysis of liquid and solid products from liquefaction of paulownia in hot-compressed water journal February 2011
An investigation of reaction pathways of hydrothermal liquefaction using Chlorella pyrenoidosa and Spirulina platensis journal May 2015
Effect of process parameters on hydrothermal liquefaction of oil palm biomass for bio-oil production and its life cycle assessment journal November 2015
A comparative experimental study on the liquefaction of wood journal September 2004
Direct liquefaction of paulownia in hot compressed water: Influence of catalysts journal December 2010
Hydrothermal liquefaction of biomass: A review of subcritical water technologies journal May 2011
Hydrothermal treatment of biomass for energy and chemicals journal December 2016
Development of a decision support tool for the assessment of biofuels journal March 2011
Comparative studies of oil compositions produced from sawdust, rice husk, lignin and cellulose by hydrothermal treatment journal May 2005
Effects of heterogeneous catalyst in hydrothermal liquefaction of dried distillers grains with solubles journal May 2014
Hydrothermal liquefaction of woody biomass in hot-compressed water: Catalyst screening and comprehensive characterization of bio-crude oils journal December 2015
Biocrude from pretreated sorghum bagasse through catalytic hydrothermal liquefaction journal January 2017
Hydrothermal liquefaction of biomass: Influence of temperature and biomass composition on the bio-oil production journal November 2017
Hydrothermal liquefaction of lignocellulosic biomass feedstock to produce biofuels: Parametric study and products characterization journal July 2020
Hydrothermal processing of macroalgae for producing crude bio-oil journal February 2015
Hydrothermal degradation of lignin: Products analysis for phenol formaldehyde adhesive synthesis journal January 2015
Review of heterogeneous catalysts for sub- and supercritical water gasification of biomass and wastes journal August 2011
Direct conversion of biomass to bio-petroleum at low temperature journal March 2007
Thermochemical liquefaction of high-diversity grassland perennials journal January 2009
Hydrothermal liquefaction of cypress: Effects of reaction conditions on 5-lump distribution and composition journal March 2012
Products of hydrothermal treatment of lignin and the importance of ortho-directed repolymerization reactions journal July 2017
Fe-assisted hydrothermal liquefaction of cellulose: Effects of hydrogenation catalyst addition on properties of water-soluble fraction journal January 2020
Natural-gas fueled spark-ignition (SI) and compression-ignition (CI) engine performance and emissions journal February 2011
Recent progress in the direct liquefaction of typical biomass journal August 2015
Bio-fuels from thermochemical conversion of renewable resources: A review journal February 2008
Biomass-based energy fuel through biochemical routes: A review journal January 2009
A review of solar thermal technologies☆ journal January 2010
A review on process conditions for optimum bio-oil yield in hydrothermal liquefaction of biomass journal April 2011
A review of hydrothermal biomass processing journal December 2014
Opportunities, recent trends and challenges of integrated biorefinery: Part II journal March 2015
Opportunities, recent trends and challenges of integrated biorefinery: Part I journal March 2015
A review of bio-oil production from hydrothermal liquefaction of algae journal August 2015
Energy valorisation of food processing residues and model compounds by hydrothermal liquefaction journal February 2016
An overview of effect of process parameters on hydrothermal carbonization of biomass journal June 2017
Hydrogen donor solvents in liquefaction of biomass: A review journal January 2018
A review on hydrothermal liquefaction of biomass journal January 2018
A review on the current status of various hydrothermal technologies on biomass feedstock journal January 2018
Hot compressed water as reaction medium and reactant journal January 2007
Hydrothermal liquefaction of beech wood using a natural calcium borate mineral journal December 2012
Kinetic analysis of cellulose depolymerization reactions in near critical water journal March 2013
Catalytic depolymerisation and conversion of Kraft lignin into liquid products using near-critical water journal February 2014
High pressure water reforming of biomass for energy and chemicals: A short review journal January 2015
Biomass conversion to bio-oil using sub-critical water: Study of model compounds for food processing waste journal January 2017
Hydrothermal liquefaction of lignin in near-critical water in a new batch reactor: Influence of phenol and temperature journal May 2017
Hydrothermal Conversion of Russian Olive Seeds into Crude Bio-oil Using a CaO Catalyst Derived from Waste Mussel Shells journal June 2015
Hydrothermal Liquefaction of Lignocellulosic Biomass Using Potassium Fluoride-Doped Alumina journal March 2019
Hydrothermal Liquefaction of Enzymatic Hydrolysis Lignin: Biomass Pretreatment Severity Affects Lignin Valorization journal March 2018
Acid and Alkali Catalyzed Hydrothermal Liquefaction of Dairy Manure Digestate and Food Waste journal December 2017
Synergistic and Antagonistic Interactions during Hydrothermal Liquefaction of Soybean Oil, Soy Protein, Cellulose, Xylose, and Lignin journal September 2018
Product Analysis from Direct Liquefaction of Several High-Moisture Biomass Feedstocks book September 1988
Roles of Water for Chemical Reactions in High-Temperature Water journal August 2002
Chemical Routes for the Transformation of Biomass into Chemicals journal June 2007
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering journal September 2006
Organic Chemical Reactions in Supercritical Water journal February 1999
Developments in direct thermochemical liquefaction of biomass: 1983-1990 journal May 1991
Low-Temperature Hydrothermal Treatment of Biomass:  Effect of Reaction Parameters on Products and Boiling Point Distributions journal December 2003
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review journal May 2006
Hydrothermal Liquefaction of Macroalgae Enteromorpha prolifera to Bio-oil journal July 2010
Hydrothermal Liquefaction and Gasification of Nannochloropsis sp. journal June 2010
Ultimate and Proximate Correlations for Estimating the Higher Heating Value of Hydrothermal Solids journal February 2013
Highly Efficient Liquefaction of Woody Biomass in Hot-Compressed Alcohol−Water Co-solvents journal September 2010
Decomposition of Cellulose in Near-Critical Water and Fermentability of the Products journal January 1996
Biomass Conversion in Water at 330−410 °C and 30−50 MPa. Identification of Key Compounds for Indicating Different Chemical Reaction Pathways journal January 2003
Hydrothermal Liquefaction of a Microalga with Heterogeneous Catalysts journal January 2011
Classified Separation of Lignin Hydrothermal Liquefied Products journal September 2011
Kinetic Analysis of Lignin Hydrothermal Conversion in Sub- and Supercritical Water journal April 2013
Hydrolysis of Microcrystalline Cellulose in Subcritical and Supercritical Water in a Continuous Flow Reactor journal December 2008
Kinetics of Glucose Epimerization and Decomposition in Subcritical and Supercritical Water journal May 1997
Mechanism and Kinetics of Cellobiose Decomposition in Sub- and Supercritical Water journal January 1998
Glucose and Fructose Decomposition in Subcritical and Supercritical Water:  Detailed Reaction Pathway, Mechanisms, and Kinetics journal August 1999
Dissolution and Hydrolysis of Cellulose in Subcritical and Supercritical Water journal August 2000
Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals journal February 2009
Occurrence of Naturally Acetylated Lignin Units journal July 2007
Hydrothermal Reactions of Agricultural and Food Processing Wastes in Sub- and Supercritical Water: A Review of Fundamentals, Mechanisms, and State of Research journal August 2013
Discovery of Cellulose as a Smart Material journal June 2006
Hydrothermal Processing of Macroalgal Feedstocks in Continuous-Flow Reactors journal October 2013
Alternative energy technologies journal November 2001
Oil's tipping point has passed journal January 2012
The geographical distribution of fossil fuels unused when limiting global warming to 2 °C journal January 2015
Towards a science of climate and energy choices journal May 2016
Acid Rain journal October 1979
Conversion of biomass to selected chemical products journal January 2012
Direct catalytic conversion of cellulose to liquid straight-chain alkanes journal January 2015
Effect of process parameters on hydrothermal liquefaction of waste furniture sawdust for bio-oil production journal January 2016
Hydrothermal liquefaction of blackcurrant pomace and model molecules: understanding of reaction mechanisms journal January 2017
Hydrothermal co-liquefaction of biomasses – quantitative analysis of bio-crude and aqueous phase composition journal January 2017
Production of bio-fuels and chemicals by microwave-assisted, catalytic, hydrothermal liquefaction (MAC-HTL) of a mixture of pine and spruce biomass journal January 2019
Back in the black: hydrothermal carbonization of plant material as an efficient chemical process to treat the CO2 problem? journal January 2007
Functional carbonaceous materials from hydrothermal carbonization of biomass: an effective chemical process journal January 2008
Thermochemical biofuel production in hydrothermal media: A review of sub- and supercritical water technologies journal January 2008
Combined dehydration/(transfer)-hydrogenation of C6-sugars (D-glucose and D-fructose) to γ-valerolactone using ruthenium catalysts journal January 2009
Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited journal January 2010
Catalytic conversion of biomass to biofuels journal January 2010
Cellulose nanomaterials review: structure, properties and nanocomposites journal January 2011
Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels journal January 2011
Biomass as renewable feedstock in standard refinery units. Feasibility, opportunities and challenges journal January 2012
Catalytic materials that improve selectivity of biomass conversions journal January 2012
Hydrothermal liquefaction of cellulose in subcritical water—the role of crystallinity on the cellulose reactivity journal January 2013
Static Dielectric Constant of Water and Steam journal October 1980
Ion product of water substance, 0–1000 °C, 1–10,000 bars New International Formulation and its background journal April 1981
Thermochemical Conversion of Biomass to Liquid Products in the Aqueous Medium journal October 2005
Recent Progress in Synthesis of Fine and Specialty Chemicals from Wood and Other Biomass by Heterogeneous Catalytic Processes journal June 2007
Energy crops: current status and future prospects journal November 2006
Biomass Recalcitrance: Engineering Plants and Enzymes for Biofuels Production journal February 2007
Catalytic Conversion of Biomass to Monofunctional Hydrocarbons and Targeted Liquid-Fuel Classes journal October 2008
Algae Under Pressure and in Hot Water journal November 2012
Gasification Technologies book April 2005
Decomposition of Cellulose and Glucose in Hot-Compressed Water under Catalyst-Free Conditions. journal January 1998
Continuous Hydrothermal Liquefaction of Biomass: A Critical Review journal November 2018
Hydrothermal carbonization of biomass residuals: a comparative review of the chemistry, processes and applications of wet and dry pyrolysis journal January 2011

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