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Chapter 10.02 - Neutron Scattering Studies of Materials for Hydrogen Storage

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Hydrogen storage presents a significant barrier to the widespread adaptation of hydrogen as an energy source in mobile and stationary applications. The development of new candidate hydrogen storage materials is therefore an outstanding goal in the field of inorganic chemistry. Neutron scattering techniques - including diffraction, inelastic, and quasielastic scattering - are integral in investigating these materials. Here, we review some of the key studies of candidate hydrogen storage materials which have employed neutron scattering techniques. We begin with a brief discussion of hydrogen's current position in the global energy landscape. Next, we provide a brief description of the theory and practical aspects of the neutron scattering techniques germane to the study of hydrogen storage. Then we enumerate the neutron scattering studies of candidate hydrogen storage materials, including metal hydrides, chemical hydrides, and porous compounds. We focus on the studies which helped develop our understanding of hydrogen storage by revealing the underlying fundamental physics and chemistry of hydrogen sorption in these systems. Finally, we provide an outlook to the future of hydrogen storage research.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Hydrogen and Fuel Cell Technologies Office (EE-3F)
DOE Contract Number:
AC36-08GO28308
OSTI ID:
1825672
Report Number(s):
NREL/CH-5900-78964; MainId:32881; UUID:f9c6b16d-99ba-4dc2-8221-15959c643eae; MainAdminID:20001
Country of Publication:
United States
Language:
English

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Role of Exposed Metal Sites in Hydrogen Storage in MOFs journal July 2008
Fundamentals of H 2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H 2 Production and Storage journal October 2007
Erratum to: Hydrogen technologies for energy storage: A perspective journal July 2020
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A Neutron Diffraction Study of Palladium Hydride journal June 1971
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Record High Hydrogen Storage Capacity in the Metal–Organic Framework Ni 2 ( m -dobdc) at Near-Ambient Temperatures journal October 2018
Quasielastic neutron scattering study of hydrogen motion in C 15 − type HfMo 2 H 0.26 journal December 2000
Direct measurement of the translational mobility of deuterium hydride molecules confined in a model microporous material: AlPO 4 -5 zeolite journal December 1996
Nanoconfined hydrides for energy storage journal January 2011
The current status of hydrogen storage in metal–organic frameworks journal January 2008
Hydrogen storage properties and neutron scattering studies of Mg2(dobdc)—a metal–organic framework with open Mg2+ adsorption sites journal January 2011
Review of hydrogen storage techniques for on board vehicle applications journal November 2013
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Neutron powder diffraction – new opportunities in hydrogen location in molecular and materials structure journal March 2014
Hydrogen storage in different carbon nanostructures journal April 2002
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Optimum Conditions for Adsorptive Storage journal February 2006
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Hydrogen dynamics in β-Mg(BH 4 ) 2 on the picosecond timescale journal January 2016
Hydrogen storage in Pd nanocrystals covered with a metal–organic framework journal July 2014
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Hydrogen-storage materials for mobile applications journal November 2001
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A panoramic overview of hydrogen storage alloys from a gas reaction point of view journal December 1999
Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials journal September 2008
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An In-Situ Neutron Diffraction and DFT Study of Hydrogen Adsorption in a Sodalite-Type Metal-Organic Framework, Cu-BTTri : An journal January 2019
Interstitial site occupation in α-LaNi5-H studied by deep inelastic neutron scattering journal May 1997
Slow Neutron Scattering by Molecular Hydrogen and Deuterium journal August 1964
Exceptional H2 Saturation Uptake in Microporous Metal−Organic Frameworks journal March 2006
Quantitative analysis of UH 3 in U metal and UO 2 matrices by neutron vibrational spectroscopy journal December 2002
Structural evolution of ammonia borane for hydrogen storage journal March 2008
Structure and hydrogen bonding in CaSiD 1 + x : Issues about covalent bonding journal December 2006
Hydrogen Adsorption in the Ti-Doped Mesoporous Silicate SBA-15 journal August 2009
The crystal structure of LaNi 5 D 7 journal June 1986
Hydrogen mobility in the lightest reversible metal hydride, LiBeH3 journal November 2017
The distribution of the deuterium atoms in the deuterated hexagonal laves-phase ZrMn2D3 journal July 1979
Adsorption of Hydrogen in Ca-Exchanged Na-A Zeolites Probed by Inelastic Neutron Scattering Spectroscopy journal January 1996
High-capacity hydrogen storage in lithium and sodium amidoboranes journal December 2007
Hydrogen Clusters in Clathrate Hydrate journal September 2002
Dihydrogen Complexation journal March 2016
Interplay of magnetic and hydrogen ordering in the hexagonal Laves hydrides journal September 2002
Thermal decomposition of complex metal hydrides journal June 1972
A neutron scattering study of hydrogen dynamics in coarse-grained and nanostructured ZrCr 2 H 3 journal January 2011
In Situ Neutron Diffraction Study of the Deuteration of Isotopic Mg 11 B 2 journal October 2011
Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage journal January 2006
Recent progress in hydrogen storage journal December 2008
Hindered Rotational Energy Barriers of BH 4 Tetrahedra in β-Mg(BH 4 ) 2 from Quasielastic Neutron Scattering and DFT Calculations journal January 2012
Liquid-Like Hydrogen Stored in Nanoporous Materials at 50 K Observed by in Situ Neutron Diffraction Experiments journal February 2013
Hydrogen Storage Properties of Rigid Three-Dimensional Hofmann Clathrate Derivatives:  The Effects of Pore Size journal May 2008
High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites journal February 2009
Structural ordering and dynamics of LaH3−x journal December 1999
An Azine-Linked Covalent Organic Framework: Synthesis, Characterization and Efficient Gas Storage journal July 2015
Structure and Dynamics of Hydrogen Molecules in the Novel Clathrate Hydrate by High Pressure Neutron Diffraction journal September 2004
Theoretical Limits of Hydrogen Storage in Metal–Organic Frameworks: Opportunities and Trade-Offs journal August 2013
Diffusivity of hydrogen and methane molecules in A zeolites: Neutron scattering measurements and comparison journal March 1992
Hydrogen storage in mechanically milled Mg–LaNi5 and MgH2–LaNi5 composites journal February 2000
Ammonia–Borane and Amine–Borane Dehydrogenation Mediated by Complex Metal Hydrides journal April 2016
Toward New Candidates for Hydrogen Storage:  High-Surface-Area Carbon Aerogels journal December 2006
Zeolite-Templated Carbon Materials for High-Pressure Hydrogen Storage journal June 2012
Molecular Level Control of the Capacitance of Two-Dimensional Covalent Organic Frameworks: Role of Hydrogen Bonding in Energy Storage Materials journal January 2017
Mixed-metal (Li, Al) amidoborane: synthesis and enhanced hydrogen storage properties journal January 2013
Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen storage materials journal May 1997
Synthesis of ultrafine titanium aluminide powders and their catalytic enhancement in dehydrogenation kinetics of NaAlH4 journal January 2007
Vibrations of hydrogen and deuterium in solid solution with lutetium journal August 1994
Amidoboranes and hydrazinidoboranes: State of the art, potential for hydrogen storage, and other prospects journal November 2020
Structure and phase relations in metal hydrides studied by neutron diffraction journal November 1982
The structure, thermal properties and phase transformations of the cubic polymorph of magnesium tetrahydroborate journal January 2012
Pressure induced structural changes in the potential hydrogen storage compound ammonia borane: A combined X-ray, neutron and theoretical investigation journal August 2010
Dynamical Perturbations of Tetrahydroborate Anions in LiBH 4 due to Nanoconfinement in Controlled-Pore Carbon Scaffolds journal August 2013
Size effects on the hydrogen storage properties of nanoscaffolded Li 3 BN 2 H 8 journal April 2009
NaBH 4 in “Graphene Wrapper:” Significantly Enhanced Hydrogen Storage Capacity and Regenerability through Nanoencapsulation journal July 2015
Structure Determination of a Low Temperature Phase of Calcium and Strontium Amide by means of Neutron Powder Diffraction on Ca(ND2)2 and Sr(ND2)2 journal December 1999
Evolution of the Reorientational Motions of the Tetrahydroborate Anions in Hexagonal LiBH 4 –LiI Solid Solution by High- Q Quasielastic Neutron Scattering journal May 2013
Transition Metal Complexation ofσ Bonds journal June 1993
Recent advances and remaining challenges of nanostructured materials for hydrogen storage applications journal July 2017
Neutron Scattering from a Liquid on a Jump Diffusion Model journal February 1961
Capture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites journal March 2017
Electronic factors determining the reactivity of metal surfaces journal December 1995
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal September 1976
A New Polymer Nanoprobe Based on Chemiluminescence Resonance Energy Transfer for Ultrasensitive Imaging of Intrinsic Superoxide Anion in Mice journal March 2016
Covalent Si–H Bonds in the Zintl Phase Hydride CaSiH1+x (x ≤ 1/3) journal August 2019
Hydrogen in the Metal−Organic Framework Cr MIL-53 journal May 2010
Synthesis and Crystal Structure of BaLaSi 2 H 0.80 journal June 2020
M2(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal–Organic Frameworks Exhibiting Increased Charge Density and Enhanced H2 Binding at the Open Metal Sites
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Local Structure of Framework Cu(II) in HKUST-1 Metallorganic Framework:  Spectroscopic Characterization upon Activation and Interaction with Adsorbates journal March 2006
Investigating H 2 Sorption in a Fluorinated Metal–Organic Framework with Small Pores Through Molecular Simulation and Inelastic Neutron Scattering journal February 2015
Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks journal March 2007
Crystal structures and phase transformations in Ca(BH4)2 journal February 2009
High-pressure synthesis and crystal structures of new ternary caesium magnesium hydrides, CsMgH3, Cs4Mg3H10 and Cs2MgH4 journal January 2002
The role of hydrogen and fuel cells in the global energy system journal January 2019
Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels journal May 2013
Dynamics of hydrogen in α- LaNi 5 hydride investigated by neutron scattering journal July 1994
Synergistic effects of co-dopants on the dehydrogenation kinetics of sodium aluminum hydride journal April 2005
Lithium boro-hydride LiBH4 journal November 2002
The synthesis and hydrogen storage properties of a MgH 2 incorporated carbon aerogel scaffold journal April 2009
Phase stability and neutron diffraction studies of Laves phases Zr(Cr1−M )2 with M = Mn, Fe, Co, Ni, Cu and 0 < x < 0.2 and their hydrides journal March 1995
Calcium Amidotrihydroborate: A Hydrogen Storage Material journal December 2007
Magnesium Imide: Synthesis and Structure Determination of an Unconventional Alkaline Earth Imide from Decomposition of Magnesium Amide journal December 2010
Hydrogen adsorption in HKUST-1: a combined inelastic neutron scattering and first-principles study journal April 2009
Kristallstruktur des Natriumamids journal March 1956
Theoretical Aspects of a Novel Mode of Hydrogen-Hydrogen Bonding journal October 1995
Structure of the high pressure phase γ-MgH2 by neutron powder diffraction journal June 1999
Thermodynamic stability of hydrogen clathrates journal December 2003
Dihydrogen in zeolite CaX—An inelastic neutron scattering study journal October 2007
Crystal Chemistry of Perovskite-Type Hydride NaMgH 3 : Implications for Hydrogen Storage journal February 2008
Characterization of H2 Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering
  • Rowsell, Jesse L. C.; Eckert, Juergen; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 127, Issue 42, p. 14904-14910 https://doi.org/10.1021/ja0542690
journal October 2005
Molecular hydrogen complexes: coordination of a .sigma. bond to transition metals journal March 1988
The vibrational excitations and the position of hydrogen in nanocrystalline palladium journal January 1995
A quasielastic and inelastic neutron scattering study of the alkaline and alkaline-earth borohydrides LiBH 4 and Mg(BH 4 ) 2 and the mixture LiBH 4 + Mg(BH 4 ) 2 journal January 2019
Hydrogen diffusion in bulk and nanocrystalline palladium: A quasielastic neutron scattering study journal August 2016
The Preparation and Properties of Hexamminecobalt(III) Borohydride, Hexamminechromium(III) Borohydride and Ammonium Borhydride 1 journal January 1958
Structure and microdomain structure of ordered niobium hydrides and deuterides by means of neutron scattering journal May 1997
Structures of transition metal hydrides determined by neutron diffraction journal June 1997
Nanoconfinement and Catalytic Dehydrogenation of Ammonia Borane by Magnesium‐Metal–Organic‐Framework‐74 journal April 2011
Raman studies of hydrogen adsorbed on nanostructured porous materials journal January 2008
Organic aerogels from the polycondensation of resorcinol with formaldehyde journal September 1989
Review of polymers of intrinsic microporosity for hydrogen storage applications journal October 2016
The magnetic susceptibility of Pd, PdH and PdD between 4 and 300 K journal March 1972
The Direct Synthesis of Na 3 AlH 6 journal September 1966
Neutron diffraction structure determination of NaAlD4 journal August 2003
Study of the N−H···H−B Dihydrogen Bond Including the Crystal Structure of BH 3 NH 3 by Neutron Diffraction journal July 1999
Neutron diffraction study of deuterium ordering in C15 type TaV2Dx (x>1) in the temperature range of 1.5–295 K journal May 1997
Observation of Molecular H 2 Chemisorption on a Nickel Surface journal October 1986
The potential of organic polymer-based hydrogen storage materials journal January 2007
Hydrogen carriers journal October 2016
An in situ neutron diffraction measurement of the pressure–temperature evolution of a MgD 2 :TiD 2 mixture journal December 2010
Concentration and temperature dependence of hydrogen vibrations along the c axis for hydrogen in yttrium: Evidence of dynamically coupled hydrogen pairs journal March 1988
Microstructures and hydrogen storage properties of La Ni Fe V Mn alloys journal November 2017
Hydrogen diffusion in β-LaNi5 hydride journal September 1980
Neutron diffraction study of the LaNi5–D system during activation journal December 1999
Hydrogen order in monoclinic ZrCr2H3.8 journal June 1999
Hydrogen Rotational and Translational Diffusion in Calcium Borohydride from Quasielastic Neutron Scattering and DFT Calculations journal November 2010
Direct hydrogenation of magnesium boride to magnesium borohydride: demonstration of >11 weight percent reversible hydrogenstorage journal January 2010
Study of H2 confined in the highly ordered pores of MCM-48 journal August 2003
In silico screening of carbon-capture materials journal May 2012
A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n journal February 1999
Local-mode dynamics in YH 2 and YD 2 by isotope-dilution neutron spectroscopy journal December 1994
Changes in magnetic properties of C15 Laves compound RCo2 due to hydrogenation journal February 1999
Alanat-Synthese aus den Elementen und ihre Bedeutung journal May 1961
Etude structurale du systeme Mg2NiH2 journal September 1984
Isotope dilution neutron spectroscopy: a vibrational probe of hydrogen/deuterium adsorbate interactions on palladium black journal March 1988
Solid‐State NMR Spectroscopy: A Powerful Technique to Directly Study Small Gas Molecules Adsorbed in Metal–Organic Frameworks journal November 2018
Novel hydrogen storage materials: A review of lightweight complex hydrides journal August 2010
Dynamics of porous and amorphous magnesium borohydride to understand solid state Mg-ion-conductors journal June 2020
Low temperature structure of Mg2NiD4: A combined study of high resolution X-ray and neutron diffraction journal February 1987
Complex and liquid hydrides for energy storage journal March 2016
Theory for superconductivity in Pd-H and Pd-D systems journal October 1973
Thermal decomposition of B–N–H compounds investigated by using combined thermoanalytical methods journal August 2002
Regeneration of sodium alanate studied by powder in situ neutron and synchrotron X-ray diffraction journal January 2014
Characterization of the structure of YD3 by neutron powder diffraction journal April 1996
Unit-cell refinement from powder diffraction scans journal December 1981
Influence of hydrogen absorption on magnetic ordering in some zirconium-based Laves phase compounds journal November 1982
Reorientational Hydrogen Dynamics in Complex Hydrides with Enhanced Li + Conduction journal August 2017
Determination of the hydrogen absorption sites in Zn4O(1,4-benzenedicarboxylate) by single crystal neutron diffraction journal January 2006
Temperature dependent neutron powder diffraction study of the Laves phase compound TbCo2 journal March 2005
Raman spectra of hydrogen and deuterium adsorbed on a metal–organic framework journal August 2005
Thermodynamical stability of calcium borohydride Ca ( B H 4 ) 2 journal October 2006
Techno-economic, environmental, and safety assessment of hydrogen powered community microgrids; case study in Canada journal May 2017
Diffusion of H 2 adsorbed on single-walled carbon nanotubes journal May 2003
Hydrogen mobility in LaNi5 hydride and its aluminium-and manganese-substituted hydrides journal November 1982
Crystal structures and phase transformation of deuterated lithium imide, Li2ND journal August 2006
Inelastic neutron scattering study of hydrogen in d8-THF∕D2O ice clathrate journal October 2007
Design and Synthesis of Vanadium Hydrazide Gels for Kubas-Type Hydrogen Adsorption: A New Class of Hydrogen Storage Materials journal August 2010
Tetrahedral occupancy in the Pd-D system observed by in situ neutron powder diffraction journal November 2003
First-Principles Prediction of a Ground State Crystal Structure of Magnesium Borohydride journal March 2008
Correlations between the structural properties, the stability and the hydrogen content of substituted LaNi5 compounds journal July 1985
Quasielastic neutron scattering of –NH3 and –BH3 rotational dynamics in orthorhombic ammonia borane journal June 2008
Magnetic structure of β − Er D 2 : Long-range and short-range order from powder neutron diffraction journal February 2005
On the reversibility of hydrogen storage in Ti- and Nb-catalyzed Ca(BH4)2 journal June 2008
Scorpionate-Type Coordination in MFU-4 l Metal-Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites journal May 2014
Hydrogen adsorption in a copper ZSM5 zeoliteAn inelastic neutron scattering study journal February 2007
Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks journal February 2008
Inelastic Neutron Scattering Study of the Activation of Molecular Hydrogen in Silver-Exchanged A Zeolite:  First Step in the Reduction to Metallic Silver at Low Temperature journal May 2004
Crystal and electronic structures of LiNH2 journal January 2006
The catalyzed hydrogen sorption mechanism in alkali alanates journal January 2015
Monoammoniate of Calcium Amidoborane: Synthesis, Structure, and Hydrogen-Storage Properties journal January 2012
Clathrate hydrates journal July 1993
Structure and dynamics of hydrogen sorption in mesoporous MCM-41
  • Edler, Karen J.; Reynolds, Phillip A.; Branton, Peter J.
  • Journal of the Chemical Society, Faraday Transactions, Vol. 93, Issue 8 https://doi.org/10.1039/a607878h
journal January 1997
Lithium amidoborane hydrazinates: synthesis, structure and hydrogen storage properties journal January 2015
Ammonia borane, a material with exceptional properties for chemical hydrogen storage journal April 2017
Hydrogen storage in clathrate hydrates: Current state of the art and future directions journal June 2014
Neutron diffraction in Ti1.2Mn1.8 deuteride: Structural and magnetic aspects journal June 1984
Vibrational Spectra of Ca(BH 4 ) 2 journal July 2008
Adsorption and melting of hydrogen in potassium-intercalated graphite journal February 2009
Hydrogen on metal surfaces: Forever young journal April 2012
Nuclear magnetic resonance studies of hydrogen diffusion in LaNi 5.0 H 6.0 and LaNi 4.8 Sn 0.2 H 5.8 journal June 1998
Room temperature isosteric heat of dihydrogen adsorption on Cu(I) cations in zeolite ZSM-5 journal November 2007
Neutron Powder Diffraction Study of D 2 Sorption in Cu 3 (1,3,5-benzenetricarboxylate) 2 journal December 2006
The crystal structure of LiND2 and Mg(ND2)2 journal January 2007
Structural Studies of Deuteration and Dedeuteration of Li 3 N by Use of In Situ Neutron Diffraction journal July 2007
Crystal Chemistry and Dehydrogenation/Rehydrogenation Properties of Perovskite Hydrides RbMgH 3 and RbCaH 3 journal July 2009
Understanding the H 2 Sorption Trends in the M-MOF-74 Series (M = Mg, Ni, Co, Zn) journal December 2014
Quasielastic neutron scattering studies of H motion in Laves-phase compounds journal December 2002
Advanced carbon aerogels for energy applications journal January 2011
Methane Storage in Paddlewheel-Based Porous Coordination Cages journal August 2018
Correlation between thermodynamical stabilities of metal borohydrides and cation electronegativites: First-principles calculations and experiments journal July 2006
Anomalous hydrogen dynamics in rare earth metals journal August 1991
Computational study of molecular hydrogen in zeolite Na–A. II. Density of rotational states and inelastic neutron scattering spectra journal June 2001
Pore size analysis of >250 000 hypothetical zeolites journal January 2011
Understanding Gas Storage in Cuboctahedral Porous Coordination Cages journal July 2019
Quasielastic neutron scattering study of hydrogen motion in C14- and C15-type ZrCr 2 H x journal January 1999
Structural studies of lithium zinc borohydride by neutron powder diffraction, Raman and NMR spectroscopy journal September 2011
Liquid Organic Hydrogen Carriers (LOHCs): Toward a Hydrogen-free Hydrogen Economy journal December 2016
2H nuclear magnetic resonance spectroscopy of deuterium adsorption on single-walled carbon nanotubes journal March 2004
Neutron diffraction studies of the cubic ZrCr2Dx and ZrV2Dx (Hx) PHASES journal September 1980
Determination of the crystal structure of Mg(AlH4)2 by combined X-ray and neutron diffraction journal January 2005
Chemical Reactions followed by in situ Neutron Powder Diffraction: Chemical Reactions followed by in situ Neutron Powder Diffraction journal October 2014
NMR spectroscopy of hydrogen adsorption on single-walled carbon nanotubes after exposure to high pressure journal February 2006
Technical assessment of compressed hydrogen storage tank systems for automotive applications journal February 2011
Structural aspects of ternary metal hydrides: A critical review journal November 1984
Observation of Cu2+–H2 Interactions in a Fully Desolvated Sodalite-Type Metal–Organic Framework journal February 2007
Hydrogen adsorption on an open metal surface: H 2 / Pd ( 210 ) journal February 2002
Neutron diffraction investigation of preferred site occupation in several CaCu5-type compounds of cerium journal April 1995
Neutron scattering lengths and cross sections journal January 1992
Hydrogenation Properties of Laves Phases LnMg 2 (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er, Tm, Yb) journal November 2017
Diffusion of Binary CO 2 /CH 4 Mixtures in the MIL-47(V) and MIL-53(Cr) Metal–Organic Framework Type Solids: A Combination of Neutron Scattering Measurements and Molecular Dynamics Simulations journal May 2013
Neutron-scattering study of the nuclear and magnetic structure of DyD 3 and associated vibrational and magnetic excitations journal May 1999
Site-Specific CO2 Adsorption and Zero Thermal Expansion in an Anisotropic Pore Network journal December 2011
van der Waals interactions in the ground state of Mg(BH 4 ) 2 from density functional theory journal June 2011
Hydrogen absorption and desorption properties of AB2 laves-phase pseudobinary compounds journal May 1977
Neutron diffraction study of magnesium deuteride journal May 1963
Lewis Base Complexes of Magnesium Borohydride: Enhanced Kinetics and Product Selectivity upon Hydrogen Release journal December 2017
Adsorption of two gas molecules at a single metal site in a metal–organic framework journal January 2016
Microstructure and hydrogen storage properties of a TiZrNbMoV high entropy alloy synthesized using Laser Engineered Net Shaping (LENS) journal June 2014
Insight to the Thermal Decomposition and Hydrogen Desorption Behaviors of NaNH 2 –NaBH 4 Hydrogen Storage Composite journal September 2017
Materials for hydrogen storage journal September 2003
Low-temperature deuterium ordering in the cubic Laves phase derivative α-ZrCr2D0.66 journal August 2001
Role of Metal Electronegativity in the Dehydrogenation Thermodynamics and Kinetics of Composite Metal Borohydride–LiNH 2 Hydrogen Storage Materials journal February 2018
Chemistry of Covalent Organic Frameworks journal November 2015
A new study of the structure of LaNi5D6.7 using a modified Rietveld method for the refinement of neutron powder diffraction data journal February 1987
High-Pressure Compounds in Methane-Hydrogen Mixtures journal March 1996
Observation of a Pake doublet in the H 1 nuclear-magnetic-resonance spectrum of CeNiInH x journal April 1993
Dihydrogen Bonds in Aqueous NaBD 4 Solution by Neutron and X-ray Diffraction journal February 2020
The design of a bismuth-based auxiliary filter for the removal of spurious background scattering associated with filter-analyzer neutron spectrometers
  • Udovic, T. J.; Brown, C. M.; Leão, J. B.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 588, Issue 3 https://doi.org/10.1016/j.nima.2008.02.006
journal April 2008
Mapping trends in the reorientational mobilities of tetrahydroborate anions via neutron-scattering fixed-window scans journal December 2013
Structural variations and hydrogen storage properties of Ca5Si3 with Cr5B3-type structure journal July 2008
Organic aerogels: microstructural dependence of mechanical properties in compression journal November 1990
Gas adsorption in an isostructural series of pillared coordination cages journal January 2018
Experimental and computational studies on collective hydrogen dynamics in ammonia borane: Incoherent inelastic neutron scattering journal January 2009
Powder diffraction methods for studies of borohydride-based energy storage materials journal December 2010
Hydrogen Adsorption in a Highly Stable Porous Rare-Earth Metal-Organic Framework: Sorption Properties and Neutron Diffraction Studies journal July 2008
Rapid low-temperature hopping of hydrogen in a pure metal: The ScH x system journal September 1990
Ordered arrangement of proton pairs in the PrNiIn H 1.29 system journal June 1996
Formation of Ca(BH 4 ) 2 from Hydrogenation of CaH 2 +MgB 2 Composite journal February 2008
Hydrogen in Ti3Sb and Ti2Sb: Neutron vibrational spectroscopy and neutron diffraction studies journal April 2010
Direct Observation of Hydrogen Molecules Adsorbed onto a Microporous Coordination Polymer journal January 2005
Tailoring Thermodynamics and Kinetics for Hydrogen Storage in Complex Hydrides towards Applications journal December 2015
Hydrogen storage using physisorption – materials demands journal May 2001
Magnetic Susceptibility and Equilibrium Diagram of PdH n journal January 1973
Etude structurale du systeme Mg2NiH2 I - La solution solide Mg2NiHx (x=0, 30) journal July 1984
Influence of hydrogen on the magnetic properties of SmCo5 journal June 1969
Syntheses, crystal structures, and thermal analyses of solvent-free Ca(AlD4)2 and CaAlD5 journal November 2009
Hydrogen energy, economy and storage: Review and recommendation journal June 2019
Diffusivity of the deuterated hydrogen molecule HD in NaA zeolite by neutron scattering experiment. Comparison with H 2 in NaA journal January 1992
Metal borohydrides and derivatives – synthesis, structure and properties journal January 2017
Hydrogen dynamics in the low temperature phase of LiBH4 probed by quasielastic neutron scattering journal December 2013
Metal−Organic Polyhedral Frameworks: High H 2 Adsorption Capacities and Neutron Powder Diffraction Studies journal March 2010
Hydrogen Storage in Metal-Organic Frameworks: A Review journal May 2014
Dynamics of Hydroxyl Anions Promotes Lithium Ion Conduction in Antiperovskite Li 2 OHCl journal September 2020
Simplified mechano-synthesis procedure of Mg2NiH4 journal March 2012
Slow Diffusion of Molecular Hydrogen in Zeolite 13X journal November 2002
Structures and Crystal Chemistry of Li 2 BNH 6 and Li 4 BN 3 H 10 journal February 2008
Influence of nano-confinement on the thermodynamics and dehydrogenation kinetics of metal hydrides journal April 2011
High-resolution inelastic neutron scattering and neutron powder diffraction study of the adsorption of dihydrogen by the Cu(II) metal–organic framework material HKUST-1 journal December 2013
The Nature of BH 4 Reorientations in Hexagonal LiBH 4 journal December 2011
Highly Effective Hydrogen Isotope Separation in Nanoporous Metal–Organic Frameworks with Open Metal Sites: Direct Measurement and Theoretical Analysis journal December 2013
A new hexagonal Laves phase deuteride CeMn1.5Al0.5Dx (0<<4) journal June 2000
Dynamical properties and temperature induced molecular disordering of LiBH 4 and LiBD 4 journal September 2008
Inelastic neutron scattering study of the hydrogenated ( Zr 55 Cu 30 Ni 5 Al 10 ) 99 Y 1 bulk metallic glass journal May 2011
Hydrogen storage properties of LiBH4 journal August 2003
Neutron-diffraction observations on the palladium-hydrogen and palladium-deuterium systems journal January 1957
Structure of the novel ternary hydrides Li 4 Tt 2 D ( Tt = Si and Ge) journal January 2007
Materials for hydrogen storage: structure and dynamics of borane ammonia complex journal January 2008
Hydrocarbon Adsorption in the Flexible Metal Organic Frameworks MIL-53(Al, Cr) journal December 2008
LiBH4 a new hydrogen storage material journal May 2003
A Metal−Organic Framework with Entatic Metal Centers Exhibiting High Gas Adsorption Affinity journal September 2006
Glass transition and positional ordering of hydrogen in bulk and nanocrystalline palladium journal August 2015
Hydrogen Storage in the Dehydrated Prussian Blue Analogues M 3 [Co(CN) 6 ] 2 (M = Mn, Fe, Co, Ni, Cu, Zn) journal May 2005
A neutron diffraction investigation of the LaNi5D phase diagram journal December 1994
An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage journal January 2018
Hydrides formed from intermetallic compounds of two transition metals: a special class of ternary alloys journal September 1982
First-Principles Determination of the Structure of Magnesium Borohydride journal December 2012
Structure of Ternary Imide Li 2 Ca(NH) 2 and Hydrogen Storage Mechanisms in Amide−Hydride System journal May 2008
Electronic structure and Rietveld refinement parameters of Ti-doped sodium alanates journal July 2004
Nanoscaffold Mediates Hydrogen Release and the Reactivity of Ammonia Borane journal June 2005
In situ synchrotron diffraction studies of phase transitions and thermal decomposition of Mg(BH4)2 and Ca(BH4)2 journal January 2007
Boron–nitrogen–hydrogen (BNH) compounds: recent developments in hydrogen storage, applications in hydrogenation and catalysis, and new syntheses journal January 2012
Time-of-flight neutron powder diffraction study of the LaNi5D3 structure journal October 1988
Quasielastic neutron scattering study of hydrogen motion in C15-type journal March 1998
Dihydrogen vs. hydrogen bonding in the solvation of ammonia borane by tetrahydrofuran and liquid ammonia journal January 2018
Hydrogen adsorption in different carbon nanostructures journal August 2005
Hydrogen Pairing and Anisotropic Potential for Hydrogen Isotopes in Yttrium journal December 1986
Evidence for Chemisorbed Molecular Hydrogen in Fe-ZSM5 from Inelastic Neutron Scattering journal July 2001
Introduction to Metal–Organic Frameworks journal September 2011
Neutron powder diffraction and magnetic phase diagram of RCo4Ga compounds (R=Y and Pr) journal November 2002
Hydrogen adsorption in the metal–organic frameworks Fe2(dobdc) and Fe2(O2)(dobdc) journal January 2012
Hydrogen Storage in Microporous Metal-Organic Frameworks journal May 2003
Potential-energy surface for H 2 dissociation over Pd(100) journal February 1996
Dynamics of Atomic Hydrogen in Palladium Probed by Neutron Spectroscopy journal May 2020
Elaboration, Structures, and Phase Transitions for YFe2DxCompounds (x=1.3, 1.75, 1.9, 2.6) Studied by Neutron Diffraction journal January 1999
Structural and spectroscopic studies on the alkali borohydrides MBH4 (M = Na, K, Rb, Cs) journal July 2004
Structural Studies of Hydrogen Storage Materials with Neutron Diffraction: A Review journal May 2020
Synthesis and Characterization of a New Ternary ImideLi 2 Ca(NH) 2 journal December 2006
The distribution of the deuterium atoms in the deuterated cubic laves-phase ZrV2D4·5 journal December 1979
Strategies for the Improvement of the Hydrogen Storage Properties of Metal Hydride Materials journal October 2008
Neutron scattering and hydrogenous materials journal January 2006
Orientational order and rotational dynamics of the amide ions in potassium amide. II. Quasielastic neutron scattering journal September 1998
Comments on the structure ambiguity of cubic Mg2NiH4 as found by neutron powder diffraction analysis journal April 1986
Superconductivity in Palladium Hydride Systems journal May 2020
Neutron-scattering studies on the vibrational excitations and the structure of ordered niobium hydrides: The ɛ phase journal May 1998
Hydrogen storage properties of clathrate hydrate materials journal December 2007
Enhanced hydrogen storage capacity in carbon aerogels treated with KOH journal July 2009
X-ray/neutron diffraction studies and ab initio electronic structure of CeMgNi4 and its hydride journal November 2009
Neutron spectroscopic evidence of concentration-dependent hydrogen ordering in the octahedral sublattice of β- TbH 2 + x journal September 1994
Investigation of the perovskite related structures of NaMgH3, NaMgF3 and Na3AlH6 journal March 2000
Natural zeolites as effective adsorbents in water and wastewater treatment journal January 2010
Hydrogen Storage in Microporous Hypercrosslinked Organic Polymer Networks journal April 2007
Carbon-hydrogen and hydrogen-hydrogen activation in transition metal complexes and on surfaces journal April 1984
A new family of metal borohydride ammonia borane complexes: Synthesis, structures, and hydrogen storage properties journal January 2010
Hydrogen vibrational modes and anisotropic potential in α - ScH x journal February 1990
Insight into Mg(BH 4 ) 2 with Synchrotron X-ray Diffraction: Structure Revision, Crystal Chemistry, and Anomalous Thermal Expansion journal March 2009
Boron-based hydrides for chemical hydrogen storage: Boron-based hydrolytic and thermolytic hydrides journal March 2013
Etude structurale du system Mg2NiH2: II — La variete haute temperature de Mg2NiH4 de symetrie cubique journal August 1984
Alkali and Alkaline-Earth Metal Amidoboranes: Structure, Crystal Chemistry, and Hydrogen Storage Properties journal November 2008
Structure and Dynamics of Borohydrides Studied by Neutron Scattering Techniques: A Review journal May 2020
Raman spectroscopic studies of hydrogen clathrate hydrates journal January 2009
McPhy-Energy’s proposal for solid state hydrogen storage materials and systems journal December 2013
The H-Pd (hydrogen-palladium) System journal February 1994
Hydrogen storage and carbon dioxide capture in an iron-based sodalite-type metal–organic framework (Fe-BTT) discovered via high-throughput methods journal January 2010
Critical Factors Driving the High Volumetric Uptake of Methane in Cu 3 (btc) 2 journal August 2015
New Developments in the Chemistry of Diborane and the Borohydrides. I. General Summary 1 journal January 1953
Metal-Hydrogen Systems in the High Pressure Range journal January 1979
High Surface Area Nanoporous Polymers for Reversible Hydrogen Storage journal September 2006
Switendick criterion for stable hydrides journal May 1985
Hydrogen Storage In A Novel Destabilized Hydride System, Ca 2 SiH x :  Effects of Amorphization journal December 2006
Porous metal-organic frameworks for gas storage and separation: Status and challenges journal July 2019
Hydrogen Storage in the Giant-Pore Metal–Organic Frameworks MIL-100 and MIL-101 journal December 2006
Structural studies of the hydrogen storage material Mg2NiH4. 1. Cubic high-temperature structure journal September 1981
The localization of benzene in a Y-zeolite journal January 1985
High-pressure synthesis and structural characterization of Na1-K MgH3 perovskite hydrides journal December 2017
Kristallstruktur von CaZn5 und CaCu5 journal May 1940
Activation of single-bond cleavage processes on metal surfaces: a comparison of dissociative hydrogen adsorption with simple gas-phase exchange reactions journal March 1984
Rotational Motion in LiBH 4 /LiI Solid Solutions journal June 2011
Hydrogen cycling behavior of zirconium and titanium–zirconium-doped sodium aluminum hydride journal June 1999
Sodium Borohydride, Its Hydrolysis and its Use as a Reducing Agent and in the Generation of Hydrogen 1 journal January 1953
Uranium(IV) Borohydride 1 journal January 1953
Quasielastic neutron scattering study of tetrahydroborate anion dynamical perturbations in sodium borohydride due to partial halide anion substitution journal October 2015
Kinetics of hydrogen absorption and desorption by ternary LaNi5-type intermetallic compounds journal January 1979
Neubestimmung der Kristallstruktur des Lithiumamids journal August 1972
UTSA-74: A MOF-74 Isomer with Two Accessible Binding Sites per Metal Center for Highly Selective Gas Separation journal April 2016
The renaissance of hydrides as energy materials journal December 2016
Inelastic neutron scattering from the alkali metal borohydrides and calcium borohydride journal January 1976