Design nanoporous metal thin films via solid state interfacial dealloying

Zhao, Chonghang; Kisslinger, Kim; Huang, Xiaojing; Bai, Jianming; Liu, Xiaoyang; Lin, Cheng-Hung; Yu, Lin-Chieh; Lu, Ming; Tong, Xiao; Zhong, Hui; Pattammattel, Ajith; Yan, Hanfei; Chu, Yong; Ghose, Sanjit; Liu, Mingzhao; Chen-Wiegart, Yu-chen Karen

doi:10.1039/d1nr03709a

Design nanoporous metal thin films via solid state interfacial dealloying

Journal Article · Tue Aug 10 00:00:00 EDT 2021 · Nanoscale

DOI:https://doi.org/10.1039/d1nr03709a· OSTI ID:1823632

^[1]; Kisslinger, Kim ^[2]; Huang, Xiaojing ^[2]; Bai, Jianming ^[2]; ^[1]; ^[1]; Yu, Lin-Chieh ^[1]; Lu, Ming ^[2]; ^[2]; Zhong, Hui ^[1]; Pattammattel, Ajith ^[2]; Yan, Hanfei ^[2]; Chu, Yong ^[2]; ^[2]; ^[2]; ^[1]

Stony Brook Univ., NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Thin-film solid-state interfacial dealloying (thin-film SSID) is an emerging technique to design nanoarchitecture thin films. The resulting controllable 3D bicontinuous nanostructure is promising for a range of applications including catalysis, sensing, and energy storage. Using a multiscale microscopy approach, we combine X-ray and electron nano-tomography to demonstrate that besides dense bicontinuous nanocomposites, thin-film SSID can create a very fine (5–15 nm) nanoporous structure. Not only is such a fine feature among one of the finest fabrications by metal-agent dealloying, but a multilayer thin-film design enables creating nanoporous films on a wider range of substrates for functional applications. Through multimodal synchrotron diffraction and spectroscopy analysis with which the materials’ chemical and structural evolution in this novel approach is characterized in details, we further deduce that the contribution of change in entropy should be considered to explain the phase evolution in metal-agent dealloying, in addition to the commonly used enthalpy term in prior studies. Here, the discussion is an important step leading towards better explaining the underlying design principles for controllable 3D nanoarchitecture, as well as exploring a wider range of elemental and substrate selections for new applications.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0012704

OSTI ID:: 1823632

Alternate ID(s):: OSTI ID: 1819779

Report Number(s):: BNL--222190-2021-JAAM

Journal Information:: Nanoscale, Journal Name: Nanoscale Journal Issue: 42 Vol. 13; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (75)

Preparation of Nano to Submicro-Porous TiMo Foams by Spark Plasma Sintering : Preparation of Nano to Submicro-Porous TiMo Foams… Zhang, Faming; Wang, Lili; Li, Ping Advanced Engineering Materials, Vol. 19, Issue 2 https://doi.org/10.1002/adem.201600600	journal	November 2016
Beating Thermal Coarsening in Nanoporous Materials via High‐Entropy Design Joo, Soo‐Hyun; Bae, Jae Wung; Park, Won‐Young Advanced Materials, Vol. 32, Issue 6 https://doi.org/10.1002/adma.201906160	journal	December 2019
Sample Preparation of Energy Materials for X-ray Nanotomography with Micromanipulation Chen-Wiegart, Yu-chen Karen; Camino, Fernando E.; Wang, Jun ChemPhysChem, Vol. 15, Issue 8 https://doi.org/10.1002/cphc.201400023	journal	March 2014
A novel solid-state dealloying method to prepare ultrafine ligament nanoporous Ti Shi, Yao; Lian, Lixian; Liu, Ying Applied Physics A, Vol. 125, Issue 10 https://doi.org/10.1007/s00339-019-2984-z	journal	September 2019
Diffusion Kinetics in Mg-Cu Binary System Dai, Jiahong; Jiang, Bin; Zhang, Jianyue Journal of Phase Equilibria and Diffusion, Vol. 36, Issue 6 https://doi.org/10.1007/s11669-015-0417-z	journal	October 2015
Structure/processing relationships in the fabrication of nanoporous gold Kertis, F.; Snyder, J.; Govada, Lata JOM, Vol. 62, Issue 6 https://doi.org/10.1007/s11837-010-0087-6	journal	June 2010
Alloy Design Criteria for Solid Metal Dealloying of Thin Films McCue, Ian; Demkowicz, Michael J. JOM, Vol. 69, Issue 11 https://doi.org/10.1007/s11837-017-2571-8	journal	September 2017
Nanoporous magnesium Okulov, Ilya Vladimirovich; Lamaka, Sviatlana V.; Wada, Takeshi Nano Research, Vol. 11, Issue 12 https://doi.org/10.1007/s12274-018-2167-9	journal	August 2018
Thermodynamic investigations of binary liquid and solid CuMg and MgNi alloys and ternary liquid CuMgNi alloys Feufel, H.; Sommer, F. Journal of Alloys and Compounds, Vol. 224, Issue 1 https://doi.org/10.1016/0925-8388(95)01526-4	journal	June 1995
Optimizing niobium dealloying with metallic melt to fabricate porous structure for electrolytic capacitors Kim, Joung Wook; Tsuda, Masashi; Wada, Takeshi Acta Materialia, Vol. 84 https://doi.org/10.1016/j.actamat.2014.11.002	journal	February 2015
Kinetics and morphological evolution of liquid metal dealloying McCue, Ian; Gaskey, Bernard; Geslin, Pierre-Antoine Acta Materialia, Vol. 115 https://doi.org/10.1016/j.actamat.2016.05.032	journal	August 2016
A critical review of high entropy alloys and related concepts Miracle, D. B.; Senkov, O. N. Acta Materialia, Vol. 122 https://doi.org/10.1016/j.actamat.2016.08.081	journal	January 2017
Three-dimensional bicontinuous porous graphite generated in low temperature metallic liquid Yu, Seung-Geun; Yubuta, Kunio; Wada, Takeshi Carbon, Vol. 96 https://doi.org/10.1016/j.carbon.2015.09.093	journal	January 2016
A molten Mg corrosion method for preparing porous Ti foam as self-supported Li–O2 battery cathodes Zhao, Guangyu; Zhang, Li; Niu, Yanning Electrochimica Acta, Vol. 224 https://doi.org/10.1016/j.electacta.2016.12.033	journal	January 2017
Synthesis of HCP, FCC and BCC structure alloys in the Mg–Ti binary system by means of ball milling Asano, Kohta; Enoki, Hirotoshi; Akiba, Etsuo Journal of Alloys and Compounds, Vol. 480, Issue 2 https://doi.org/10.1016/j.jallcom.2009.01.086	journal	July 2009
Kinetics of crystallization of amorphous Cu50Ti50 alloy Pratap, Arun; Lad, Kirit N.; Rao, T. Lilly Shanker Journal of Non-Crystalline Solids, Vol. 345-346 https://doi.org/10.1016/j.jnoncrysol.2004.08.018	journal	October 2004
Preparation of three-dimensional nanoporous Si using dealloying by metallic melt and application as a lithium-ion rechargeable battery negative electrode Wada, Takeshi; Yamada, Junpei; Kato, Hidemi Journal of Power Sources, Vol. 306 https://doi.org/10.1016/j.jpowsour.2015.11.079	journal	February 2016
XANES and XPS study of electronic structure of Ti-enriched Nd–Fe–B ribbons Bilovol, V.; Ferrari, S.; Derewnicka, D. Materials Chemistry and Physics, Vol. 146, Issue 3 https://doi.org/10.1016/j.matchemphys.2014.03.021	journal	August 2014
Dealloying by metallic melt Wada, Takeshi; Yubuta, Kunio; Inoue, Akihisa Materials Letters, Vol. 65, Issue 7 https://doi.org/10.1016/j.matlet.2011.01.054	journal	April 2011
Imaging of 3D morphological evolution of nanoporous silicon anode in lithium ion battery by X-ray nano-tomography Zhao, Chonghang; Wada, Takeshi; De Andrade, Vincent Nano Energy, Vol. 52 https://doi.org/10.1016/j.nanoen.2018.08.009	journal	October 2018
Nano- to submicro-porous β-Ti alloy prepared from dealloying in a metallic melt Wada, Takeshi; Setyawan, Albertus Deny; Yubuta, Kunio Scripta Materialia, Vol. 65, Issue 6 https://doi.org/10.1016/j.scriptamat.2011.06.019	journal	September 2011
Three-dimensional open-cell macroporous iron, chromium and ferritic stainless steel Wada, Takeshi; Kato, Hidemi Scripta Materialia, Vol. 68, Issue 9 https://doi.org/10.1016/j.scriptamat.2013.01.011	journal	May 2013
Evolution of a bicontinuous nanostructure via a solid-state interfacial dealloying reaction Wada, Takeshi; Yubuta, Kunio; Kato, Hidemi Scripta Materialia, Vol. 118 https://doi.org/10.1016/j.scriptamat.2016.03.008	journal	June 2016
Preparation of hierarchical porous metals by two-step liquid metal dealloying Wada, Takeshi; Geslin, Pierre-Antoine; Kato, Hidemi Scripta Materialia, Vol. 142 https://doi.org/10.1016/j.scriptamat.2017.08.038	journal	January 2018
Analysis of hydrogen absorption by Ti and Ti?6Al?4V using the ERDA technique Lopezsuarez, A. International Journal of Hydrogen Energy, Vol. 28, Issue 10 https://doi.org/10.1016/s0360-3199(02)00202-1	journal	October 2003
Tomviz: Open Source Platform Connecting Image Processing Pipelines to GPU Accelerated 3D Visualization Hanwell, Marcus D.; Harris, Christopher J.; Genova, Alessandro Microscopy and Microanalysis, Vol. 25, Issue S2 https://doi.org/10.1017/S1431927619002770	journal	August 2019
Three-Dimensional Morphological and Chemical Evolution of Nanoporous Stainless Steel by Liquid Metal Dealloying Zhao, Chonghang; Wada, Takeshi; De Andrade, Vincent ACS Applied Materials & Interfaces, Vol. 9, Issue 39 https://doi.org/10.1021/acsami.7b04659	journal	April 2017
Designing Multiscale Porous Metal by Simple Dealloying with 3D Morphological Evolution Mechanism Revealed via X-ray Nano-tomography Zou, Lijie; Ge, Mingyuan; Zhao, Chonghang ACS Applied Materials & Interfaces, Vol. 12, Issue 2 https://doi.org/10.1021/acsami.9b16392	journal	December 2019
Environmentally Friendly Zr-Based Conversion Nanocoatings for Corrosion Inhibition of Metal Surfaces Evaluated by Multimodal X-ray Analysis Liu, Xiaoyang; Vonk, Donald; Jiang, Hua ACS Applied Nano Materials, Vol. 2, Issue 4 https://doi.org/10.1021/acsanm.8b02309	journal	March 2019
Atomically Resolved Dealloying of Structurally Ordered Pt Nanoalloy as an Oxygen Reduction Reaction Electrocatalyst Pavlišič, Andraž; Jovanovič, Primož; Šelih, Vid Simon ACS Catalysis, Vol. 6, Issue 8 https://doi.org/10.1021/acscatal.6b00557	journal	July 2016
Reduced Enthalpy of Metal Hydride Formation for Mg–Ti Nanocomposites Produced by Spark Discharge Generation Anastasopol, Anca; Pfeiffer, Tobias V.; Middelkoop, Joost Journal of the American Chemical Society, Vol. 135, Issue 21 https://doi.org/10.1021/ja3123416	journal	May 2013
ALD Functionalized Nanoporous Gold: Thermal Stability, Mechanical Properties, and Catalytic Activity Biener, Monika M.; Biener, Juergen; Wichmann, Andre Nano Letters, Vol. 11, Issue 8 https://doi.org/10.1021/nl200993g	journal	August 2011
Bulk-Nanoporous-Silicon Negative Electrode with Extremely High Cyclability for Lithium-Ion Batteries Prepared Using a Top-Down Process Wada, Takeshi; Ichitsubo, Tetsu; Yubuta, Kunio Nano Letters, Vol. 14, Issue 8 https://doi.org/10.1021/nl501500g	journal	July 2014
Evolution of nanoporosity in dealloying Erlebacher, Jonah; Aziz, Michael J.; Karma, Alain Nature, Vol. 410, Issue 6827, p. 450-453 https://doi.org/10.1038/35068529	journal	March 2001
Topology-generating interfacial pattern formation during liquid metal dealloying Geslin, Pierre-Antoine; McCue, Ian; Gaskey, Bernard Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9887	journal	November 2015
Oxygen reduction in nanoporous metal–ionic liquid composite electrocatalysts Snyder, J.; Fujita, T.; Chen, M. W. Nature Materials, Vol. 9, Issue 11 https://doi.org/10.1038/nmat2878	journal	October 2010
Atomic origins of the high catalytic activity of nanoporous gold Fujita, Takeshi; Guan, Pengfei; McKenna, Keith Nature Materials, Vol. 11, Issue 9 https://doi.org/10.1038/nmat3391	journal	August 2012
Spontaneous evolution of bicontinuous nanostructures in dealloyed Li-based systems Chen, Qing; Sieradzki, Karl Nature Materials, Vol. 12, Issue 12 https://doi.org/10.1038/nmat3741	journal	August 2013
Dynamic restructuring drives catalytic activity on nanoporous gold–silver alloy catalysts Zugic, Branko; Wang, Lucun; Heine, Christian Nature Materials, Vol. 16, Issue 5 https://doi.org/10.1038/nmat4824	journal	December 2016
NIH Image to ImageJ: 25 years of image analysis Schneider, Caroline A.; Rasband, Wayne S.; Eliceiri, Kevin W. Nature Methods, Vol. 9, Issue 7 https://doi.org/10.1038/nmeth.2089	journal	June 2012
Scalable synthesis of ant-nest-like bulk porous silicon for high-performance lithium-ion battery anodes An, Weili; Gao, Biao; Mei, Shixiong Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09510-5	journal	March 2019
Dual-phase nanostructuring of layered metal oxides for high-performance aqueous rechargeable potassium ion microbatteries Li, Ying-Qi; Shi, Hang; Wang, Sheng-Bo Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12274-7	journal	September 2019
Atomic-scale phase separation induced clustering of solute atoms Zou, Lianfeng; Cao, Penghui; Lei, Yinkai Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-17826-w	journal	August 2020
Entropy contributions to phase stability in binary random solid solutions Manzoor, Anus; Pandey, Shubham; Chakraborty, Debajit npj Computational Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41524-018-0102-y	journal	August 2018
Decoupling the role of stress and corrosion in the intergranular cracking of noble-metal alloys Badwe, N.; Chen, X.; Schreiber, D. K. Nature Materials, Vol. 17, Issue 10 https://doi.org/10.1038/s41563-018-0162-x	journal	September 2018
Power generation by reverse electrodialysis in a single-layer nanoporous membrane made from core–rim polycyclic aromatic hydrocarbons Liu, Xue; He, Meng; Calvani, Dario Nature Nanotechnology, Vol. 15, Issue 4 https://doi.org/10.1038/s41565-020-0641-5	journal	March 2020
Dealloying-based interpenetrating-phase nanocomposites matching the elastic behavior of human bone Okulov, I. V.; Weissmüller, J.; Markmann, J. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-00048-4	journal	February 2017
High-throughput ab-initio dilute solute diffusion database Wu, Henry; Mayeshiba, Tam; Morgan, Dane Scientific Data, Vol. 3, Issue 1 https://doi.org/10.1038/sdata.2016.54	journal	July 2016
Nanoporous metals: fabrication strategies and advanced electrochemical applications in catalysis, sensing and energy systems Zhang, Jintao; Li, Chang Ming Chemical Society Reviews, Vol. 41, Issue 21 https://doi.org/10.1039/c2cs35210a	journal	January 2012
The phase, morphology and surface characterization of Ti–Mo alloy films prepared by magnetron sputtering Liu, Gang; Yang, Yanqing; Luo, Xian RSC Advances, Vol. 7, Issue 83 https://doi.org/10.1039/c7ra10510j	journal	January 2017
Bi-continuous pattern formation in thin films via solid-state interfacial dealloying studied by multimodal characterization Zhao, Chonghang; Kisslinger, Kim; Huang, Xiaojing Materials Horizons, Vol. 6, Issue 10 https://doi.org/10.1039/c9mh00669a	journal	January 2019
Tantalum as a diffusion barrier between copper and silicon Holloway, Karen; Fryer, Peter M. Applied Physics Letters, Vol. 57, Issue 17 https://doi.org/10.1063/1.104051	journal	October 1990
Synthesis of TiO2 nanoparticles on the Au(111) surface Biener, Jürgen; Farfan-Arribas, Enrique; Biener, Monika The Journal of Chemical Physics, Vol. 123, Issue 9 https://doi.org/10.1063/1.1999607	journal	September 2005
Kinetics of formation and coarsening of nanoporous α-titanium dealloyed with Mg melt Tsuda, Masashi; Wada, Takeshi; Kato, Hidemi Journal of Applied Physics, Vol. 114, Issue 11 https://doi.org/10.1063/1.4821066	journal	September 2013
Some observed bcc, fcc, and hcp superstructures Sluiter, M. H. F. Phase Transitions, Vol. 80, Issue 4-5 https://doi.org/10.1080/01411590701228562	journal	April 2007
Controlled ligament coarsening in nanoporous gold by annealing in vacuum versus nitrogen Sun, Ye; Burger, Sofie A.; Balk, T. John Philosophical Magazine, Vol. 94, Issue 10 https://doi.org/10.1080/14786435.2013.876113	journal	February 2014
Fabrication and characterization of hierarchically porous titanium membrane for dye wastewater treatment Duan, Yalong; Hui, Hongsen; Wang, Hong Materials Research Express, Vol. 6, Issue 11 https://doi.org/10.1088/2053-1591/ab4abe	journal	September 2019
TomoPy: a framework for the analysis of synchrotron tomographic data Gürsoy, Dogˇa; De Carlo, Francesco; Xiao, Xianghui Journal of Synchrotron Radiation, Vol. 21, Issue 5 https://doi.org/10.1107/S1600577514013939	journal	August 2014
Annealed crystallization of ultrafine amorphous NiB alloy studied by XAFS Wei, Shiqiang; Li, Zhongrui; Yin, Shilong Journal of Synchrotron Radiation, Vol. 8, Issue 2 https://doi.org/10.1107/s0909049500018070	journal	March 2001
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/s0909049505012719	journal	June 2005
Design and performance of an X-ray scanning microscope at the Hard X-ray Nanoprobe beamline of NSLS-II Nazaretski, E.; Yan, H.; Lauer, K. Journal of Synchrotron Radiation, Vol. 24, Issue 6 https://doi.org/10.1107/s1600577517011183	journal	October 2017
A pyramid approach to subpixel registration based on intensity Thevenaz, P.; Ruttimann, U. E.; Unser, M. IEEE Transactions on Image Processing, Vol. 7, Issue 1 https://doi.org/10.1109/83.650848	journal	January 1998
Contradicting Geometrical Concepts in Pore Size Analysis Attained with Electron Microscopy and Mercury Intrusion Münch, Beat; Holzer, Lorenz Journal of the American Ceramic Society, Vol. 91, Issue 12 https://doi.org/10.1111/j.1551-2916.2008.02736.x	journal	December 2008
Toward digitally controlled catalyst architectures: Hierarchical nanoporous gold via 3D printing Zhu, Cheng; Qi, Zhen; Beck, Victor A. Science Advances, Vol. 4, Issue 8 https://doi.org/10.1126/sciadv.aas9459	journal	August 2018
Enabling near-atomic–scale analysis of frozen water El-Zoka, A. A.; Kim, S. -H.; Deville, S. Science Advances, Vol. 6, Issue 49 https://doi.org/10.1126/sciadv.abd6324	journal	December 2020
Nanoporous Gold Catalysts for Selective Gas-Phase Oxidative Coupling of Methanol at Low Temperature Wittstock, A.; Zielasek, V.; Biener, J. Science, Vol. 327, Issue 5963 https://doi.org/10.1126/science.1183591	journal	January 2010
Shape regulation of high-index facet nanoparticles by dealloying Huang, Liliang; Liu, Mohan; Lin, Haixin Science, Vol. 365, Issue 6458 https://doi.org/10.1126/science.aax5843	journal	September 2019
Scaling behavior of stiffness and strength of hierarchical network nanomaterials Shi, Shan; Li, Yong; Ngo-Dinh, Bao-Nam Science, Vol. 371, Issue 6533 https://doi.org/10.1126/science.abd9391	journal	March 2021
An Atomistic Description of Dealloying Erlebacher, Jonah Journal of The Electrochemical Society, Vol. 151, Issue 10 https://doi.org/10.1149/1.1784820	journal	January 2004
Classification of Bulk Metallic Glasses by Atomic Size Difference, Heat of Mixing and Period of Constituent Elements and Its Application to Characterization of the Main Alloying Element Takeuchi, Akira; Inoue, Akihisa MATERIALS TRANSACTIONS, Vol. 46, Issue 12 https://doi.org/10.2320/matertrans.46.2817	journal	January 2005
Reaction Diffusion in Mg–Cu System Nonaka, Katsuhiko; Sakazawa, Toshiyuki; Nakajima, Hideo Materials Transactions, JIM, Vol. 36, Issue 12 https://doi.org/10.2320/matertrans1989.36.1463	journal	January 1995
Challenges and Opportunities for Integrating Dealloying Methods into Additive Manufacturing Chuang, A.; Erlebacher, J. Materials, Vol. 13, Issue 17 https://doi.org/10.3390/ma13173706	journal	August 2020
A Review of Metastable Beta Titanium Alloys Kolli, R.; Devaraj, Arun Metals, Vol. 8, Issue 7 https://doi.org/10.3390/met8070506	journal	June 2018
ImageSURF: An ImageJ Plugin for Batch Pixel-Based Image Segmentation Using Random Forests O’Mara, Aidan; King, Anna E.; Vickers, James C. Journal of Open Research Software, Vol. 5 https://doi.org/10.5334/jors.172	journal	November 2017
XAFS Studies of Amorphous Silicon Nitride Umesaki, N.; Kamijo, N.; Tanaka, I. Japanese Journal of Applied Physics, Vol. 32, Issue S2 https://doi.org/10.7567/jjaps.32s2.649	journal	January 1993

Similar Records

Oxidation Driven Thin‐Film Solid‐State Metal Dealloying Forming Bicontinuous Nanostructures

Journal Article · Mon Sep 18 20:00:00 EDT 2023 · Advanced Materials Interfaces · OSTI ID:2001145

Related Subjects

36 MATERIALS SCIENCE
Porous
dealloying
entropy
multimodal characterization
solid states
thin films

Design nanoporous metal thin films via solid state interfacial dealloying

Citation Formats

References (75)

Similar Records

Related Subjects