Assessment of Plant and Microalgal Oil-Derived Nonisocyanate Polyurethane Products for Potential Commercialization

Dong, Tao; Dheressa, Ermias; Wiatrowski, Matthew; Pereira, Andre Prates; Zeller, Ashton; Laurens, Lieve M. L.; Pienkos, Philip T.

doi:10.1021/acssuschemeng.1c03653

Assessment of Plant and Microalgal Oil-Derived Nonisocyanate Polyurethane Products for Potential Commercialization

Journal Article · Wed Sep 15 00:00:00 EDT 2021 · ACS Sustainable Chemistry & Engineering

DOI:https://doi.org/10.1021/acssuschemeng.1c03653· OSTI ID:1822828

^[1]; Dheressa, Ermias ^[2]; Wiatrowski, Matthew ^[1]; Pereira, Andre Prates ^[3]; Zeller, Ashton ^[4]; ^[1]; Pienkos, Philip T. ^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States)
Intel Corporation, Phoenix, AZ (United States)
University of Bath (United Kingdom)
Algix, Meridian, MI (United States)

Green pathways for nonisocyanate polyurethane (NIPU) production have attracted increasing levels of interest. The reaction between 5-membered cyclic carbonate and polyamines is one of the most promising pathways to produce NIPU polymers. Though promising, major technical hurdles such as slow polymerization rate and poor performance hinder the commercialization of NIPU. In this paper, we screened several commercially available triglyceride oil feedstocks for NIPU products, focusing on polymerization kinetics and product performance for industrial application. The impact of carbonated group density on polymerization rate and mechanical strength was determined. We have demonstrated a remarkably higher reactivity of carbonated oil derived from feedstocks with polyunsaturated fatty acid (PUFA). The NIPU derived from such feedstocks also showed improved performance for industrial application. Unlike traditional polyurethane foam production that uses isocyanate and water to generate CO2 as a blowing reagent, there is no gas formation in NIPU polymerization. We have demonstrated a practical and cost-effective approach to produce NIPU foam material using bicarbonate as a blowing reagent. Furthermore, we conducted the first-ever technoeconomic analysis (TEA), revealing that profitable commercial NIPU production can be achieved when operating at sufficient production capacities.

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Bioenergy Technologies Office; USDOE Office of Technology Transitions (OTT)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1822828

Report Number(s):: NREL/JA--2800-77638; MainId:29564; UUID:744fe418-1c65-40a2-996b-bcc7cdd2ae05; MainAdminID:62995

Journal Information:: ACS Sustainable Chemistry & Engineering, Journal Name: ACS Sustainable Chemistry & Engineering Journal Issue: 38 Vol. 9; ISSN 2168-0485

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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