Degradation-resistant TiO2@Sn anodes for high-capacity lithium-ion batteries

Goriparti, Subrahmanyam; Harrison, Katharine L.; Jungjohann, Katherine L.

doi:10.1007/s10853-021-06265-7

Degradation-resistant TiO₂@Sn anodes for high-capacity lithium-ion batteries

Journal Article · Mon Aug 16 00:00:00 EDT 2021 · Journal of Materials Science

DOI:https://doi.org/10.1007/s10853-021-06265-7· OSTI ID:1822245

Goriparti, Subrahmanyam ^[1]; Harrison, Katharine L. ^[1]; ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

As the demand for higher-performance batteries has increased, so has the body of research on theoretical high-capacity anode materials. However, the research has been hindered because the high-capacity anode material properties and interactions are not well understood, largely due to the difficulty of observing cycling in situ. Using electrochemical scanning transmission electron microscopy (ec-STEM), we report the real-time observation and electrochemical analysis of pristine tin (Sn) and titanium dioxide-coated Sn (TiO₂@Sn) electrodes during lithiation/delithiation. As expected, we observed a volume expansion of the pristine Sn electrodes during lithiation, but we further observed that the expansion was followed by Sn detachment from the current collector. Remarkably, although the TiO₂@Sn electrodes also exhibited similar volume expansion during lithiation, they showed no evidence of Sn detachment. We found that the TiO₂ surface layer acted as an electrochemically activated artificial solid-electrolyte interphase that serves to conduct Li ions. As a physical coating, it mechanically prevented Sn detachment following volume changes during cycling, providing significant degradation resistance and 80% Coulombic efficiency for a complete lithiation/delithiation cycle. Interestingly, upon delithiation, TiO₂@Sn electrode displayed a self-healing mechanism of small pore formation in the Sn particle followed by agglomeration into several larger pores as delithiation continued.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: NA0003525; SC0001160

OSTI ID:: 1822245

Report Number(s):: SAND--2021-11782J; 699788

Journal Information:: Journal of Materials Science, Journal Name: Journal of Materials Science Journal Issue: 30 Vol. 56; ISSN 0022-2461

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

References (44)

30 Years of Lithium-Ion Batteries Li, Matthew; Lu, Jun; Chen, Zhongwei Advanced Materials, Vol. 30, Issue 33 https://doi.org/10.1002/adma.201800561	journal	June 2018
Nanomaterials for Rechargeable Lithium Batteries Bruce, Peter G.; Scrosati, Bruno; Tarascon, Jean-Marie Angewandte Chemie International Edition, Vol. 47, Issue 16, p. 2930-2946 https://doi.org/10.1002/anie.200702505	journal	April 2008
Group IVA Element (Si, Ge, Sn)-Based Alloying/Dealloying Anodes as Negative Electrodes for Full-Cell Lithium-Ion Batteries Liu, Dequan; Liu, Zheng jiao; Li, Xiuwan Small, Vol. 13, Issue 45 https://doi.org/10.1002/smll.201702000	journal	October 2017
Si-, Ge-, Sn-Based Anode Materials for Lithium-Ion Batteries: From Structure Design to Electrochemical Performance Li, Weihan; Sun, Xueliang; Yu, Yan Small Methods, Vol. 1, Issue 3 https://doi.org/10.1002/smtd.201600037	journal	January 2017
Template-free electrochemical synthesis of tin nanostructures Mackay, David T.; Janish, Matthew T.; Sahaym, Uttara Journal of Materials Science, Vol. 49, Issue 4 https://doi.org/10.1007/s10853-013-7917-1	journal	December 2013
Tin and tin-based intermetallics as new anode materials for lithium-ion cells Wachtler, Mario; Besenhard, Jürgen O.; Winter, Martin Journal of Power Sources, Vol. 94, Issue 2 https://doi.org/10.1016/S0378-7753(00)00585-1	journal	March 2001
Porous Fe2O3 nanorods anchored on nitrogen-doped graphenes and ultrathin Al2O3 coating by atomic layer deposition for long-lived lithium ion battery anode Hu, Tao; Xie, Ming; Zhong, Jing Carbon, Vol. 76 https://doi.org/10.1016/j.carbon.2014.04.060	journal	September 2014
Artificial solid-electrolyte interphase (SEI) for improved cycleability and safety of lithium–ion cells for EV applications Menkin, S.; Golodnitsky, D.; Peled, E. Electrochemistry Communications, Vol. 11, Issue 9 https://doi.org/10.1016/j.elecom.2009.07.019	journal	September 2009
TiO2-Sn/C composite nanofibers with high-capacity and long-cycle life as anode materials for sodium ion batteries Nie, Su; Liu, Li; Liu, Junfang Journal of Alloys and Compounds, Vol. 772 https://doi.org/10.1016/j.jallcom.2018.09.044	journal	January 2019
Fast and Huge Anisotropic Diffusion of Cu (Ag) and Its Resistance on the Sn Self-diffusivity in Solid β–Sn Liu, Peitao; Wang, Shoulong; Li, Dianzhong Journal of Materials Science & Technology, Vol. 32, Issue 2 https://doi.org/10.1016/j.jmst.2015.12.007	journal	February 2016
From silver nanoparticles to thin films: Evolution of microstructure and electrical conduction on glass substrates Wei, Haoyan; Eilers, Hergen Journal of Physics and Chemistry of Solids, Vol. 70, Issue 2 https://doi.org/10.1016/j.jpcs.2008.11.012	journal	February 2009
TiO2–B nanowires as negative electrodes for rechargeable lithium batteries Armstrong, A. Robert; Armstrong, Graham; Canales, Jesus Journal of Power Sources, Vol. 146, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2005.03.057	journal	August 2005
Review on recent progress of nanostructured anode materials for Li-ion batteries Goriparti, Subrahmanyam; Miele, Ermanno; De Angelis, Francesco Journal of Power Sources, Vol. 257 https://doi.org/10.1016/j.jpowsour.2013.11.103	journal	July 2014
Tin-based anode materials with well-designed architectures for next-generation lithium-ion batteries Liu, Lehao; Xie, Fan; Lyu, Jing Journal of Power Sources, Vol. 321 https://doi.org/10.1016/j.jpowsour.2016.04.105	journal	July 2016
Advances in sealed liquid cells for in-situ TEM electrochemial investigation of lithium-ion battery Wu, Fan; Yao, Nan Nano Energy, Vol. 11 https://doi.org/10.1016/j.nanoen.2014.11.004	journal	January 2015
In Situ TEM Observations of Sn-Containing Silicon Nanowires Undergoing Reversible Pore Formation Due to Fast Lithiation/Delithiation Kinetics Lu, Xiaotang; Bogart, Timothy D.; Gu, Meng The Journal of Physical Chemistry C, Vol. 119, Issue 38 https://doi.org/10.1021/acs.jpcc.5b06386	journal	September 2015
Size Dependent Pore Formation in Germanium Nanowires Undergoing Reversible Delithiation Observed by In Situ TEM Lu, Xiaotang; He, Yang; Mao, Scott X. The Journal of Physical Chemistry C, Vol. 120, Issue 50 https://doi.org/10.1021/acs.jpcc.6b10174	journal	December 2016
Direct Synthesis of Carbon-Doped TiO ₂ –Bronze Nanowires as Anode Materials for High Performance Lithium-Ion Batteries Goriparti, Subrahmanyam; Miele, Ermanno; Prato, Mirko ACS Applied Materials & Interfaces, Vol. 7, Issue 45 https://doi.org/10.1021/acsami.5b06426	journal	November 2015
In Situ Transmission Electron Microsopy of Oxide Shell-Induced Pore Formation in (De)lithiated Silicon Nanowires Adkins, Emily R.; Jiang, Taizhi; Luo, Langli ACS Energy Letters, Vol. 3, Issue 11 https://doi.org/10.1021/acsenergylett.8b01904	journal	October 2018
Lithium Electrodeposition Dynamics in Aprotic Electrolyte Observed in Situ via Transmission Electron Microscopy Leenheer, Andrew J.; Jungjohann, Katherine L.; Zavadil, Kevin R. ACS Nano, Vol. 9, Issue 4 https://doi.org/10.1021/acsnano.5b00876	journal	February 2015
Phase Boundary Propagation in Li-Alloying Battery Electrodes Revealed by Liquid-Cell Transmission Electron Microscopy Leenheer, Andrew J.; Jungjohann, Katherine L.; Zavadil, Kevin R. ACS Nano, Vol. 10, Issue 6 https://doi.org/10.1021/acsnano.6b02200	journal	May 2016
Lithium Self-Discharge and Its Prevention: Direct Visualization through In Situ Electrochemical Scanning Transmission Electron Microscopy Harrison, Katharine L.; Zavadil, Kevin R.; Hahn, Nathan T. ACS Nano, Vol. 11, Issue 11 https://doi.org/10.1021/acsnano.7b05513	journal	September 2017
Amorphous Carbon-Coated Tin Anode Material for Lithium Secondary Battery Noh, Mijung; Kwon, Yoojung; Lee, Hyojin Chemistry of Materials, Vol. 17, Issue 8 https://doi.org/10.1021/cm0481372	journal	April 2005
In Situ TEM on the Reversibility of Nanosized Sn Anodes during the Electrochemical Reaction Li, Qianqian; Wang, Peng; Feng, Qiong Chemistry of Materials, Vol. 26, Issue 14 https://doi.org/10.1021/cm5009448	journal	July 2014
Multiple Li Positions inside Oxygen Octahedra in Lithiated TiO ₂ Anatase Wagemaker, Marnix; Kearley, Gordon J.; van Well, Ad A. Journal of the American Chemical Society, Vol. 125, Issue 3 https://doi.org/10.1021/ja028165q	journal	January 2003
A Comparative First-Principles Study of the Structure, Energetics, and Properties of Li–M (M = Si, Ge, Sn) Alloys Chou, Chia-Yun; Kim, Hyunwoo; Hwang, Gyeong S. The Journal of Physical Chemistry C, Vol. 115, Issue 40 https://doi.org/10.1021/jp205484v	journal	September 2011
Demonstration of an Electrochemical Liquid Cell for Operando Transmission Electron Microscopy Observation of the Lithiation/Delithiation Behavior of Si Nanowire Battery Anodes Gu, Meng; Parent, Lucas R.; Mehdi, B. Layla Nano Letters, Vol. 13, Issue 12 https://doi.org/10.1021/nl403402q	journal	November 2013
Visualization of Electrode–Electrolyte Interfaces in LiPF ₆ /EC/DEC Electrolyte for Lithium Ion Batteries via in Situ TEM Zeng, Zhiyuan; Liang, Wen-I; Liao, Hong-Gang Nano Letters, Vol. 14, Issue 4 https://doi.org/10.1021/nl403922u	journal	March 2014
Highly Stable and Reversible Lithium Storage in SnO ₂ Nanowires Surface Coated with a Uniform Hollow Shell by Atomic Layer Deposition Guan, Cao; Wang, Xinghui; Zhang, Qing Nano Letters, Vol. 14, Issue 8 https://doi.org/10.1021/nl502192p	journal	July 2014
Rate of Self-Diffusion in Tin Crystals Boas, W.; Fensham, P. J. Nature, Vol. 164, Issue 4183 https://doi.org/10.1038/1641127b0	journal	December 1949
Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries Albertus, Paul; Babinec, Susan; Litzelman, Scott Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0047-2	journal	December 2017
Performance and cost of materials for lithium-based rechargeable automotive batteries Schmuch, Richard; Wagner, Ralf; Hörpel, Gerhard Nature Energy, Vol. 3, Issue 4 https://doi.org/10.1038/s41560-018-0107-2	journal	April 2018
Silicon Surface Tethered Polymer as Artificial Solid Electrolyte Interface Shen, Brian H.; Veith, Gabriel M.; Tenhaeff, Wyatt E. Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-30000-z	journal	August 2018
In Situ and Ex Situ TEM Study of Lithiation Behaviours of Porous Silicon Nanostructures Shen, Chenfei; Ge, Mingyuan; Luo, Langli Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep31334	journal	August 2016
Si nanotubes ALD coated with TiO ₂ , TiN or Al ₂ O ₃ as high performance lithium ion battery anodes Lotfabad, Elmira Memarzadeh; Kalisvaart, Peter; Kohandehghan, Alireza J. Mater. Chem. A, Vol. 2, Issue 8 https://doi.org/10.1039/C3TA14302C	journal	January 2014
Introducing nanodiamond into TiO ₂ -based anode for improving the performance of lithium-ion batteries Gao, Xuan; Sun, Xiaochen; Jiang, Zhigang New Journal of Chemistry, Vol. 43, Issue 9 https://doi.org/10.1039/C8NJ06226A	journal	January 2019
Ti-based compounds as anode materials for Li-ion batteries Zhu, Guan-Nan; Wang, Yong-Gang; Xia, Yong-Yao Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee03410g	journal	January 2012
Multifunctional TiO2 coating for a SiO anode in Li-ion batteries Jeong, Goojin; Kim, Jae-Hun; Kim, Young-Ugk Journal of Materials Chemistry, Vol. 22, Issue 16 https://doi.org/10.1039/c2jm15677f	journal	January 2012
Mesoporous TiO2–Sn@C core–shell microspheres for Li-ion batteries Chen, Jizhang; Yang, Li; Zhang, Zhengxi Chemical Communications, Vol. 49, Issue 27 https://doi.org/10.1039/c3cc40671g	journal	January 2013
ALD TiO2 coated silicon nanowires for lithium ion battery anodes with enhanced cycling stability and coulombic efficiency Memarzadeh Lotfabad, Elmira; Kalisvaart, Peter; Cui, Kai Physical Chemistry Chemical Physics, Vol. 15, Issue 32 https://doi.org/10.1039/c3cp52485j	journal	January 2013
Unravelling the physical mechanisms that determine microstructural evolution of ultrathin Volmer-Weber films Elofsson, V.; Lü, B.; Magnfält, D. Journal of Applied Physics, Vol. 116, Issue 4 https://doi.org/10.1063/1.4890522	journal	July 2014
A Sealed Liquid Cell for In Situ Transmission Electron Microscopy of Controlled Electrochemical Processes Leenheer, Andrew J.; Sullivan, John P.; Shaw, Michael J. Journal of Microelectromechanical Systems, Vol. 24, Issue 4 https://doi.org/10.1109/JMEMS.2014.2380771	journal	August 2015
Structural Evolution and Pulverization of Tin Nanoparticles during Lithiation-Delithiation Cycling Wang, Jiangwei; Fan, Feifei; Liu, Yang Journal of The Electrochemical Society, Vol. 161, Issue 11 https://doi.org/10.1149/2.0041411jes	journal	January 2014
Investigation of the Li-Ion Insertion Mechanism for Amorphous and Anatase TiO ₂ Thin-Films Moitzheim, S.; De Gendt, S.; Vereecken, P. M. Journal of The Electrochemical Society, Vol. 166, Issue 2 https://doi.org/10.1149/2.1091816jes	journal	January 2019

Similar Records

Minimized Volume Expansion in Hierarchical Porous Silicon upon Lithiation

Journal Article · Tue Feb 26 19:00:00 EST 2019 · ACS Applied Materials and Interfaces · OSTI ID:1909181

In Situ Focused Ion Beam Scanning Electron Microscope Study of Microstructural Evolution of Single Tin Particle Anode for Li-Ion Batteries

Journal Article · Wed Jan 02 19:00:00 EST 2019 · ACS Applied Materials and Interfaces · OSTI ID:1510075

In operando X-ray diffraction strain measurement in Ni₃Sn₂ – Coated inverse opal nanoscaffold anodes for Li-ion batteries

Journal Article · Tue Oct 31 20:00:00 EDT 2017 · Journal of Power Sources · OSTI ID:1432952

Related Subjects

25 ENERGY STORAGE
electrochemistry
in-situ TEM
lithium ion batteries
nanoscale
pore
tin anode

Degradation-resistant TiO2@Sn anodes for high-capacity lithium-ion batteries

Citation Formats

References (44)

Similar Records

Related Subjects

Degradation-resistant TiO₂@Sn anodes for high-capacity lithium-ion batteries