High-Entropy Perovskite Fluorides: A New Platform for Oxygen Evolution Catalysis

Wang, Tao; Chen, Hao; Yang, Zhenzhen; Liang, Jiyuan; Dai, Sheng

doi:10.1021/jacs.9b12377

High-Entropy Perovskite Fluorides: A New Platform for Oxygen Evolution Catalysis

Journal Article · Thu Feb 27 00:00:00 UTC 2020 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.9b12377· OSTI ID:1822092

^[1]; ^[1]; ^[1]; Liang, Jiyuan ^[1]; ^[2]

Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

High-entropy perovskite fluorides (HEPFs) have great potential in electrocatalysis that has not been realized because of the limitation of a high-temperature synthetic route and the limited understanding of high-entropy materials. The use of HEPFs in effective oxygen evolution catalysis and a feasible synthesis route for HEPFs in a boiled solution by combining a hydrothermal method with mechanochemistry are first reported here. These HEPFs consisting of cost-effective elements dramatically gave excellent catalytic activity for the oxygen evolution reaction in an alkaline media.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1822092

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 10 Vol. 142; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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