Direct observation of C60- nano-ion gas phase ozonation via ion mobility-mass spectrometry

Li, Chenxi; Hogan Jr, Christopher J.

doi:10.1039/c9cp01394f

Direct observation of C₆₀- nano-ion gas phase ozonation via ion mobility-mass spectrometry

Journal Article · Tue Jan 01 00:00:00 EST 2019 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/c9cp01394f· OSTI ID:1820661

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Univ. of Minnesota, Minneapolis, MN (United States); Federal Inst. of Technology, Zurich (Switzerland). Laboratory for Physical Chemistry; University of Minnesota
Univ. of Minnesota, Minneapolis, MN (United States)

Improved methods to probe the reactivity of nano-ions, such as C₆₀-, would find utility in nanochemistry, combustion chemistry, and in generally understanding the behavior of matter at the nanometer scale. Here, we demonstrate that ion mobility-mass spectrometry (IM-MS) with a low-field differential mobility analyzer can be used to probe nano-ion reaction kinetics. We used the developed IM-MS approach to examine the gas phase reactivity of C₆₀- ions with ozone at atmospheric pressure. Experimental results show that ozonation of C₆₀- mainly leads to the formation of C₆₀O_n-. The controlled reaction time within the ion mobility instrument enables calculation of ozonation reaction rates and assuming oxygen atoms are added sequentially, we find that the reaction rate between C₆₀- and O₃ is near the collision controlled limit. We propose an exponentially decaying reaction rate coefficient expression to describe ozonation leading to the addition of >20 oxygen atoms. At high ozone concentrations, CO or CO₂ loss from C₆₀O_n- is additionally observed.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Minnesota, Minneapolis, MN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Fusion Energy Sciences (FES)

Grant/Contract Number:: SC0018202

OSTI ID:: 1820661

Alternate ID(s):: OSTI ID: 1511764
OSTI ID: 1612875

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 20 Vol. 21; ISSN 1463-9076

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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