Decoupling Lattice and Magnetic Instabilities in Frustrated CuMnO2

Lawler, Keith V.; Smith, Dean; Evans, Shaun R.; dos Santos, Antonio M.; Molaison, Jamie J.; Bos, Jan-Willem G.; Mutka, Hannu; Henry, Paul F.; Argyriou, Dimitri N.; Salamat, Ashkan; Kimber, Simon J.

doi:10.1021/acs.inorgchem.1c00435

Decoupling Lattice and Magnetic Instabilities in Frustrated CuMnO2

Journal Article · Wed Mar 31 00:00:00 EDT 2021 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.1c00435· OSTI ID:1819679

Lawler, Keith V. ^[1]; ^[2]; Evans, Shaun R. ^[3]; dos Santos, Antonio M. ^[4]; Molaison, Jamie J. ^[4]; ^[5]; Mutka, Hannu ^[6]; ^[7]; Argyriou, Dimitri N. ^[8]; ^[2]; ^[9]

Department of Chemistry and Biochemistry, University of Nevada Las Vegas, Las Vegas, Nevada 89154, United States
Department of Physics and Astronomy and HiPSEC, University of Nevada Las Vegas, Las Vegas, Nevada 89154, United States
European Synchrotron Radiation Facility - 71, avenue des Martyrs, CS 40220, 38043 Grenoble Cedex 9, France
Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States
Institute of Chemical Sciences, Centre for Advanced Energy Storage and Recovery, School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS, United Kingdom
Institut Laue-Langevin, 71 avenue des Martyrs, CS 20156, 38042 Grenoble, France
ISIS Pulsed Neutron Muon Facility, Rutherford Appleton Laboratory, Harwell Campus, Didcot OX11 0QX, United Kingdom
European Spallation Source ERIC, P.O. Box 176, SE-221 00 Lund, Sweden
ICB-Laboratoire Interdisciplinaire Carnot de Bourgogne, Bâtiment Sciences Mirande, Université Bourgogne-Franche Comté, Université de Bourgogne, 9 Avenue Alain Savary, B.P. 47870, 21078 Dijon Cedex, France

The AMnO₂ delafossites (A = Na, Cu) are model frustrated antiferromagnets, with triangular layers of Mn³⁺ spins. At low temperatures (T_N = 65 K), a C2/m → P$$\bar1$$ transition is found in CuMnO₂, which breaks frustration and establishes magnetic order. In contrast to this clean transition, A = Na only shows short-range distortions at T_N. Here, we report a systematic crystallographic, spectroscopic, and theoretical investigation of CuMnO₂. We show that, even in stoichiometric samples, nonzero anisotropic Cu displacements coexist with magnetic order. Using X-ray/neutron diffraction and Raman scattering, we show that high pressures act to decouple these degrees of freedom. This manifests as an isostuctural phase transition at ~10 GPa, with a reversible collapse of the c-axis. This is shown to be the high-pressure analogue of the c-axis negative thermal expansion seen at ambient pressure. Density functional theory (DFT) simulations confirm that dynamical instabilities of the Cu⁺ cations and edge-shared MnO₆ layers are intertwined at ambient pressure. However, high pressure selectively activates the former, before an eventual predicted reemergence of magnetism at the highest pressures. Our results show that the lattice dynamics and local structure of CuMnO₂ are quantitatively different from nonmagnetic Cu delafossites and raise questions about the role of intrinsic inhomogeneity in frustrated antiferromagnets.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; AC05-00OR22725

OSTI ID:: 1819679

Alternate ID(s):: OSTI ID: 1828267

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 8 Vol. 60; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (72)

Negative thermal expansion: a review Miller, W.; Smith, C. W.; Mackenzie, D. S. Journal of Materials Science, Vol. 44, Issue 20 https://doi.org/10.1007/s10853-009-3692-4	journal	July 2009
New developments in neutron-scattering methods under high pressure with the Paris—Edinburgh cells Besson, J. M.; Nelmes, R. J. Physica B: Condensed Matter, Vol. 213-214 https://doi.org/10.1016/0921-4526(95)00055-E	journal	August 1995
X-Ray diffraction study of copper iron oxide [CuFeO2] under pressures up to 10 Gpa Zhao, T. R.; Hasegawa, M.; Kondo, T. Materials Research Bulletin, Vol. 32, Issue 2 https://doi.org/10.1016/S0025-5408(96)00182-1	journal	February 1997
Phonon line shapes and excitation energies Fåk, B.; Dorner, B. Physica B: Condensed Matter, Vol. 234-236 https://doi.org/10.1016/S0921-4526(97)00121-X	journal	June 1997
Crednerite-CuMnO2 thin films prepared using atmospheric pressure plasma annealing Chen, Hong-Ying; Lin, Yu-Chang; Lee, Jiann-Shing Applied Surface Science, Vol. 338 https://doi.org/10.1016/j.apsusc.2015.02.112	journal	May 2015
Trends in negative thermal expansion behavior for AMO2 (A=Cu or Ag; M=Al, Sc, In, or La) compounds with the delafossite structure Li, J.; Sleight, A. W.; Jones, C. Y. Journal of Solid State Chemistry, Vol. 178, Issue 1 https://doi.org/10.1016/j.jssc.2004.11.017	journal	January 2005
Crystal chemistry and electrical properties of the delafossite structure Marquardt, Meagen A.; Ashmore, Nathan A.; Cann, David P. Thin Solid Films, Vol. 496, Issue 1 https://doi.org/10.1016/j.tsf.2005.08.316	journal	February 2006
Raman spectroscopic studies of CuFeO2 at high pressures Salke, Nilesh P.; Kamali, K.; Ravindran, T. R. Vibrational Spectroscopy, Vol. 81 https://doi.org/10.1016/j.vibspec.2015.10.010	journal	November 2015
Molecular and Electronic Structures of M ₂ O ₇ (M = Mn, Tc, Re) Lawler, Keith V.; Childs, Bradley C.; Mast, Daniel S. Inorganic Chemistry, Vol. 56, Issue 5 https://doi.org/10.1021/acs.inorgchem.6b02503	journal	February 2017
Crystal Chemistry and Phonon Heat Capacity in Quaternary Honeycomb Delafossites: Cu[Li _1/3 Sn _2/3 ]O ₂ and Cu[Na _1/3 Sn _2/3 ]O ₂ Abramchuk, Mykola; Lebedev, Oleg I.; Hellman, Olle Inorganic Chemistry, Vol. 57, Issue 20 https://doi.org/10.1021/acs.inorgchem.8b01866	journal	October 2018
An Atomistic Understanding of the Unusual Thermal Behavior of the Molecular Oxide Tc ₂ O ₇ Mast, Daniel S.; Lawler, Keith V.; Childs, Bradley C. Inorganic Chemistry, Vol. 58, Issue 9 https://doi.org/10.1021/acs.inorgchem.8b02368	journal	April 2019
Strong Negative Thermal Expansion along the O−Cu−O Linkage in CuScO ₂ Li, J.; Yokochi, A.; Amos, T. G. Chemistry of Materials, Vol. 14, Issue 6 https://doi.org/10.1021/cm011633v	journal	June 2002
Substitution Effect on the Interplane Coupling in Crednerite: the Cu _1.04 Mn _0.96 O ₂ Case Poienar, M.; Vecchini, C.; André, G. Chemistry of Materials, Vol. 23, Issue 1 https://doi.org/10.1021/cm102483m	journal	January 2011
Anomalous Thermal Expansion of Cuprites: A Combined High Resolution Pair Distribution Function and Geometric Analysis Chapman, Karena W.; Chupas, Peter J. Chemistry of Materials, Vol. 21, Issue 2 https://doi.org/10.1021/cm802900t	journal	January 2009
Direct Observation of a Transverse Vibrational Mechanism for Negative Thermal Expansion in Zn(CN) ₂ : An Atomic Pair Distribution Function Analysis Chapman, Karena W.; Chupas, Peter J.; Kepert, Cameron J. Journal of the American Chemical Society, Vol. 127, Issue 44 https://doi.org/10.1021/ja055197f	journal	November 2005
Frustration-induced nanometre-scale inhomogeneity in a triangular antiferromagnet Zorko, A.; Adamopoulos, O.; Komelj, M. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4222	journal	January 2014
Amplitude mode in the planar triangular antiferromagnet Na0.9MnO2 Dally, Rebecca L.; Zhao, Yang; Xu, Zhijun Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04601-1	journal	June 2018
Co-emergence of magnetic order and structural fluctuations in magnetite Perversi, Giuditta; Pachoud, Elise; Cumby, James Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10949-9	journal	June 2019
Magnetic inhomogeneity on a triangular lattice: the magnetic-exchange versus the elastic energy and the role of disorder Zorko, A.; Kokalj, J.; Komelj, M. Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep09272	journal	March 2015
Negative thermal expansion in molecular materials Liu, Zhanning; Gao, Qilong; Chen, Jun Chemical Communications, Vol. 54, Issue 41 https://doi.org/10.1039/C8CC01153B	journal	January 2018
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy Weigend, Florian; Ahlrichs, Reinhart Physical Chemistry Chemical Physics, Vol. 7, Issue 18, p. 3297-3305 https://doi.org/10.1039/b508541a	journal	January 2005
LOBA: a localized orbital bonding analysis to calculate oxidation states, with application to a model water oxidation catalyst Thom, Alex J. W.; Sundstrom, Eric J.; Head-Gordon, Martin Physical Chemistry Chemical Physics, Vol. 11, Issue 47 https://doi.org/10.1039/b915364k	journal	January 2009
Magnetic frustration in α-NaMnO ₂ and CuMnO ₂ Jia, Ting; Zhang, Guoren; Zhang, Xiaoli Journal of Applied Physics, Vol. 109, Issue 7 https://doi.org/10.1063/1.3536533	journal	April 2011
Strength analysis and optimisation of double-toroidal anvils for high-pressure research Fang, J.; Bull, C. L.; Loveday, J. S. Review of Scientific Instruments, Vol. 83, Issue 9 https://doi.org/10.1063/1.4746993	journal	September 2012
Multiferroic CuCrO ₂ under high pressure: In situ X-ray diffraction and Raman spectroscopic studies Garg, Alka B.; Mishra, A. K.; Pandey, K. K. Journal of Applied Physics, Vol. 116, Issue 13 https://doi.org/10.1063/1.4896952	journal	October 2014
A suite-level review of the neutron powder diffraction instruments at Oak Ridge National Laboratory Calder, S.; An, K.; Boehler, R. Review of Scientific Instruments, Vol. 89, Issue 9 https://doi.org/10.1063/1.5033906	journal	September 2018
Advances in molecular quantum chemistry contained in the Q-Chem 4 program package Shao, Yihan; Gan, Zhengting; Epifanovsky, Evgeny Molecular Physics, Vol. 113, Issue 2 https://doi.org/10.1080/00268976.2014.952696	journal	September 2014
Bilbao Crystallographic Server : Useful Databases and Tools for Phase-Transition Studies Kroumova, E.; Aroyo, M. I.; Perez-Mato, J. M. Phase Transitions, Vol. 76, Issue 1-2 https://doi.org/10.1080/0141159031000076110	journal	January 2003
Toroid type high-pressure device: history and prospects Khvostantsev, L. G.; Slesarev, V. N.; Brazhkin, V. V. High Pressure Research, Vol. 24, Issue 3 https://doi.org/10.1080/08957950412331298761	journal	September 2004
PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals Farrow, C. L.; Juhas, P.; Liu, J. W. Journal of Physics: Condensed Matter, Vol. 19, Issue 33 https://doi.org/10.1088/0953-8984/19/33/335219	journal	July 2007
Magnetic structure of CuCrO ₂ : a single crystal neutron diffraction study Frontzek, M.; Ehlers, G.; Podlesnyak, A. Journal of Physics: Condensed Matter, Vol. 24, Issue 1 https://doi.org/10.1088/0953-8984/24/1/016004	journal	December 2011
Charge and orbital order in frustrated Pb ₃ Mn ₇ O ₁₅ Kimber, Simon A. J. Journal of Physics: Condensed Matter, Vol. 24, Issue 18 https://doi.org/10.1088/0953-8984/24/18/186002	journal	April 2012
Raman scattering study of delafossite magnetoelectric multiferroic compounds: CuFeO ₂ and CuCrO ₂ Aktas, O.; Truong, K. D.; Otani, T. Journal of Physics: Condensed Matter, Vol. 24, Issue 3 https://doi.org/10.1088/0953-8984/24/3/036003	journal	December 2011
Spin-chain correlations in the frustrated triangular lattice material CuMnO ₂ Kimber, Simon A. J.; Wildes, Andrew R.; Mutka, Hannu Journal of Physics: Condensed Matter, Vol. 32, Issue 44 https://doi.org/10.1088/1361-648X/ab9d4b	journal	August 2020
Inhomogeneous Electron Gas Hohenberg, P.; Kohn, W. Physical Review, Vol. 136, Issue 3B, p. B864-B871 https://doi.org/10.1103/PhysRev.136.B864	journal	November 1964
Self-Consistent Equations Including Exchange and Correlation Effects Kohn, W.; Sham, L. J. Physical Review, Vol. 140, Issue 4A, p. A1133-A1138 https://doi.org/10.1103/PhysRev.140.A1133	journal	November 1965
Nanoscale degeneracy lifting in a geometrically frustrated antiferromagnet Frandsen, Benjamin A.; Bozin, Emil S.; Aza, Eleni Physical Review B, Vol. 101, Issue 2 https://doi.org/10.1103/PhysRevB.101.024423	journal	January 2020
High-pressure structural and electronic properties of Cu M O 2 ( M = Cr , Mn ) delafossite-type oxides Levy, D.; Greenberg, E.; Layek, S. Physical Review B, Vol. 101, Issue 24 https://doi.org/10.1103/PhysRevB.101.245121	journal	June 2020
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Lattice instabilities near the critical V-V separation for localized versus itinerant electrons in LiV 1 − y M y O 2 (M=Cr or Ti) Li 1 − x VO 2 Goodenough, J. B.; Dutta, G.; Manthiram, A. Physical Review B, Vol. 43, Issue 13 https://doi.org/10.1103/PhysRevB.43.10170	journal	May 1991
Filled skutterudite antimonides: Electron crystals and phonon glasses Sales, B. C.; Mandrus, D.; Chakoumakos, B. C. Physical Review B, Vol. 56, Issue 23 https://doi.org/10.1103/PhysRevB.56.15081	journal	December 1997
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y. Physical Review B, Vol. 57, Issue 3, p. 1505-1509 https://doi.org/10.1103/PhysRevB.57.1505	journal	January 1998
Vibrational properties of delafossite Cu Ga O 2 at ambient and high pressures Pellicer-Porres, J.; Segura, A.; Martínez, E. Physical Review B, Vol. 72, Issue 6 https://doi.org/10.1103/PhysRevB.72.064301	journal	August 2005
Oxidation energies of transition metal oxides within the GGA + U framework Wang, Lei; Maxisch, Thomas; Ceder, Gerbrand Physical Review B, Vol. 73, Issue 19 https://doi.org/10.1103/PhysRevB.73.195107	journal	May 2006
Pressure and temperature dependence of the lattice dynamics of Cu Al O 2 investigated by Raman scattering experiments and ab initio calculations Pellicer-Porres, J.; Martínez-García, D.; Segura, A. Physical Review B, Vol. 74, Issue 18 https://doi.org/10.1103/PhysRevB.74.184301	journal	November 2006
Negative thermal expansion in crystals with the delafossite structure: An extended x-ray absorption fine structure study of CuScO 2 and CuLaO 2 Ahmed, S. I.; Dalba, G.; Fornasini, P. Physical Review B, Vol. 79, Issue 10 https://doi.org/10.1103/PhysRevB.79.104302	journal	March 2009
Spin excitations in frustrated A -site spinels investigated with inelastic neutron scattering Krimmel, A.; Mutka, H.; Koza, M. M. Physical Review B, Vol. 79, Issue 13 https://doi.org/10.1103/PhysRevB.79.134406	journal	April 2009
Spin-lattice coupling induced phase transition in the S = 2 frustrated antiferromagnet CuMnO 2 Damay, F.; Poienar, M.; Martin, C. Physical Review B, Vol. 80, Issue 9 https://doi.org/10.1103/PhysRevB.80.094410	journal	September 2009
Pressure-induced Fe ↔ Cu cationic valence exchange and its structural consequences: High-pressure studies of delafossite CuFeO 2 Xu, W. M.; Rozenberg, G. Kh.; Pasternak, M. P. Physical Review B, Vol. 81, Issue 10 https://doi.org/10.1103/PhysRevB.81.104110	journal	March 2010
Magnetoelastic coupling in the frustrated antiferromagnetic triangular lattice CuMnO 2 Vecchini, C.; Poienar, M.; Damay, F. Physical Review B, Vol. 82, Issue 9 https://doi.org/10.1103/PhysRevB.82.094404	journal	September 2010
Tuning the magnetic ground state of a triangular lattice system Cu(Mn 1 − x Cu x )O 2 Garlea, V. Ovidiu; Savici, Andrei T.; Jin, Rongying Physical Review B, Vol. 83, Issue 17 https://doi.org/10.1103/PhysRevB.83.172407	journal	May 2011
Magnetic correlations and the influence of atomic disorder in frustrated isosceles triangular lattice antiferromagnet CuMnO 2 Terada, Noriki; Tsuchiya, Yoshinori; Kitazawa, Hideaki Physical Review B, Vol. 84, Issue 6 https://doi.org/10.1103/PhysRevB.84.064432	journal	August 2011
Valence bond liquid phase in the honeycomb lattice material Li 2 Ru O 3 Kimber, Simon A. J.; Mazin, I. I.; Shen, Juan Physical Review B, Vol. 89, Issue 8 https://doi.org/10.1103/PhysRevB.89.081408	journal	February 2014
CuFe O 2 at a megabar: Stabilization of a mixed-valence low-spin magnetic semiconducting ground state Xu, W. M.; Hearne, G. R.; Pasternak, M. P. Physical Review B, Vol. 94, Issue 3 https://doi.org/10.1103/PhysRevB.94.035155	journal	July 2016
One-Dimensional Magnetic Fluctuations in the Spin-2 Triangular Lattice α − NaMnO 2 Stock, C.; Chapon, L. C.; Adamopoulos, O. Physical Review Letters, Vol. 103, Issue 7 https://doi.org/10.1103/PhysRevLett.103.077202	journal	August 2009
Strongly Constrained and Appropriately Normed Semilocal Density Functional Sun, Jianwei; Ruzsinszky, Adrienn; Perdew, John P. Physical Review Letters, Vol. 115, Issue 3 https://doi.org/10.1103/PhysRevLett.115.036402	journal	July 2015
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Frustration Driven Lattice Distortion: An NMR Investigation of Y 2 Mo 2 O 7 Keren, Amit; Gardner, Jason S. Physical Review Letters, Vol. 87, Issue 17 https://doi.org/10.1103/PhysRevLett.87.177201	journal	October 2001
Magnetoelastic Coupling and Symmetry Breaking in the Frustrated Antiferromagnet α − NaMnO 2 Giot, Maud; Chapon, Laurent C.; Androulakis, John Physical Review Letters, Vol. 99, Issue 24 https://doi.org/10.1103/PhysRevLett.99.247211	journal	December 2007
EXPGUI , a graphical user interface for GSAS Toby, Brian H. Journal of Applied Crystallography, Vol. 34, Issue 2 https://doi.org/10.1107/S0021889801002242	journal	April 2001
Parametric Rietveld refinement Stinton, Graham W.; Evans, John S. O. Journal of Applied Crystallography, Vol. 40, Issue 1 https://doi.org/10.1107/S0021889806043275	journal	January 2007
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811038970	journal	October 2011
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
PDFgetX3 : a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions Juhás, P.; Davis, T.; Farrow, C. L. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813005190	journal	March 2013
Unit-cell refinement from powder diffraction scans Pawley, G. S. Journal of Applied Crystallography, Vol. 14, Issue 6 https://doi.org/10.1107/S0021889881009618	journal	December 1981
The effect of thermal motion on the estimation of bond lengths from diffraction measurements Busing, W. R.; Levy, H. A. Acta Crystallographica, Vol. 17, Issue 2 https://doi.org/10.1107/S0365110X64000408	journal	February 1964
The fast azimuthal integration Python library: pyFAI Ashiotis, Giannis; Deschildre, Aurore; Nawaz, Zubair Journal of Applied Crystallography, Vol. 48, Issue 2 https://doi.org/10.1107/S1600576715004306	journal	March 2015
FIT2D : a multi-purpose data reduction, analysis and visualization program Hammersley, A. P. Journal of Applied Crystallography, Vol. 49, Issue 2 https://doi.org/10.1107/S1600576716000455	journal	March 2016
TOPAS and TOPAS-Academic : an optimization program integrating computer algebra and crystallographic objects written in C++ Coelho, Alan A. Journal of Applied Crystallography, Vol. 51, Issue 1 https://doi.org/10.1107/S1600576718000183	journal	February 2018
Role of Structural Change in Phase Transition in LiVO ₂ Onoda, Masashige; Inabe, Tamotsu Journal of the Physical Society of Japan, Vol. 62, Issue 7 https://doi.org/10.1143/JPSJ.62.2216	journal	July 1993
Copper Delafossites under High Pressure—A Brief Review of XRD and Raman Spectroscopic Studies Garg, Alka; Rao, Rekha Crystals, Vol. 8, Issue 6 https://doi.org/10.3390/cryst8060255	journal	June 2018
E9: The New High-Resolution Neutron Powder Diffractometer at the Berlin Neutron Scattering Center Többens, D. M.; Stüßer, N.; Knorr, K. Materials Science Forum, Vol. 378-381 https://doi.org/10.4028/www.scientific.net/MSF.378-381.288	journal	October 2001

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