Self-Stabilized LiNi0.8Mn0.1Co0.1O2 in thiophosphate-based all-solid-state batteries through extra LiOH

Zhang, Yubin; Sun, Xiao; Cao, Daxian; Gao, Guanhui; Yang, Zhenzhen; Zhu, Hongli; Wang, Yan

doi:10.1016/j.ensm.2021.06.024

Self-Stabilized LiNi_0.8Mn_0.1Co_0.1O₂ in thiophosphate-based all-solid-state batteries through extra LiOH

Journal Article · Fri Jun 18 00:00:00 EDT 2021 · Energy Storage Materials

DOI:https://doi.org/10.1016/j.ensm.2021.06.024· OSTI ID:1819503

Zhang, Yubin ^[1]; Sun, Xiao ^[2]; Cao, Daxian ^[2]; Gao, Guanhui ^[3]; Yang, Zhenzhen ^[4]; Zhu, Hongli ^[2]; Wang, Yan ^[1]

Worcester Polytechnic Institute, MA (United States)
Northeastern Univ., Boston, MA (United States)
Rice Univ., Houston, TX (United States)
Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division

Nickle-rich LiNi_0.8Co_0.1Mn_0.1O₂ (NMC 811) cathode material exhibits engaging properties in high energy density and low cost, making it great potential for the next generation high-energy all-solid-state lithium batteries (ASSLBs). However, NMC 811 suffers from severe surface electrochemical, chemical, and voltage incompatibility towards solid-state electrolytes (SSE), especially thiophosphate-based electrolytes like Li₆PS₅Cl. Although diverse coating methods have been made to overcome this issue, they are typically cumbersome and expensive. A coating strategy that satisfied all the requirements of cost-efficiency, stability, uniformity, scalability, and easy-achieving is still challenging. Here, we developed a LiOH-based surface stabilization strategy that provides a ~10 nm stable permeable layer on NMC 811. After one-step sintering of NMC 811 precursor mixed with LiOH, which is commonly used for NMC 811 lithiation process, excessive LiOH simultaneously distributes on NMC 811 particles. Unlike other reported methods, this coating method can be easily controlled and fabricated without additional complicated processes. By simply controlling the thickness of LiOH layer, which protects the Li₆PS₅Cl solid electrolyte materials from being oxidized, optimized cycling stability can be obtained for 600 cycles with capacity of 130 mAh g ^– ¹ on average at a wide electrochemical window of 2.50–4.20 V (vs. Li-In).

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1819503

Journal Information:: Energy Storage Materials, Journal Name: Energy Storage Materials Vol. 41; ISSN 2405-8297

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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