Elucidating the influence of molten salt chemistries on the synthesis and stability of perovskites oxides

Levitas, Benjamin; Piligian, Spencer; Ireland, Thomas; Gopalan, Srikanth

doi:10.1039/D0RA04324A

Elucidating the influence of molten salt chemistries on the synthesis and stability of perovskites oxides

Journal Article · Wed Sep 01 00:00:00 UTC 2021 · RSC Advances

DOI:https://doi.org/10.1039/D0RA04324A· OSTI ID:1818190

^[1]; Piligian, Spencer ^[2]; Ireland, Thomas ^[3]; Gopalan, Srikanth ^[4]

Division of Materials Science and Engineering, Boston University, Brookline, Massachusetts 02445, USA
Department of Electrical and Computer Engineering, Boston University, Boston, Massachusetts 02215, USA
Department of Earth and Environment, Boston University, Boston, Massachusetts 02215, USA
Division of Materials Science and Engineering, Boston University, Brookline, Massachusetts 02445, USA, Department of Mechanical Engineering, Boston University, Boston, Massachusetts 02215, USA

For the successful molten salt synthesis of La _0.8 Sr _0.2 MnO ₃ , the salt cation is more influential than the anion. With a KNO ₃ solvent, pure phase LSM nanoparticles are synthesized at 600 °C in 1 hour.

View Journal Article

Research Organization:: Boston Univ., MA (United States); Worcester Polytechnic Institute, MA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: FE0031205; FE0031652

OSTI ID:: 1818190

Alternate ID(s):: OSTI ID: 1849246

Journal Information:: RSC Advances, Journal Name: RSC Advances Journal Issue: 47 Vol. 11; ISSN 2046-2069; ISSN RSCACL

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (28)

Surface-Driven Magnetotransport in Perovskite Nanocrystals Thi N'Goc, Ha Le; Mouafo, Louis Donald Notemgnou; Etrillard, Céline Advanced Materials, Vol. 29, Issue 9 https://doi.org/10.1002/adma.201604745	journal	December 2016
Molten salt synthesis of LaCoO3 perovskite Vradman, L.; Friedland, E.; Zana, J. Journal of Materials Science, Vol. 52, Issue 19 https://doi.org/10.1007/s10853-017-1332-y	journal	July 2017
Molten salt synthesis of La0.8Sr0.2MnO3 powders for SOFC cathode electrode Gu, Sin-il; Shin, Hyo-soon; Hong, Youn-woo Metals and Materials International, Vol. 18, Issue 4 https://doi.org/10.1007/s12540-012-4009-8	journal	August 2012
Lead zirconate titanate ceramics from molten salt solvent synthesized powders Arendt, R. H.; Rosolowski, J. H.; Szymaszek, J. W. Materials Research Bulletin, Vol. 14, Issue 5 https://doi.org/10.1016/0025-5408(79)90055-2	journal	May 1979
Synthesis of solid materials in molten nitrates Afanasiev, P.; Geantet, C. Coordination Chemistry Reviews, Vol. 178-180 https://doi.org/10.1016/S0010-8545(98)00154-4	journal	December 1998
Effect of foreign particles: a comprehensive understanding of 3D heterogeneous nucleation Liu, X. Y. Journal of Crystal Growth, Vol. 237-239 https://doi.org/10.1016/S0022-0248(01)02348-X	journal	April 2002
Potentiometric acid-base titration in molten salts. The acid character of Li+, Na+, K+, Ca2+, Sr2+, Ba2+ and Pb2+ as inferred from the reaction of their carbonates with K2Cr2O7 in molten KNO3 Shams El Din, A. M.; El Hosary, A. A. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 16, Issue 4 https://doi.org/10.1016/S0022-0728(68)80145-7	journal	April 1968
Electrochemical reduction of oxygen on a strontium doped lanthanum manganite electrode Jiang, Y. Solid State Ionics, Vol. 110, Issue 1-2 https://doi.org/10.1016/S0167-2738(98)00111-8	journal	July 1998
Molten alkali metal nitrate flux to well-crystallized and homogeneous La0.7Sr0.3MnO3 nanocrystallites Luo, Feng; Huang, Yun-Hui; Yan, Chun-Hua Journal of Magnetism and Magnetic Materials, Vol. 260, Issue 1-2 https://doi.org/10.1016/S0304-8853(02)01317-3	journal	March 2003
Oxygen storage capacity of La1−xA′xBO3 perovskites (with A′=Sr, Ce; B=Co, Mn)—relation with catalytic activity in the CH4 oxidation reaction Royer, S.; Alamdari, H.; Duprez, D. Applied Catalysis B: Environmental, Vol. 58, Issue 3-4 https://doi.org/10.1016/j.apcatb.2004.12.010	journal	June 2005
Selected perovskite oxides: Characterization, preparation and photocatalytic properties—A review Grabowska, Ewelina Applied Catalysis B: Environmental, Vol. 186 https://doi.org/10.1016/j.apcatb.2015.12.035	journal	June 2016
Diffusion behavior of actinide and lanthanide elements in molten salt for reductive extraction Yamada, Daichi; Murai, Takayuki; Moritani, Kimikazu Journal of Alloys and Compounds, Vol. 444-445 https://doi.org/10.1016/j.jallcom.2007.02.153	journal	October 2007
Oxygen transport in perovskite and related oxides: A brief review Chroneos, A.; Vovk, R. V.; Goulatis, I. L. Journal of Alloys and Compounds, Vol. 494, Issue 1-2 https://doi.org/10.1016/j.jallcom.2010.01.071	journal	April 2010
Influence of the strontium content on the performance of La1-xSrxMnO3/Bi1.5Er0.5O3 composite electrodes for low temperature Solid Oxide Fuel Cells Pajot, Martin; Duffort, Victor; Capoen, Edouard Journal of Power Sources, Vol. 450 https://doi.org/10.1016/j.jpowsour.2019.227649	journal	February 2020
ABO3-based photocatalysts for water splitting Shi, Jinwen; Guo, Liejin Progress in Natural Science: Materials International, Vol. 22, Issue 6 https://doi.org/10.1016/j.pnsc.2012.12.002	journal	December 2012
Lanthanum-based perovskites obtained in molten nitrates or nitrites Matei, C.; Berger, D.; Marote, P. Progress in Solid State Chemistry, Vol. 35, Issue 2-4 https://doi.org/10.1016/j.progsolidstchem.2007.01.002	journal	January 2007
Recent advances in perovskites: Processing and properties Moure, Carlos; Peña, Octavio Progress in Solid State Chemistry, Vol. 43, Issue 4 https://doi.org/10.1016/j.progsolidstchem.2015.09.001	journal	December 2015
Time-dependent performance of mixed-conducting SOFC cathodes Mai, A.; Becker, M.; Assenmacher, W. Solid State Ionics, Vol. 177, Issue 19-25 https://doi.org/10.1016/j.ssi.2006.06.021	journal	October 2006
Original Synthetic Route To Obtain a SrAl ₂ O ₄ Phosphor by the Molten Salt Method: Insights into the Reaction Mechanism and Enhancement of the Persistent Luminescence Rojas-Hernandez, Rocío Estefanía; Rubio-Marcos, Fernando; Gonçalves, Ricardo Henrique Inorganic Chemistry, Vol. 54, Issue 20 https://doi.org/10.1021/acs.inorgchem.5b01656	journal	October 2015
Molten Salt Flux Synthesis, Crystal Facet Design, Characterization, Electronic Structure, and Catalytic Properties of Perovskite Cobaltite Wang, Xiyang; Huang, Keke; Yuan, Long ACS Applied Materials & Interfaces, Vol. 10, Issue 33 https://doi.org/10.1021/acsami.8b08621	journal	July 2018
Probing Structure−Parameter Correlations in the Molten Salt Synthesis of BaZrO ₃ Perovskite Submicrometer-Sized Particles Zhou, Hongjun; Mao, Yuanbing; Wong, Stanislaus S. Chemistry of Materials, Vol. 19, Issue 22 https://doi.org/10.1021/cm071456j	journal	October 2007
Salt melt synthesis of ceramics, semiconductors and carbon nanostructures Liu, Xiaofeng; Fechler, Nina; Antonietti, Markus Chemical Society Reviews, Vol. 42, Issue 21 https://doi.org/10.1039/C3CS60159E	journal	January 2013
A perspective on liquid salts for energy and materials Irvine, J. T. S. Faraday Discussions, Vol. 190 https://doi.org/10.1039/C6FD00173D	journal	January 2016
Magnetic properties of La ₁₋ _x Sr _x MnO ₃ nanoparticles prepared in a molten salt Kačenka, M.; Kaman, O.; Jirák, Z. Journal of Applied Physics, Vol. 115, Issue 17 https://doi.org/10.1063/1.4867958	journal	May 2014
Sintering Analysis of Undoped and Cobalt Oxide Doped Ceria Solid Solutions Jud, Eva; Huwiler, Christoph B.; Gauckler, Ludwig J. Journal of the American Ceramic Society, Vol. 88, Issue 11 https://doi.org/10.1111/j.1551-2916.2005.00567.x	journal	November 2005
Degradation Mechanisms of La–Sr–Co–Fe–O[sub 3] SOFC Cathodes Simner, S. P.; Anderson, M. D.; Engelhard, M. H. Electrochemical and Solid-State Letters, Vol. 9, Issue 10 https://doi.org/10.1149/1.2266160	journal	January 2006
The Acidic and Basic Properties of Oxides. Flood, H.; Förland, T.; Sillén, Lars Gunnar Acta Chemica Scandinavica, Vol. 1 https://doi.org/10.3891/acta.chem.scand.01-0592	journal	January 1947
LaMnO₃ (La_0.8Sr_0.2MnO₃) Perovskites for Lean Methane Combustion: Effect of Synthesis Method Miniajluk, Natalia; Trawczyński, Janusz; Zawadzki, Mirosław Advances in Materials Physics and Chemistry, Vol. 08, Issue 04 https://doi.org/10.4236/ampc.2018.84013	journal	January 2018

Similar Records

A Facile, One-Step Synthesis for Core–Shell Perovskite Materials via Molten Salt

Journal Article · Thu Apr 01 00:00:00 UTC 2021 · Crystal Growth and Design · OSTI ID:1992213

The chemistry and status of rechargeable molten-salt batteries

Conference · Sun May 01 04:00:00 UTC 1983 · Proc. - Electrochem. Soc.; (United States) · OSTI ID:6288440

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Elucidating the influence of molten salt chemistries on the synthesis and stability of perovskites oxides

Citation Formats

References (28)

Similar Records

Related Subjects