Coherent Hopping Transport and Giant Negative Magnetoresistance in Epitaxial CsSnBr3

Zhang, Liangji; King, Isaac; Nasyedkin, Kostyantyn; Chen, Pei; Skinner, Brian; Lunt, Richard R.; Pollanen, Johannes

doi:10.1021/acsaelm.1c00409

Coherent Hopping Transport and Giant Negative Magnetoresistance in Epitaxial CsSnBr₃

Journal Article · Tue Jul 13 00:00:00 EDT 2021 · ACS Applied Electronic Materials

DOI:https://doi.org/10.1021/acsaelm.1c00409· OSTI ID:1817461

Zhang, Liangji ^[1]; King, Isaac ^[1]; Nasyedkin, Kostyantyn ^[2]; Chen, Pei ^[1]; Skinner, Brian ^[3]; ^[1]; ^[1]

Michigan State Univ., East Lansing, MI (United States)
Michigan State Univ., East Lansing, MI (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
The Ohio State Univ., Columbus, OH (United States)

Single-crystal inorganic halide perovskites are attracting interest for quantum device applications. Here we present low-temperature quantum magnetotransport measurements on thin film devices of epitaxial single-crystal CsSnBr₃, which exhibit two-dimensional Mott variable range hopping (VRH) and giant negative magnetoresistance. These findings are described by a model for quantum interference between different directed hopping paths, and we extract the temperature-dependent hopping length of charge carriers, their localization length, and a lower bound for their phase coherence length of ~100 nm at low temperatures. These observations demonstrate that epitaxial halide perovskite devices are emerging as a material class for low-dimensional quantum coherent transport devices.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1817461

Journal Information:: ACS Applied Electronic Materials, Journal Name: ACS Applied Electronic Materials Journal Issue: 7 Vol. 3; ISSN 2637-6113

Publisher:: ACS PublicationsCopyright Statement

Country of Publication:: United States

Language:: English

References (24)

Orbital magnetoconductance in the variable-range – hopping regime Sivan, U.; Entin-Wohlman, O.; Imry, Y. Physical Review Letters, Vol. 60, Issue 15 https://doi.org/10.1103/physrevlett.60.1566	journal	April 1988
High-Temperature Ionic Epitaxy of Halide Perovskite Thin Film and the Hidden Carrier Dynamics Wang, Yiping; Sun, Xin; Chen, Zhizhong Advanced Materials, Vol. 29, Issue 35 https://doi.org/10.1002/adma.201702643	journal	July 2017
Rich Chemistry in Inorganic Halide Perovskite Nanostructures Huang, Jianmei; Lai, Minliang; Lin, Jia Advanced Materials, Vol. 30, Issue 48 https://doi.org/10.1002/adma.201802856	journal	September 2018
Unlocking the Single-Domain Epitaxy of Halide Perovskites Wang, Lili; Chen, Pei; Thongprong, Non Advanced Materials Interfaces, Vol. 4, Issue 22 https://doi.org/10.1002/admi.201701003	journal	September 2017
Conduction in glasses containing transition metal ions Mott, N. F. Journal of Non-Crystalline Solids, Vol. 1, Issue 1 https://doi.org/10.1016/0022-3093(68)90002-1	journal	December 1968
Weak localization in thin films Bergmann, Gerd Physics Reports, Vol. 107, Issue 1 https://doi.org/10.1016/0370-1573(84)90103-0	journal	May 1984
Potassium Incorporation for Enhanced Performance and Stability of Fully Inorganic Cesium Lead Halide Perovskite Solar Cells Nam, Jae Keun; Chai, Sung Uk; Cha, Wonhee Nano Letters, Vol. 17, Issue 3 https://doi.org/10.1021/acs.nanolett.7b00050	journal	February 2017
Monolithically Integrated Perovskite Semiconductor Lasers on Silicon Photonic Chips by Scalable Top-Down Fabrication Cegielski, Piotr J.; Giesecke, Anna Lena; Neutzner, Stefanie Nano Letters, Vol. 18, Issue 11 https://doi.org/10.1021/acs.nanolett.8b02811	journal	October 2018
Epitaxial Stabilization of Tetragonal Cesium Tin Iodide Wang, Lili; Chen, Pei; Kuttipillai, Padmanaban S. ACS Applied Materials & Interfaces, Vol. 11, Issue 35 https://doi.org/10.1021/acsami.9b05592	journal	June 2019
Light- and Temperature-Modulated Magneto-Transport in Organic–Inorganic Lead Halide Perovskites Keshavarz, Masoumeh; Wiedmann, Steffen; Yuan, Haifeng ACS Energy Letters, Vol. 3, Issue 1 https://doi.org/10.1021/acsenergylett.7b00941	journal	November 2017
Single-Crystal Thin Films of Cesium Lead Bromide Perovskite Epitaxially Grown on Metal Oxide Perovskite (SrTiO ₃ ) Chen, Jie; Morrow, Darien J.; Fu, Yongping Journal of the American Chemical Society, Vol. 139, Issue 38 https://doi.org/10.1021/jacs.7b07506	journal	September 2017
Double-slit photoelectron interference in strong-field ionization of the neon dimer Kunitski, Maksim; Eicke, Nicolas; Huber, Pia Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-018-07882-8	journal	January 2019
Electrode-induced impurities in tin halide perovskite solar cell material CsSnBr3 from first principles Liang, Yuhang; Cui, Xiangyuan; Li, Feng npj Computational Materials, Vol. 7, Issue 1 https://doi.org/10.1038/s41524-021-00533-5	journal	May 2021
Metal halide perovskite nanostructures for optoelectronic applications and the study of physical properties Fu, Yongping; Zhu, Haiming; Chen, Jie Nature Reviews Materials, Vol. 4, Issue 3 https://doi.org/10.1038/s41578-019-0080-9	journal	February 2019
Low-dimensional halide perovskites: review and issues Hong, Kootak; Le, Quyet Van; Kim, Soo Young Journal of Materials Chemistry C, Vol. 6, Issue 9 https://doi.org/10.1039/C7TC05658C	journal	January 2018
Large negative magnetoresistance in Ge films at ultralow temperatures and low magnetic fields Mitin, V. F.; Dugaev, V. K.; Ihas, G. G. Applied Physics Letters, Vol. 91, Issue 20 https://doi.org/10.1063/1.2813615	journal	November 2007
Selection of contact materials to p -type halide perovskite by electronegativity matching Long, Ruiying; Li, Binghan; Mi, Qixi AIP Advances, Vol. 10, Issue 6 https://doi.org/10.1063/5.0008406	journal	June 2020
Epitaxial and quasiepitaxial growth of halide perovskites: New routes to high end optoelectronics Wang, Lili; King, Isaac; Chen, Pei APL Materials, Vol. 8, Issue 10 https://doi.org/10.1063/5.0017172	journal	October 2020
An X-ray study of successive phase transitions in CsSnBr ₃ Mori, M.; Saito, H. Journal of Physics C: Solid State Physics, Vol. 19, Issue 14 https://doi.org/10.1088/0022-3719/19/14/005	journal	May 1986
Negative magnetoresistance in variable-range-hopping conduction Zhao, Hui Lin; Spivak, Boris Z.; Gelfand, Martin P. Physical Review B, Vol. 44, Issue 19 https://doi.org/10.1103/PhysRevB.44.10760	journal	November 1991
Giant negative magnetoresistance of a degenerate two-dimensional electron gas in the variable-range-hopping regime Jiang, H. W.; Johnson, C. E.; Wang, K. L. Physical Review B, Vol. 46, Issue 19 https://doi.org/10.1103/PhysRevB.46.12830	journal	November 1992
Colossal negative magnetoresistance in dilute fluorinated graphene Hong, X.; Cheng, S. -H.; Herding, C. Physical Review B, Vol. 83, Issue 8 https://doi.org/10.1103/PhysRevB.83.085410	journal	February 2011
Observation of conductance fluctuations in large In 2 O 3 − x films Milliken, F. P.; Ovadyahu, Z. Physical Review Letters, Vol. 65, Issue 7 https://doi.org/10.1103/PhysRevLett.65.911	journal	August 1990
Giant magnetoresistance in the variable-range hopping regime Ioffe, L. B.; Spivak, B. Z. Journal of Experimental and Theoretical Physics, Vol. 117, Issue 3 https://doi.org/10.1134/S1063776113110101	journal	September 2013

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CsSnBr3
epitaxial halide perovskites
giant negative magnetoresistance
magnetotransport
quantum devices

Coherent Hopping Transport and Giant Negative Magnetoresistance in Epitaxial CsSnBr3

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References (24)

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Related Subjects

Coherent Hopping Transport and Giant Negative Magnetoresistance in Epitaxial CsSnBr₃