Dry reforming of methane over Ni supported on LaMnO3 thin films

Kwon, Ohhun; Huang, Renjing; Cao, Tianyu; Vohs, John M.; Gorte, Raymond J.

doi:10.1016/j.cattod.2021.08.001

Dry reforming of methane over Ni supported on LaMnO₃ thin films

Journal Article · Sun Aug 08 00:00:00 EDT 2021 · Catalysis Today

DOI:https://doi.org/10.1016/j.cattod.2021.08.001· OSTI ID:1814128

^[1]; Huang, Renjing ^[2]; Cao, Tianyu ^[2]; Vohs, John M. ^[2]; Gorte, Raymond J. ^[2]

Univ. of Pennsylvania, Philadelphia, PA (United States); University of Pennsylvania
Univ. of Pennsylvania, Philadelphia, PA (United States)

Thin films of LaMnO₃ were deposited onto MgAl₂O₄ by Atomic Layer Deposition (ALD) and studied as supports for Ni in the Dry Reforming of Methane (DRM). Scanning Transmission Electron Microscopy (STEM) with Energy-Dispersive X-ray Spectroscopy (EDS) demonstrated that LaMnO₃ covered the support uniformly, and X-ray diffraction (XRD) showed that the LaMnO₃ films maintained their perovskite structure after 5 redox cycles at 1073 K. The Ni also remained well dispersed after 5 redox cycles at 1073 K. The LaMnO₃-supported catalyst was more active than Ni on the unmodified MgAl₂O₄ and showed superior resistance against coke formation. Lastly, the results for Ni on the LaMnO₃ films are compared to previous results for Ni on LaFeO₃, CaTiO₃, SrTiO₃, and BaTiO₃ films.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Pennsylvania, Philadelphia, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0009440

OSTI ID:: 1814128

Alternate ID(s):: OSTI ID: 1862592

Journal Information:: Catalysis Today, Journal Name: Catalysis Today Vol. 365; ISSN 0920-5861

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (31)

Self-Regenerating Rh- and Pt-Based Perovskite Catalysts for Automotive-Emissions Control Tanaka, Hirohisa; Taniguchi, Masashi; Uenishi, Mari Angewandte Chemie International Edition, Vol. 45, Issue 36 https://doi.org/10.1002/anie.200503938	journal	September 2006
A Nickel-Based Perovskite Catalyst with a Bimodal Size Distribution of Nickel Particles for Dry Reforming of Methane Chai, Yingjie; Fu, Yu; Feng, He ChemCatChem, Vol. 10, Issue 9 https://doi.org/10.1002/cctc.201701483	journal	March 2018
Progress of Exsolved Metal Nanoparticles on Oxides as High Performance (Electro)Catalysts for the Conversion of Small Molecules Sun, Xiang; Chen, Huijun; Yin, Yimei Small, Vol. 17, Issue 10 https://doi.org/10.1002/smll.202005383	journal	February 2021
A Study of Support Effects for CH4 and CO Oxidation over Pd Catalysts on ALD-Modified Al2O3 Mao, Xinyu; Foucher, Alexandre; Stach, Eric A. Catalysis Letters, Vol. 149, Issue 4 https://doi.org/10.1007/s10562-019-02699-6	journal	February 2019
Stability of the perovskite phase LaBO3 (B = V, Cr, Mn, Fe, Co, Ni) in reducing atmosphere I. Experimental results Nakamura, Tetsurō; Petzow, G.; Gauckler, L. J. Materials Research Bulletin, Vol. 14, Issue 5 https://doi.org/10.1016/0025-5408(79)90048-5	journal	May 1979
Industrial scale experience on steam reforming of CO 2 -rich gas Mortensen, Peter Mølgaard; Dybkjær, Ib Applied Catalysis A: General, Vol. 495 https://doi.org/10.1016/j.apcata.2015.02.022	journal	April 2015
LaMnO3-based perovskite with in-situ exsolved Ni nanoparticles: a highly active, performance stable and coking resistant catalyst for CO2 dry reforming of CH4 Wei, Tong; Jia, Lichao; Zheng, Haoyu Applied Catalysis A: General, Vol. 564 https://doi.org/10.1016/j.apcata.2018.07.031	journal	August 2018
LaNi1-xMnxO3 perovskite-type oxides as catalysts precursors for dry reforming of methane Valderrama, Gustavo; Kiennemann, Alain; de Navarro, Caribay Urbina Applied Catalysis A: General, Vol. 565 https://doi.org/10.1016/j.apcata.2018.07.039	journal	September 2018
Dry reforming of methane over Ni perovskite type oxides Valderrama, Gustavo; Goldwasser, Mireya R.; Navarro, Caribay Urbina de Catalysis Today, Vol. 107-108 https://doi.org/10.1016/j.cattod.2005.07.010	journal	October 2005
Comparison of precious metal doped and impregnated perovskite oxides for TWC application Malamis, Sotirios A.; Harrington, Rachael J.; Katz, Michael B. Catalysis Today, Vol. 258 https://doi.org/10.1016/j.cattod.2014.11.028	journal	December 2015
Changes in Ni-NiO equilibrium due to LaFeO3 and the effect on dry reforming of CH4 Mao, Xinyu; Foucher, Alexandre C.; Stach, Eric A. Journal of Catalysis, Vol. 381 https://doi.org/10.1016/j.jcat.2019.11.040	journal	January 2020
Screening Divalent Metals for A- and B-Site Dopants in LaFeO ₃ Taylor, Felicity H.; Buckeridge, John; Catlow, C. Richard A. Chemistry of Materials, Vol. 29, Issue 19 https://doi.org/10.1021/acs.chemmater.7b01993	journal	October 2017
Evidence and Model for Strain-Driven Release of Metal Nanocatalysts from Perovskites during Exsolution Oh, Tae-Sik; Rahani, Ehsan K.; Neagu, Dragos The Journal of Physical Chemistry Letters, Vol. 6, Issue 24 https://doi.org/10.1021/acs.jpclett.5b02292	journal	December 2015
Improved Coking Resistance of “Intelligent” Ni Catalysts Prepared by Atomic Layer Deposition Lin, Chao; Jang, Joon Baek; Zhang, Lihua ACS Catalysis, Vol. 8, Issue 8 https://doi.org/10.1021/acscatal.8b01598	journal	July 2018
Approaches for Understanding and Controlling Interfacial Effects in Oxide-Supported Metal Catalysts Ro, Insoo; Resasco, Joaquin; Christopher, Phillip ACS Catalysis, Vol. 8, Issue 8 https://doi.org/10.1021/acscatal.8b02071	journal	July 2018
“Intelligent” Pt Catalysts Studied on High-Surface-Area CaTiO ₃ Films Lin, Chao; Foucher, Alexandre C.; Ji, Yichen ACS Catalysis, Vol. 9, Issue 8 https://doi.org/10.1021/acscatal.9b01278	journal	June 2019
Tutorial on Powder X-ray Diffraction for Characterizing Nanoscale Materials Holder, Cameron F.; Schaak, Raymond E. ACS Nano, Vol. 13, Issue 7 https://doi.org/10.1021/acsnano.9b05157	journal	July 2019
Epitaxial and Strong Support Interactions between Pt and LaFeO ₃ Films Stabilize Pt Dispersion Mao, Xinyu; Foucher, Alexandre C.; Montini, Tiziano Journal of the American Chemical Society, Vol. 142, Issue 23 https://doi.org/10.1021/jacs.0c00138	journal	May 2020
Smart Pd Catalyst with Improved Thermal Stability Supported on High-Surface-Area LaFeO ₃ Prepared by Atomic Layer Deposition Onn, Tzia Ming; Monai, Matteo; Dai, Sheng Journal of the American Chemical Society, Vol. 140, Issue 14 https://doi.org/10.1021/jacs.7b12900	journal	January 2018
Facet-Dependent in Situ Growth of Nanoparticles in Epitaxial Thin Films: The Role of Interfacial Energy Kim, Kun Joong; Han, Hyeon; Defferriere, Thomas Journal of the American Chemical Society, Vol. 141, Issue 18 https://doi.org/10.1021/jacs.9b02283	journal	April 2019
Regeneration of Palladium Subsequent to Solid Solution and Segregation in a Perovskite Catalyst: An Intelligent Catalyst Tanaka, Hirohisa; Tan, Isao; Uenishi, Mari Topics in Catalysis, Vol. 16/17, Issue 1/4, p. 63-70 https://doi.org/10.1023/A:1016626713430	journal	January 2001
Self-regeneration of a Pd-perovskite catalyst for automotive emissions control Nishihata, Y.; Mizuki, J.; Akao, T. Nature, Vol. 418, Issue 6894 https://doi.org/10.1038/nature00893	journal	July 2002
Exsolution trends and co-segregation aspects of self-grown catalyst nanoparticles in perovskites Kwon, Ohhun; Sengodan, Sivaprakash; Kim, Kyeounghak Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15967	journal	June 2017
Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution Neagu, Dragos; Oh, Tae-Sik; Miller, David N. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9120	journal	September 2015
Elucidation of the higher coking resistance of small versus large nickel nanoparticles in methane dry reforming via computational modeling Aleksandrov, Hristiyan A.; Pegios, Nikolaos; Palkovits, Regina Catalysis Science & Technology, Vol. 7, Issue 15 https://doi.org/10.1039/C7CY00773F	journal	January 2017
Self-assembled alloy nanoparticles in a layered double perovskite as a fuel oxidation catalyst for solid oxide fuel cells Kwon, Ohhun; Kim, Kyeounghak; Joo, Sangwook Journal of Materials Chemistry A, Vol. 6, Issue 33 https://doi.org/10.1039/C8TA05105D	journal	January 2018
Investigation of Rh–titanate (ATiO ₃ ) interactions on high-surface-area perovskite thin films prepared by atomic layer deposition Lin, Chao; Foucher, Alexandre C.; Ji, Yichen Journal of Materials Chemistry A, Vol. 8, Issue 33 https://doi.org/10.1039/D0TA05981A	journal	January 2020
Ni-Based Catalysts for Low Temperature Methane Steam Reforming: Recent Results on Ni-Au and Comparison with Other Bi-Metallic Systems Wu, Hongjing; La Parola, Valeria; Pantaleo, Giuseppe Catalysts, Vol. 3, Issue 2 https://doi.org/10.3390/catal3020563	journal	June 2013
Atomic Layer Deposition on Porous Materials: Problems with Conventional Approaches to Catalyst and Fuel Cell Electrode Preparation Onn, Tzia; Küngas, Rainer; Fornasiero, Paolo Inorganics, Vol. 6, Issue 1 https://doi.org/10.3390/inorganics6010034	journal	March 2018
“Intelligent” Pt Catalysts Based on Thin LaCoO3 Films Prepared by Atomic Layer Deposition Mao, Xinyu; Foucher, Alexandre C.; Stach, Eric A. Inorganics, Vol. 7, Issue 9 https://doi.org/10.3390/inorganics7090113	journal	September 2019
A Thermodynamic Investigation of Ni on Thin-Film Titanates (ATiO3) Lin, Chao; Foucher, Alexandre C.; Stach, Eric A. Inorganics, Vol. 8, Issue 12 https://doi.org/10.3390/inorganics8120069	journal	December 2020

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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References (31)

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