Binary Atomically Dispersed Metal-Site Catalysts with Core–Shell Nanostructures for O2 and CO2 Reduction Reactions

Yang, Xiaoxuan; Wang, Maoyu; Zachman, Michael J.; Zhou, Hua; He, Yanghua; Liu, Shengwen; Zang, Hong-Ying; Feng, Zhenxing; Wu, Gang

doi:10.1002/smsc.202100046

Binary Atomically Dispersed Metal-Site Catalysts with Core–Shell Nanostructures for O₂ and CO₂ Reduction Reactions

Journal Article · Thu Aug 05 00:00:00 EDT 2021 · Small Science

DOI:https://doi.org/10.1002/smsc.202100046· OSTI ID:1813129

Yang, Xiaoxuan ^[1]; Wang, Maoyu ^[2]; ^[3]; Zhou, Hua ^[4]; He, Yanghua ^[5]; Liu, Shengwen ^[5]; Zang, Hong-Ying ^[6]; Feng, Zhenxing ^[2]; ^[5]

Northeast Normal Univ., Changchun (China). Key Lab. of Polyoxometetalate Science; State Univ. of New York (SUNY), Buffalo, NY (United States)
Oregon State Univ., Corvallis, OR (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Argonne National Lab. (ANL), Argonne, IL (United States)
State Univ. of New York (SUNY), Buffalo, NY (United States)
Northeast Normal Univ., Changchun (China). Key Lab. of Polyoxometetalate Science

Engineering atomically dispersed metal site catalysts with controlled local coordination environments and 3D nanostructures effectively improves the catalytic performance for the oxygen reduction reaction (ORR) and the carbon dioxide reduction reaction (CO₂RR), which are critical for clean energy conversion and chemical production. Herein, an innovative approach for preparing core-shell nanostructured catalysts with different single-metal sites in the core and the shell, respectively, is developed. In particular, as the shell precursors, covalent organic polymers with a thin layered structure that is polymerized in situ and coated on a metal-doped ZIF-derived carbon core are used, followed by a controlled thermal activation. The selective combination and construction of different metal sites increase active site density in the surface layers, promote structural robustness, facilitate mass/charge transfer, and yield a possible synergy of active sites in the core and the shell. The p-FeNC(shell)@CoNC(core), consisting of a polymerized FeTPPCl-derived carbon layer (p-FeNC) on a Co-doped ZIF-derived carbon (CoNC), exhibits remarkable ORR activity and stability in acidic media along with encouraging durability in H₂–air fuel cells. Likewise, a p-FeNC(shell)@NiNC(core) catalyst demonstrates outstanding CO₂RR activity and stability. Hence, integrating two appropriate single-metal sites in core and shell precursors, respectively, can modulate morphological and catalytic properties for a possible synergy toward different electrocatalysis processes.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: Fundamental Research Funds for the Central Universities; Jilin Provincial Education Department; National Natural Science Foundation of China (NSFC); National Science Foundation (NSF); Natural Science Foundation of Jilin Province; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1813129

Journal Information:: Small Science, Journal Name: Small Science Journal Issue: 10 Vol. 1; ISSN 2688-4046

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (67)

Fabrication of Nickel-Cobalt Bimetal Phosphide Nanocages for Enhanced Oxygen Evolution Catalysis Qiu, Bocheng; Cai, Lejuan; Wang, Yang Advanced Functional Materials, Vol. 28, Issue 17 https://doi.org/10.1002/adfm.201706008	journal	February 2018
Enhanced Capacity and Rate Capability of Nitrogen/Oxygen Dual-Doped Hard Carbon in Capacitive Potassium-Ion Storage Yang, Jinlin; Ju, Zhicheng; Jiang, Yong Advanced Materials, Vol. 30, Issue 4 https://doi.org/10.1002/adma.201700104	journal	December 2017
Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells Wang, Xiao Xia; Cullen, David A.; Pan, Yung-Tin Advanced Materials, Vol. 30, Issue 11 https://doi.org/10.1002/adma.201706758	journal	January 2018
Iron‐Free Cathode Catalysts for Proton‐Exchange‐Membrane Fuel Cells: Cobalt Catalysts and the Peroxide Mitigation Approach Wang, Xiao Xia; Prabhakaran, Venkateshkumar; He, Yanghua Advanced Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adma.201805126	journal	December 2018
Progress in the Development of Fe‐Based PGM‐Free Electrocatalysts for the Oxygen Reduction Reaction Martinez, Ulises; Komini Babu, Siddharth; Holby, Edward F. Advanced Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adma.201806545	journal	December 2018
PGM‐Free Cathode Catalysts for PEM Fuel Cells: A Mini‐Review on Stability Challenges Shao, Yuyan; Dodelet, Jean‐Pol; Wu, Gang Advanced Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adma.201807615	journal	December 2018
Synergistic Catalysis over Iron‐Nitrogen Sites Anchored with Cobalt Phthalocyanine for Efficient CO ₂ Electroreduction Lin, Long; Li, Haobo; Yan, Chengcheng Advanced Materials, Vol. 31, Issue 41 https://doi.org/10.1002/adma.201903470	journal	August 2019
Single Cobalt Sites Dispersed in Hierarchically Porous Nanofiber Networks for Durable and High‐Power PGM‐Free Cathodes in Fuel Cells He, Yanghua; Guo, Hui; Hwang, Sooyeon Advanced Materials, Vol. 32, Issue 46 https://doi.org/10.1002/adma.202003577	journal	October 2020
Highly Active and Stable Graphene Tubes Decorated with FeCoNi Alloy Nanoparticles via a Template-Free Graphitization for Bifunctional Oxygen Reduction and Evolution Gupta, Shiva; Qiao, Liang; Zhao, Shuai Advanced Energy Materials, Vol. 6, Issue 22 https://doi.org/10.1002/aenm.201601198	journal	August 2016
Engineering Local Coordination Environments of Atomically Dispersed and Heteroatom‐Coordinated Single Metal Site Electrocatalysts for Clean Energy‐Conversion Zhu, Yuanzhi; Sokolowski, Joshua; Song, Xiancheng Advanced Energy Materials, Vol. 10, Issue 11 https://doi.org/10.1002/aenm.201902844	journal	November 2019
Highly Efficient Electrocatalysts for Oxygen Reduction Based on 2D Covalent Organic Polymers Complexed with Non-precious Metals Xiang, Zhonghua; Xue, Yuhua; Cao, Dapeng Angewandte Chemie International Edition, Vol. 53, Issue 9 https://doi.org/10.1002/anie.201308896	journal	January 2014
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts Yin, Peiqun; Yao, Tao; Wu, Yuen Angewandte Chemie International Edition, Vol. 55, Issue 36 https://doi.org/10.1002/anie.201604802	journal	August 2016
Isolated Diatomic Ni-Fe Metal-Nitrogen Sites for Synergistic Electroreduction of CO ₂ Ren, Wenhao; Tan, Xin; Yang, Wanfeng Angewandte Chemie International Edition, Vol. 58, Issue 21 https://doi.org/10.1002/anie.201901575	journal	April 2019
Hard‐Sphere Random Close‐Packed Au ₄₇ Cd ₂ (TBBT) ₃₁ Nanoclusters with a Faradaic Efficiency of Up to 96 % for Electrocatalytic CO ₂ Reduction to CO Zhuang, Shengli; Chen, Dong; Liao, Lingwen Angewandte Chemie International Edition, Vol. 59, Issue 8 https://doi.org/10.1002/anie.201912845	journal	February 2020
Understanding the Origin of Highly Selective CO ₂ Electroreduction to CO on Ni,N‐doped Carbon Catalysts Koshy, David M.; Chen, Shucheng; Lee, Dong Un Angewandte Chemie International Edition, Vol. 59, Issue 10 https://doi.org/10.1002/anie.201912857	journal	January 2020
Coordination Tunes Selectivity: Two‐Electron Oxygen Reduction on High‐Loading Molybdenum Single‐Atom Catalysts Tang, Cheng; Jiao, Yan; Shi, Bingyang Angewandte Chemie International Edition, Vol. 59, Issue 23 https://doi.org/10.1002/anie.202003842	journal	April 2020
Electrochemical Reduction of CO ₂ to Ethane through Stabilization of an Ethoxy Intermediate Vasileff, Anthony; Zhu, Yanping; Zhi, Xing Angewandte Chemie International Edition, Vol. 59, Issue 44 https://doi.org/10.1002/anie.202004846	journal	May 2020
Chemical Vapor Deposition for Atomically Dispersed and Nitrogen Coordinated Single Metal Site Catalysts Liu, Shengwen; Wang, Maoyu; Yang, Xiaoxuan Angewandte Chemie International Edition, Vol. 59, Issue 48 https://doi.org/10.1002/anie.202009331	journal	September 2020
Engineering Atomically Dispersed FeN ₄ Active Sites for CO ₂ Electroreduction Mohd Adli, Nadia; Shan, Weitao; Hwang, Sooyeon Angewandte Chemie International Edition, Vol. 60, Issue 2 https://doi.org/10.1002/anie.202012329	journal	November 2020
Dynamically Unveiling Metal–Nitrogen Coordination during Thermal Activation to Design High‐Efficient Atomically Dispersed CoN ₄ Active Sites He, Yanghua; Shi, Qiurong; Shan, Weitao Angewandte Chemie International Edition, Vol. 60, Issue 17 https://doi.org/10.1002/anie.202017288	journal	March 2021
Carbon‐Supported Single Metal Site Catalysts for Electrochemical CO ₂ Reduction to CO and Beyond Zhu, Yuanzhi; Yang, Xiaoxuan; Peng, Cheng Small, Vol. 17, Issue 16 https://doi.org/10.1002/smll.202005148	journal	January 2021
ReS ₂ Nanosheets with In Situ Formed Sulfur Vacancies for Efficient and Highly Selective Photocatalytic CO ₂ Reduction Zhang, Yanzhao; Yao, Dazhi; Xia, Bingquan Small Science, Vol. 1, Issue 2 https://doi.org/10.1002/smsc.202000052	journal	January 2021
In Situ X-ray Absorption Spectroscopy Studies of Nanoscale Electrocatalysts Wang, Maoyu; Árnadóttir, Líney; Xu, Zhichuan J. Nano-Micro Letters, Vol. 11, Issue 1 https://doi.org/10.1007/s40820-019-0277-x	journal	June 2019
Metal-Nitrogen-Carbon Catalysts for Oxygen Reduction in PEM Fuel Cells: Self-Template Synthesis Approach to Enhancing Catalytic Activity and Stability He, Yanghua; Tan, Qiang; Lu, Leilei Electrochemical Energy Reviews, Vol. 2, Issue 2 https://doi.org/10.1007/s41918-019-00031-9	journal	March 2019
Facile synthesis of single-nickel-atomic dispersed N-doped carbon framework for efficient electrochemical CO2 reduction Lu, Peilong; Yang, Yijun; Yao, Jiannian Applied Catalysis B: Environmental, Vol. 241 https://doi.org/10.1016/j.apcatb.2018.09.025	journal	February 2019
Single-Iron Site Catalysts with Self-Assembled Dual-size Architecture and Hierarchical Porosity for Proton-Exchange Membrane Fuel Cells Zhao, Xiaolin; Yang, Xiaoxuan; Wang, Maoyu Applied Catalysis B: Environmental, Vol. 279 https://doi.org/10.1016/j.apcatb.2020.119400	journal	December 2020
Metal-Organic-Framework-Based Materials as Platforms for Renewable Energy and Environmental Applications Zhang, Huabin; Nai, Jianwei; Yu, Le Joule, Vol. 1, Issue 1 https://doi.org/10.1016/j.joule.2017.08.008	journal	September 2017
Iron-Nitrogen-Carbon Catalysts for Proton Exchange Membrane Fuel Cells Asset, Tristan; Atanassov, Plamen Joule, Vol. 4, Issue 1 https://doi.org/10.1016/j.joule.2019.12.002	journal	January 2020
Supported and coordinated single metal site electrocatalysts Shi, Qiurong; Hwang, Sooyeon; Yang, Haipeng Materials Today https://doi.org/10.1016/j.mattod.2020.02.019	journal	March 2020
Carbon nanocomposite catalysts for oxygen reduction and evolution reactions: From nitrogen doping to transition-metal addition Wu, Gang; Santandreu, Ana; Kellogg, William Nano Energy, Vol. 29 https://doi.org/10.1016/j.nanoen.2015.12.032	journal	November 2016
Role of Local Carbon Structure Surrounding FeN ₄ Sites in Boosting the Catalytic Activity for Oxygen Reduction Liu, Kexi; Wu, Gang; Wang, Guofeng The Journal of Physical Chemistry C, Vol. 121, Issue 21 https://doi.org/10.1021/acs.jpcc.7b00913	journal	May 2017
High Power Density Platinum Group Metal-free Cathodes for Polymer Electrolyte Fuel Cells Uddin, Aman; Dunsmore, Lisa; Zhang, Hanguang ACS Applied Materials & Interfaces, Vol. 12, Issue 2 https://doi.org/10.1021/acsami.9b13945	journal	December 2019
Ultrahigh Oxygen Evolution Reaction Activity Achieved Using Ir Single Atoms on Amorphous CoO _x Nanosheets Cai, Chao; Wang, Maoyu; Han, Shaobo ACS Catalysis, Vol. 11, Issue 1 https://doi.org/10.1021/acscatal.0c04656	journal	December 2020
Quaternary FeCoNiMn-Based Nanocarbon Electrocatalysts for Bifunctional Oxygen Reduction and Evolution: Promotional Role of Mn Doping in Stabilizing Carbon Gupta, Shiva; Zhao, Shuai; Wang, Xiao Xia ACS Catalysis, Vol. 7, Issue 12 https://doi.org/10.1021/acscatal.7b02949	journal	November 2017
Microporous Framework Induced Synthesis of Single-Atom Dispersed Fe-N-C Acidic ORR Catalyst and Its in Situ Reduced Fe-N ₄ Active Site Identification Revealed by X-ray Absorption Spectroscopy Xiao, Meiling; Zhu, Jianbing; Ma, Liang ACS Catalysis, Vol. 8, Issue 4 https://doi.org/10.1021/acscatal.8b00138	journal	February 2018
Volcano Trend in Electrocatalytic CO ₂ Reduction Activity over Atomically Dispersed Metal Sites on Nitrogen-Doped Carbon Li, Jingkun; Pršlja, Paulina; Shinagawa, Tatsuya ACS Catalysis, Vol. 9, Issue 11 https://doi.org/10.1021/acscatal.9b02594	journal	September 2019
Well-Defined 2D Covalent Organic Polymers for Energy Electrocatalysis Peng, Peng; Zhou, Zhuohang; Guo, Jianing ACS Energy Letters, Vol. 2, Issue 6 https://doi.org/10.1021/acsenergylett.7b00267	journal	May 2017
pH Effects on the Selectivity of the Electrocatalytic CO ₂ Reduction on Graphene-Embedded Fe–N–C Motifs: Bridging Concepts between Molecular Homogeneous and Solid-State Heterogeneous Catalysis Varela, Ana Sofia; Kroschel, Matthias; Leonard, Nathaniel D. ACS Energy Letters, Vol. 3, Issue 4 https://doi.org/10.1021/acsenergylett.8b00273	journal	March 2018
Atomically Dispersed Metal Catalysts for Oxygen Reduction Chen, Mengjie; He, Yanghua; Spendelow, Jacob S. ACS Energy Letters, Vol. 4, Issue 7 https://doi.org/10.1021/acsenergylett.9b00804	journal	June 2019
Copper(I)-Catalyzed Synthesis of Nanoporous Azo-Linked Polymers: Impact of Textural Properties on Gas Storage and Selective Carbon Dioxide Capture Arab, Pezhman; Rabbani, Mohammad Gulam; Sekizkardes, Ali Kemal Chemistry of Materials, Vol. 26, Issue 3 https://doi.org/10.1021/cm403161e	journal	January 2014
Short-Range Ordered Iridium Single Atoms Integrated into Cobalt Oxide Spinel Structure for Highly Efficient Electrocatalytic Water Oxidation Shan, Jieqiong; Ye, Chao; Chen, Shuangming Journal of the American Chemical Society, Vol. 143, Issue 13 https://doi.org/10.1021/jacs.1c01525	journal	March 2021
Single Atomic Iron Catalysts for Oxygen Reduction in Acidic Media: Particle Size Control and Thermal Activation Zhang, Hanguang; Hwang, Sooyeon; Wang, Maoyu Journal of the American Chemical Society, Vol. 139, Issue 40 https://doi.org/10.1021/jacs.7b06514	journal	September 2017
Hollow N-Doped Carbon Spheres with Isolated Cobalt Single Atomic Sites: Superior Electrocatalysts for Oxygen Reduction Han, Yunhu; Wang, Yang-Gang; Chen, Wenxing Journal of the American Chemical Society, Vol. 139, Issue 48 https://doi.org/10.1021/jacs.7b10194	journal	November 2017
Design of N-Coordinated Dual-Metal Sites: A Stable and Active Pt-Free Catalyst for Acidic Oxygen Reduction Reaction Wang, Jing; Huang, Zhengqing; Liu, Wei Journal of the American Chemical Society, Vol. 139, Issue 48 https://doi.org/10.1021/jacs.7b10385	journal	November 2017
Climbing the Apex of the ORR Volcano Plot via Binuclear Site Construction: Electronic and Geometric Engineering Xiao, Meiling; Chen, Yongting; Zhu, Jianbing Journal of the American Chemical Society, Vol. 141, Issue 44 https://doi.org/10.1021/jacs.9b08362	journal	October 2019
Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts Lin, Lili; Zhou, Wu; Gao, Rui Nature, Vol. 544, Issue 7648 https://doi.org/10.1038/nature21672	journal	March 2017
Single-atom catalysis of CO oxidation using Pt1/FeOx Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng Nature Chemistry, Vol. 3, Issue 8 https://doi.org/10.1038/nchem.1095	journal	July 2011
MoS2 monolayer catalyst doped with isolated Co atoms for the hydrodeoxygenation reaction Liu, Guoliang; Robertson, Alex W.; Li, Molly Meng-Jung Nature Chemistry, Vol. 9, Issue 8 https://doi.org/10.1038/nchem.2740	journal	March 2017
Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2 Ju, Wen; Bagger, Alexander; Hao, Guang-Ping Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01035-z	journal	October 2017
The effects of currents and potentials on the selectivities of copper toward carbon dioxide electroreduction Ren, Dan; Fong, Jinhuan; Yeo, Boon Siang Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03286-w	journal	March 2018
Cation vacancy stabilization of single-atomic-site Pt1/Ni(OH)x catalyst for diboration of alkynes and alkenes Zhang, Jian; Wu, Xi; Cheong, Weng-Chon Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03380-z	journal	March 2018
Stable, high-performance, dendrite-free, seawater-based aqueous batteries Tian, Huajun; Li, Zhao; Feng, Guangxia Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-020-20334-6	journal	January 2021
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction Yang, Hong Bin; Hung, Sung-Fu; Liu, Song Nature Energy, Vol. 3, Issue 2 https://doi.org/10.1038/s41560-017-0078-8	journal	February 2018
Heterogeneous single-atom catalysis Wang, Aiqin; Li, Jun; Zhang, Tao Nature Reviews Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/s41570-018-0010-1	journal	May 2018
Fe–N–C electrocatalyst with dense active sites and efficient mass transport for high-performance proton exchange membrane fuel cells Wan, Xin; Liu, Xiaofang; Li, Yongcheng Nature Catalysis, Vol. 2, Issue 3 https://doi.org/10.1038/s41929-019-0237-3	journal	March 2019
Achievements, challenges and perspectives on cathode catalysts in proton exchange membrane fuel cells for transportation Wang, Xiao Xia; Swihart, Mark T.; Wu, Gang Nature Catalysis, Vol. 2, Issue 7 https://doi.org/10.1038/s41929-019-0304-9	journal	July 2019
Performance enhancement and degradation mechanism identification of a single-atom Co–N–C catalyst for proton exchange membrane fuel cells Xie, Xiaohong; He, Cheng; Li, Boyang Nature Catalysis, Vol. 3, Issue 12 https://doi.org/10.1038/s41929-020-00546-1	journal	November 2020
Solving the activity–stability trade-off riddle Liu, Shengwen; Shi, Qiurong; Wu, Gang Nature Catalysis, Vol. 4, Issue 1 https://doi.org/10.1038/s41929-020-00567-w	journal	January 2021
Ni-based bimetallic heterogeneous catalysts for energy and environmental applications De, Sudipta; Zhang, Jiaguang; Luque, Rafael Energy & Environmental Science, Vol. 9, Issue 11 https://doi.org/10.1039/C6EE02002J	journal	January 2016
Rational design of electrocatalysts and photo(electro)catalysts for nitrogen reduction to ammonia (NH ₃ ) under ambient conditions Guo, Chunxian; Ran, Jingrun; Vasileff, Anthony Energy & Environmental Science, Vol. 11, Issue 1 https://doi.org/10.1039/C7EE02220D	journal	January 2018
Mass transfer effects in CO ₂ reduction on Cu nanowire electrocatalysts Raciti, David; Mao, Mark; Park, Jun Ha Catalysis Science & Technology, Vol. 8, Issue 9 https://doi.org/10.1039/C8CY00372F	journal	January 2018
Highly active atomically dispersed CoN ₄ fuel cell cathode catalysts derived from surfactant-assisted MOFs: carbon-shell confinement strategy He, Yanghua; Hwang, Sooyeon; Cullen, David A. Energy & Environmental Science, Vol. 12, Issue 1 https://doi.org/10.1039/C8EE02694G	journal	January 2019
The chemical identity, state and structure of catalytically active centers during the electrochemical CO ₂ reduction on porous Fe–nitrogen–carbon (Fe–N–C) materials Leonard, Nathaniel; Ju, Wen; Sinev, Ilya Chemical Science, Vol. 9, Issue 22 https://doi.org/10.1039/C8SC00491A	journal	January 2018
Atomically dispersed metal–nitrogen–carbon catalysts for fuel cells: advances in catalyst design, electrode performance, and durability improvement He, Yanghua; Liu, Shengwen; Priest, Cameron Chemical Society Reviews, Vol. 49, Issue 11 https://doi.org/10.1039/C9CS00903E	journal	January 2020
High-performance fuel cell cathodes exclusively containing atomically dispersed iron active sites Zhang, Hanguang; Chung, Hoon T.; Cullen, David A. Energy & Environmental Science, Vol. 12, Issue 8 https://doi.org/10.1039/C9EE00877B	journal	January 2019
Methanol tolerance of atomically dispersed single metal site catalysts: mechanistic understanding and high-performance direct methanol fuel cells Shi, Qiurong; He, Yanghua; Bai, Xiaowan Energy & Environmental Science, Vol. 13, Issue 10 https://doi.org/10.1039/D0EE01968B	journal	January 2020
PEM Fuel Cell Start-up/Shut-down Losses vs Temperature for Non-Graphitized and Graphitized Cathode Carbon Supports Mittermeier, Thomas; Weiß, Alexandra; Hasché, Frédéric Journal of The Electrochemical Society, Vol. 164, Issue 2 https://doi.org/10.1149/2.1061702jes	journal	December 2016

Similar Records

Highly active atomically dispersed CoN ₄ fuel cell cathode catalysts derived from surfactant-assisted MOFs: carbon-shell confinement strategy

Journal Article · Mon Oct 22 20:00:00 EDT 2018 · Energy & Environmental Science · OSTI ID:1480958

Surface and Interface Control in Nanoparticle Catalysis

Journal Article · Wed Oct 02 20:00:00 EDT 2019 · Chemical Reviews · OSTI ID:1599834

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CO2 reduction
atomic metal sites
core-shell structures
electrocatalysis
oxygen reduction

Binary Atomically Dispersed Metal-Site Catalysts with Core–Shell Nanostructures for O2 and CO2 Reduction Reactions

Citation Formats

References (67)

Similar Records

Related Subjects

Binary Atomically Dispersed Metal-Site Catalysts with Core–Shell Nanostructures for O₂ and CO₂ Reduction Reactions