Ready Access to Anhydrous Anionic Lanthanide Acetates by Using Imidazolium Acetate Ionic Liquids as the Reaction Medium

Bousrez, Guillaume; Renier, Olivier; Kelley, Steven P.; Adranno, Brando; Tahavori, Elnaz; Titi, Hatem M.; Smetana, Volodymyr; Tang, Si‐Fu; Mudring, Anja‐Verena; Rogers, Robin D.

doi:10.1002/chem.202100141

Ready Access to Anhydrous Anionic Lanthanide Acetates by Using Imidazolium Acetate Ionic Liquids as the Reaction Medium

Journal Article · Thu Aug 12 00:00:00 EDT 2021 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.202100141· OSTI ID:1812956

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Department of Materials and Environmental Chemistry Stockholm University Svante Arrhenius väg 16 C Stockholm 10691 Sweden
Department of Chemistry University of Missouri 601, S. College Avenue Columbia MO 65211 USA
Department of Chemistry McGill University Montreal QC H3A 0B8 Canada
College of Chemistry and Pharmaceutical Sciences Qingdao Agricultural University Changcheng Road 700, Chengyang District Qingdao 266109 P. R. China
Department of Materials and Environmental Chemistry Stockholm University Svante Arrhenius väg 16 C Stockholm 10691 Sweden, College of Arts &, Sciences The University of Alabama Tuscaloosa AL 35401 USA

Abstract

Access to lanthanide acetate coordination compounds is challenged by the tendency of lanthanides to coordinate water and the plethora of acetate coordination modes. A straightforward, reproducible synthetic procedure by treating lanthanide chloride hydrates with defined ratios of the ionic liquid (IL) 1‐ethyl‐3‐methylimidazolium acetate ([C ₂ mim][OAc]) has been developed. This reaction pathway leads to two isostructural crystalline anhydrous coordination complexes, the polymeric [C ₂ mim] _n [{Ln ₂ (OAc) ₇ } _n ] and the dimeric [C ₂ mim] ₂ [Ln ₂ (OAc) ₈ ], based on the ion size and the ratio of IL used. A reaction with an IL : Ln‐salt ratio of 5 : 1, where Ln=Nd, Sm, and Gd, led exclusively to the polymer, whilst for the heaviest lanthanides (Dy−Lu) the dimer was observed. Reaction with Eu and Tb resulted in a mixture of both polymeric and dimeric forms. When the amount of IL and/or the size of the cation was increased, the reaction led to only the dimeric compound for all the lanthanide series. Crystallographic analyses of the resulting salts revealed three different types of metal‐acetate coordination modes where η ² μκ ² is the most represented in both structure types.

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Research Organization:: Univ. of Alabama, Tuscaloosa, AL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019220

OSTI ID:: 1812956

Alternate ID(s):: OSTI ID: 1812957
OSTI ID: 1831275

Journal Information:: Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 52 Vol. 27; ISSN 0947-6539

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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